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李晓倩, 西北工业大学化学与化工学院材料学专业在读博士研究生, 研究方向为多孔离子液体的构筑及其气体吸附分离与催化转化应用. |
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张靖, 西北工业大学化学与化工学院在读硕士研究生, 研究方向为先进多孔液体的合成及其催化应用. |
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苏芳芳, 西北工业大学化学与化工学院化学专业在读博士研究生, 研究方向为先进多孔液体及无溶剂纳米流体的合成及其在光热转化领域的应用. |
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王德超, 西北工业大学化学与化工学院化学专业博士研究生在读, 研究方向为新型分离复合材料(无溶剂纳米流体与多孔液体及其膜材料)、碳捕集和吸附工艺、化工过程计算机模拟. |
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姚东东, 西北工业大学化学与化工学院副教授, 2013年获得中国科学院化学所高分子化学与物理专业博士学位, 神奈川大学博士后, 长期从事杂化多孔液体和聚合物纳米复合材料的制备及其应用研究. |
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郑亚萍, 西北工业大学化学与化工学院教授, 博士生导师, 美国康奈尔大学访问学者, 研究方向为多孔液体、无溶剂纳米流体的构筑及其在CO2捕集、聚合物基复合材料纳米填料、膜分离、催化转化、光热转换等领域的应用. 现已主持完成国家自然科学基金、陕西省自然科学基金、航空科学基金等国家级、省部级纵向课题和横向课题20余项. 在AFM、ACS Nano、Angew. Chem.、Small、JMCA、CEJ、Nano-Micro Lett等权威期刊发表论文180余篇; 授权国家发明专利12件; 参编高等学校教材4部. |
收稿日期: 2022-01-27
网络出版日期: 2022-03-23
基金资助
西北工业大学博士论文创新基金(CX2021110); 国家自然科学基金(21905228); 航空科学基金(2018ZF53065)
Construction and Application of Porous Ionic Liquids
Received date: 2022-01-27
Online published: 2022-03-23
Supported by
Innovation Foundation for Doctor Dissertation of NWPU(CX2021110); National Natural Science Foundation of China(21905228); Aeronautical Science Foundation of China(2018ZF53065)
多孔液体(Porous Liquids, PLs)是一类结合了多孔固体永久性孔隙与液态流动性优势的新材料. 自2007年, PLs的概念被首次提出以来, 其在合成策略与应用领域方面均取得了较大的突破. 然而, 传统的PLs因高黏度、高密度、高熔点与高原材料成本等缺陷极大程度制约了其在流动工业系统中的大规模应用. 因此, 迫切需要寻求理想的位阻溶剂用于制备先进的多孔液体. 离子液体(Ionic Liquids, ILs)因独特的可调节物理特性、非挥发性、高稳定性、易获得、经济性高、低再生能耗等特性, 使其成为构筑PLs中最具有应用前景的理想溶剂之一. 在过去的5年间, 基于多种ILs与先进多孔固体(如有机笼、金属有机框架、中空碳、沸石、多孔聚合物等)制备的多孔离子液体(Porous Ionic Liquids, PILs)被陆续报道. PILs独特的永久性孔隙、无溶剂挥发、再生能力强、黏度可调、低熔点、高稳定性等特性加快了其在气体吸附、分离、催化、萃取、分子分离等领域的快速发展. 本综述围绕PILs的构筑策略、特性、应用领域等阐述了其研究进展. 最后, 对PILs在制备中存在的挑战与未来的研究方向进行了归纳与展望.
李晓倩 , 张靖 , 苏芳芳 , 王德超 , 姚东东 , 郑亚萍 . 多孔离子液体的构筑及应用[J]. 化学学报, 2022 , 80(6) : 848 -860 . DOI: 10.6023/A22010053
The concept of porous liquids (PLs) was initially proposed and divided into three types in 2007 by James, which combine the merits of porous solids and flowing liquids. Recently, PLs have made great progress in preparations and applications. However, challenges for PLs still present to be addressed including their high density, viscosity melting temperatures, and materials cost, which severely limit their large-scale applications in flowing systems. Therefore, it is urgent to look for ideal sterically hindered solutions to construct PLs materials. Notably, the unique properties of ionic liquids (ILs), such as the tunable physicochemical properties for task-specific applications, economic, low regeneration energy requirements, enable them as promising candidates for constructing novel porous ionic liquids (PILs). Over the past five years, PILs based on ILs and existing advanced porous solids, such as porous organic cages (POCs), metal-organic frameworks (MOFs), porous carbons, zeolites, porous polymers, etc., have successively witnessed the achievement in synthesis strategies and applications. Notably, PILs exhibit remarkable properties including permanent porosity, negligible volatility, high thermal/chemical stability, non-corrosivity, adjustable melting temperature, viscosity, high gas solubilities, and fast gas diffusion, which have accelerated their applications in gas adsorption/separation, chiral separation, catalytic conversion, extraction, molecular separations, and other fields. In this review, we summarized recent research progress on the synthesis strategies, properties, and applications of PILs. In the end, challenges and future developments for PILs are summarized and prospected.
Key words： porous ionic liquids; porous liquids; ionic liquids; gas capture; separation; catalysis
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