具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料的储镁性能研究

doi:10.6023/A16100542

化学学报 ›› 2017, Vol. 75 ›› Issue (2): 206-211.DOI: 10.6023/A16100542 上一篇下一篇

所属专题：先进电池材料

研究论文

具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料的储镁性能研究

张长欢^a, 李念武^a, 姚胡蓉^a,b, 刘琳^a,b, 殷雅侠^a,b, 郭玉国^a,b

a 中国科学院化学研究所中国科学院分子纳米结构与纳米技术重点实验室北京 100190;
b 中国科学院大学化学与化工学院北京 100049

投稿日期:2016-10-13 修回日期:2016-12-19 发布日期:2016-12-20
通讯作者: 殷雅侠,E-mail:yxyin@iccas.ac.cn;郭玉国,E-mail:ygguo@iccas.ac.cn;Tel.:010-82617069;Fax:010-82617069 E-mail:yxyin@iccas.ac.cn;ygguo@iccas.ac.cn
基金资助:
项目受国家自然科学基金（Nos.51225204，21303222，21127901）和中国科学院战略性先导科技专项（XDA09010100）资助.

Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage

Zhang Changhuan^a, Li Nianwu^a, Yao Hurong^a,b, Liu Lin^a,b, Yin Yaxia^a,b, Guo Yuguo^a,b

a CAS Key Laboratory of Molecular Nanostructure and Nanotechnology, Institute of Chemistry, Chinese Academy of Sciences(CAS), Beijing 100190, China;
b School of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2016-10-13 Revised:2016-12-19 Published:2016-12-20
Contact: 10.6023/A16100542 E-mail:yxyin@iccas.ac.cn;ygguo@iccas.ac.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Grant Nos. 51225204, 21303222, and 21127901) and the "Strategic Priority Research Program" of the Chinese Academy of Sciences (Grant No. XDA09010100).

文章分享

1. 具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料的储镁性能研究.PDF(358KB)

摘要/Abstract

镁二次电池具有安全性高、价格低廉等优点，是一种具有潜在应用前景的高能量密度电池体系.目前，镁二次电池的研究重点之一是寻找合适的电极材料.最近，我们通过水热和热处理相结合的方法成功制备了具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料.研究发现，在石墨烯的三维导电网络片层上，均匀分布了粒径小于100 nm的锡纳米颗粒.将锡纳米颗粒/石墨烯纳米片复合材料作为镁二次电池电极材料，当电流密度为15 mA·g^-1和300 mA·g^-1时，首次放电容量分别达到了545.4 mAh·g^-1和238.8 mAh·g^-1，经过150圈后，容量保持率达到了93%，库伦效率为99%，表现出了较高的电化学活性.研究还发现，镁离子嵌入复合材料中形成镁锡合金，当镁离子脱出后，再次形成锡纳米颗粒/石墨烯纳米片复合电极材料，镁离子的脱出和嵌入具有很高的可逆性.这对未来研究设计高性能镁离子电极材料具有十分重要的意义.

关键词: 储镁材料, 镁二次电池, 纳米复合材料, 三维导电网络, 锡纳米颗粒, 石墨烯纳米片

Rechargeable magnesium (Mg) batteries have attracted research attention as one promising alternative for energy storage because of abundant raw materials. However, the strong electrostatic interaction between bivalent Mg-ions and host lattices often cause sluggish solid state diffusion of Mg-ion within the local crystal structure and consequently prevent reversible insertion/extraction of Mg-ion. Thus much more effort has been paid to develop suitable electrode materials with Mg-ion storage capability. This paper reports the synthesis of Sn nanoparticles/reduced-graphene-oxide nanosheet hybrid nanocomposite (Sn/rGO), by simple hydrothermal method and subsequent thermal treatment. Transmission electron microscopy (TEM) clearly shows that in the as-synthesized Sn/rGO powder Sn nanoparticles are well crystallized, and X-ray diffraction (XRD) pattern was consistent well with tetragonal Sn. Thermogravimetric analysis (TG) suggested that the mass percentage of Sn is ca. 82.3 wt% in the Sn/rGO nanocomposite, very close to the design ratio of ca. 83.4 wt%. As Mg-ion battery anode, the Sn/rGO electrode material exhibit a high initial discharge specific capacity (545.4 mAh·g^-1 at 15 mA·g^-1), good reversible ability and rate performance. The impressive electrochemical property could be attributed to the unique structure of Sn/rGO, in which the three-dimensional (3D) conducting network of rGO can effectively prevent the aggregation of Sn nanoparticles and alleviate the serious volume variation of Sn during repeated discharging/charging process, as well as facilitate the fast access of electrons and Mg-ion to improve kinetics for Mg-ion insertion/extraction. Ex situ XRD and SEM characterization were performed to investigate the electrochemical evolution of Sn/rGO electrode at different discharging/charging states. It is found that upon magnesiation crystalline Mg₂Sn appears and subsequently disappears during de-magnesiation process, which indicates the good electrochemical activity of Sn nanoparticles in Sn/rGO hybrid nanocomposite for magnesium storage. Our result will open new avenue to develop high-efficient magnesium storage material for rechargeable Mg batteries.

Key words: magnesium storage, rechargeable magnesium battery, nanocomposite, conducting network, tin, graphene

引用此文

张长欢, 李念武, 姚胡蓉, 刘琳, 殷雅侠, 郭玉国. 具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料的储镁性能研究[J]. 化学学报, 2017, 75(2): 206-211.

Zhang Changhuan, Li Nianwu, Yao Hurong, Liu Lin, Yin Yaxia, Guo Yuguo. Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage[J]. Acta Chim. Sinica, 2017, 75(2): 206-211.

导出引用 EndNote|Reference Manager|ProCite|BibTeX|RefWorks

分享此文

参考文献

[1] Ye, Y.; Zhu, J.; Yao, Y.; Wang, Y.; Wu, P.; Tang, Y.; Zhou, Y.; Lu, T. Acta Chim. Sinica 2015, 73, 151. (叶亚, 朱婧怡, 姚依男, 王雨果, 吴平, 唐亚文, 周益明, 陆天虹, 化学学报, 2015, 73, 151.)
[2] Lyu, Z.; Feng, R.; Zhao, J.; Fan, H.; Xu, D.; Wu, Q.; Yang, L.; Chen, Q.; Wang, X.; Hu, Z. Acta Chim. Sinica 2015, 73, 1013. (吕之阳, 冯瑞, 赵进, 范豪, 徐丹, 吴强, 杨立军, 陈强, 王喜章, 胡征, 化学学报, 2015, 73, 1013.)
[3] Qiu, Z. P.; Zhang, Y. J.; Xia, S. B.; Dong, P. Acta Chim. Sinica 2015, 73, 992. (邱振平, 张英杰, 夏书标, 董鹏, 化学学报, 2015, 73, 992.)
[4] Luo, F.; Zheng, J. Y.; Chu, G.; Liu, B. N.; Zhang, S. L.; Li, H.; Chen, L. Q. Acta Chim. Sinica 2015, 73, 808. (罗飞, 郑杰允, 褚赓, 刘柏男, 张素林, 李泓, 陈立泉, 化学学报, 2015, 73, 808.)
[5] Yan, Y.; Yin, Y. X.; Guo, Y. G.; Wan, L. J. Sci. China-Chem. 2014, 57, 1564.
[6] Matsui, M. J. Power Sources 2011, 196, 7048.
[7] Ling, C.; Banerjee, D.; Matsui, M. Electrochim. Acta 2012, 76, 270.
[8] Saha, P.; Datta, M. K.; Velikokhatnyi, O. I.; Manivannan, A.; Alman, D.; Kumta, P. N. Prog. Mater. Sci. 2014, 66, 1.
[9] Yoo, H. D.; Shterenberg, I.; Gofer, Y.; Gershinsky, G.; Pour, N.; Aurbach, D. Energ. Environ. Sci. 2013, 6, 2265.
[10] Shterenberg, I.; Salama, M.; Gofer, Y.; Levi, E.; Aurbach, D. Mrs. Bull. 2014, 39, 453.
[11] Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.; Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature 2000, 407, 724.
[12] Aurbach, D.; Weissman, I.; Gofer, Y.; Levi, E. Chem. Rec. 2003, 3, 61.
[13] Chusid, O.; Gofer, Y.; Gizbar, H.; Vestfrid, Y.; Levi, E.; Aurbach, D.; Riech, I. Adv. Mater. 2003, 15, 627.
[14] Levi, E.; Gofer, Y.; Aurbach, D. Chem. Mater. 2010, 22, 860.
[15] Imamura, D.; Miyayama, M.; Hibino, M.; Kudo, T. J. Electrochem. Soc. 2003, 150, A753.
[16] Tao, Z. L.; Xu, L. N.; Gou, X. L.; Chen, J.; Yuan, H. T. Chem. Commun. 2004, 18, 2080.
[17] Singh, N.; Arthur, T. S.; Ling, C.; Matsui, M.; Mizuno, F. Chem. Commun. 2013, 49, 149.
[18] Shao, Y.; Gu, M.; Li, X.; Nie, Z.; Zuo, P.; Li, G.; Liu, T.; Xiao, J.; Cheng, Y.; Wang, C.; Zhang, J. G.; Liu, J. Nano Lett. 2014, 14, 255.
[19] Wu, N.; Lyu, Y. C.; Xiao, R. J.; Yu, X.; Yin, Y. X.; Yang, X. Q.; Li, H.; Gu, L.; Guo, Y. G. Npg Asia Mater. 2014, 6, e120.
[20] Wu, N.; Yang, Z. Z.; Yao, H. R.; Yin, Y. X.; Gu, L.; Guo, Y. G. Angew. Chem. Int. Ed. 2015, 54, 5757.
[21] He, D.; Wu, D.; Gao, J.; Wu, X.; Zeng, X.; Ding, W. J. Power Sources 2015, 294, 643.
[22] Kim, C.; Phillips, P. J.; Key, B.; Yi, T.; Nordlund, D.; Yu, Y.-S.; Bayliss, R. D.; Han, S.-D.; He, M.; Zhang, Z.; Burrell, A. K.; Klie, R. F.; Cabana, J. Adv. Mater. 2015, 27, 3377.
[23] Liang, Y.; Yoo, H. D.; Li, Y.; Shuai, J.; Calderon, H. A.; Hernandez, F. C. R.; Grabow, L. C.; Yao, Y. Nano Lett. 2015, 15, 2194.
[24] Murgia, F.; Stievano, L.; Monconduit, L.; Berthelot, R. J. Mater. Chem. A 2015, 3, 16478.
[25] Su, S.; Huang, Z.; Nuli, Y.; Tuerxun, F.; Yang, J.; Wang, J. Chem. Commun. 2015, 51, 2641.
[26] Huang, J.; Poyraz, A. S.; Takeuchi, K. J.; Takeuchi, E. S.; Marschilok, A. C. Chem. Commun. 2016, 52, 4088.
[27] Malyi, O. I.; Tan, T. L.; Manzhos, S. J. Power Sources 2013, 233, 341.
[28] Xin, S.; Guo, Y. G.; Wan, L. J. Acc. Chem. Res. 2012, 45, 1759.
[29] Hummers, W. S.; Offeman, R. E. J. Am. Chem. Soc. 1958, 80, 1339.
[30] Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.; Gottlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D. J. Electrochem. Soc. 2008, 155, A103.

具有三维导电网络结构的锡纳米颗粒/石墨烯纳米片复合电极材料的储镁性能研究

Synthesis of Sn Nanoparticles/Graphene Nanosheet Hybrid Electrode Material with Three-Dimensional Conducting Network for Magnesium Storage

PDF

补充材料

可视化

摘要/Abstract

引用此文

分享此文

参考文献

相关文章 15

编辑推荐

相关统计

本文评价

[1]	王华高, 程群峰. 冰模板技术仿生构筑层状高分子纳米复合材料的研究进展^★[J]. 化学学报, 2023, 81(9): 1231-1239.
[2]	薛晓兰, 张洋, 石美瑜, 李天琳, 黄天龙, 戚继球, 委福祥, 隋艳伟, 金钟. 有机电极材料在非水系金属镁二次电池中的研究进展[J]. 化学学报, 2022, 80(12): 1618-1628.
[3]	马超, 武佳炜, 朱琳, 韩晓霞, 阮伟东, 宋薇, 王旭, 赵冰. g-C₃N₄/Ag纳米复合材料表面增强拉曼基底对婴幼儿糖果中的罗丹明B的痕量检测[J]. 化学学报, 2019, 77(10): 1024-1030.
[4]	靳琪, 裴龙凯, 胡宇翔, 杜婧, 韩晓鹏, 程方益, 陈军. 溶剂热/水热法制备MnO_x@rGO纳米复合材料及其氧还原催化性能[J]. 化学学报, 2014, 72(8): 920-926.
[5]	张文凯, 胡成龙, 黄赟赟, 章明秋, 梁晖, 陈旭东. 发光聚合物与大笼型介孔硅构筑的纳米复合体系的光学性能研究[J]. 化学学报, 2012, 70(23): 2425-2432.
[6]	张蕴, 奚晓青, 许姗妮, 周俊晨, 周津金, 徐启宏, 沈昊宇. 氨基功能化纳米复合材料对磷酸盐的吸附研究[J]. 化学学报, 2012, 70(17): 1839-1846.
[7]	陈琳, 申来法, 聂平, 苏晓飞, 张校刚, 李洪森. TiO₂@MWNTs纳米复合材料的制备及其储锂性能[J]. 化学学报, 2012, 70(01): 15-20.
[8]	罗亮, 窦辉, 郝迪, 高思旖, 张校刚. 磁性离子液体中聚乙撑二氧噻吩/多壁碳纳米管纳米复合材料的球磨法制备及表征[J]. 化学学报, 2011, 69(14): 1609-1616.
[9]	盛玮, 徐学诚. 接枝聚苯乙烯/多壁碳纳米管纳米复合材料制备及合成机理[J]. 化学学报, 2011, 69(12): 1393-1398.
[10]	赵茜, 邱东方, 王晓燕, 刘天西. 壳聚糖/氧化石墨烯纳米复合材料的形态和力学性能研究[J]. 化学学报, 2011, 69(10): 1259-1263.
[11]	王继芹, 李鑫, 李淑萍, 仲慧. 醇水介质中共沉淀法制备甲氨蝶呤/层状双氢氧化物纳米材料的研究[J]. 化学学报, 2011, 69(02): 137-144.
[12]	王娜, 苗頔, 李洪伟, 方庆红, 陈尔凡. 界面作用对PMMA/MCM-41/OMMT复合材料性能的影响[J]. 化学学报, 2010, 68(22): 2356-2362.
[13]	孙建平, 翁家宝, 林婷, 马琳璞. 聚(2-甲氧基-5-辛氧基)对苯乙炔/Tb₄O₇纳米复合材料的制备及其光物理性能研究[J]. 化学学报, 2010, 68(13): 1337-1342.
[14]	王晓娟,马淳安,李国华,郑遗凡. WC/TiO2纳米复合材料的制备及其电催化性能[J]. 化学学报, 2009, 67(5): 367-371.
[15]	李淑萍 . 合成温度对Tyr/LDH纳米复合物性质的影响[J]. 化学学报, 2006, 64(23): 2301-2304.