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化学学报
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化学学报 ›› 2004, Vol. 62 ›› Issue (5): 518-522. 上一篇    下一篇

研究论文

新型有机非线性光学分子MC-FTC的合成

尹冬冬1, 任宇1, 翟剑峰2, 邱玲2, 沈玉全2   

  1. 1. 北京师范大学化学系, 北京, 100875;
    2. 中国科学院理化技术研究所, 北京, 100101
  • 投稿日期:2003-08-11 修回日期:2003-11-03 发布日期:2014-02-18
  • 通讯作者: 沈玉全,E-mail:shenyq@ipc.ac.cn E-mail:shenyq@ipc.ac.cn
  • 基金资助:
    国家自然科学基金(Nos.60237010,60077024)资助项目.

Synthesis of a Novel Organic Nonlinear Optical Molecule MC-FTC

YIN Dong-Dong1, REN Yu1, ZHAI Jian-Feng2, QIU Ling2, SHEN Yu-Quan2   

  1. 1. Department of Chemistry, Beijing Normal University, Beijing 100875;
    2. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101
  • Received:2003-08-11 Revised:2003-11-03 Published:2014-02-18

PDF

368

被引次数

8

设计和合成了一种新型的有机非线性光学分子,2-二氰基甲叉-3-氰基-4-[2-(N,N-二-乙酰氧基乙基氨基苯乙烯基)-3-正丁基噻吩基-5-乙烯基]-5,5-二甲基-2,5-二氢呋喃 (MC-FTC).报道了它的详细合成方法,给出了反应路线和产物及各个中间体的化学结构,并通过IR, UV/Vis, NMR, MS和元素分析方法确证.

关键词: 有机非线性光学分子, 噻吩, 电光材料

A novel organic nonlinear optical (NLO) chromophore, 2-dicyanomethylene-3-cyano-4-{2-[2-(4-(N,N-di-(2-acetoxyethyl)-amino)phenyl)vinyl-3-(n-butyl)-thien-5-yl]vinyl}-5,5-dimethyl-2,5-dihydrofuran (denoted as MC-FTC), has been designed and synthesized. The detailed synthetic procedure is reported. The reaction route for MC-FTC synthesis including the chemical structures of the related intermediates and the target product has been confirmed by IR, UV-Vis, NMR, MS and elemental analysis.

Key words: organic non-linear material, thiophene, electro-optic material