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2022 , Vol. 80 >Issue 12: 1618 - 1628

DOI: https://doi.org/10.6023/A22090385

综述

有机电极材料在非水系金属镁二次电池中的研究进展

  • 薛晓兰 ,
  • 张洋 ,
  • 石美瑜 ,
  • 李天琳 ,
  • 黄天龙 ,
  • 戚继球 ,
  • 委福祥 ,
  • 隋艳伟 ,
  • 金钟
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  • a中国矿业大学 材料与物理学院 徐州 221116
    b南京大学 化学化工学院 介观化学教育部重点实验室 高性能高分子材料与技术教育部重点实验室 江苏省先进有机材料重点实验室 南京 210023

薛晓兰, 2015年于陕西师范大学化学化工学院获学士学位, 2020年于南京大学化学化工学院获博士学位. 2020年被聘为中国矿业大学材料与物理学院讲师. 主要研究方向为新型多价态金属离子电池电极材料的设计合成及储能机制研究.

隋艳伟, 2003年于哈尔滨理工大学获学士学位, 2009年于哈尔滨工业大学获博士学位. 2009年被聘为中国矿业大学材料与物理学院讲师, 2016年于新西兰奥克兰大学进行访学, 2020年被聘为中国矿业大学材料与物理学院教授. 主要从事新能源材料与器件和合金材料及功能化方面的研究.

金钟, 2003年于北京大学化学与分子工程学院获学士学位, 2008年于北京大学化学与分子工程学院获博士学位. 2008年和2010年分别于美国莱斯大学和麻省理工学院进行博士后研究. 2014年被聘为南京大学化学化工学院教授. 主要从事清洁能源转换/存储材料及器件和新型纳米材料性质调控与光电功能器件方面的研究.

收稿日期: 2022-09-05

  网络出版日期: 2022-10-27

基金资助

江苏省自然科学基金青年基金项目(BK20210518); 江苏省自然科学基金青年基金项目(BK20221113); 江苏省双创博士(JSSCBS20211233); 中央高校基本科研业务费(2021QN1106); 中央高校基本科研业务费(020514380266); 中央高校基本科研业务费(020514380272); 中央高校基本科研业务费(020514380274); 国家重点研发计划项目(2017YFA0208200); 国家自然科学基金项目(22022505); 国家自然科学基金项目(21872069); 江苏省碳达峰碳中和科技创新专项资金项目(BK20220008); 南京市国际联合研发项目(202201007); 南京市国际联合研发项目(2022SX00000955); 苏州市(吴江区)姑苏科技创新创业领军人才计划项目(ZXL2021273)

收起

Recent Progress on Organic Electrode Materials for Nonaqueous Magnesium Secondary Batteries

  • Xiaolan Xue ,
  • Yang Zhang ,
  • Meiyu Shi ,
  • Tianlin Li ,
  • Tianlong Huang ,
  • Jiqiu Qi ,
  • Fuxiang Wei ,
  • Yanwei Sui ,
  • Zhong Jin
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  • aSchool of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, China
    bKey Laboratory of Mesoscopic Chemistry of MOE, MOE Key Laboratory of High Performance Polymer Materials and Technology, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China
*E-mail: ;

Received date: 2022-09-05

  Online published: 2022-10-27

Supported by

Natural Science Foundation of Jiangsu Province(BK20210518); Natural Science Foundation of Jiangsu Province(BK20221113); Shuangchuang Program of Jiangsu Province(JSSCBS20211233); Fundamental Research Funds for the Central Universities(2021QN1106); Fundamental Research Funds for the Central Universities(020514380266); Fundamental Research Funds for the Central Universities(020514380272); Fundamental Research Funds for the Central Universities(020514380274); National Key Research and Development Program of China(2017YFA0208200); National Natural Science Foundation of China(22022505); National Natural Science Foundation of China(21872069); Scientific and Technological Innovation Special Fund for Carbon Peak and Carbon Neutrality of Jiangsu Province(BK20220008); Nanjing International Collaboration Research Program(202201007); Nanjing International Collaboration Research Program(2022SX00000955); Suzhou Gusu Leading Talent Program of Science and Technology Innovation and Entrepreneurship in Wujiang District(ZXL2021273)

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摘要

由于镁资源储量丰富、成本低廉, 且金属镁具有理论体积比容量高(3833 mAh/cm3), 沉积/溶解过程中不易形成枝晶等优点, 金属镁二次电池受到了研究者的广泛关注. 然而, Mg2+较大的极性导致其在多数锂离子电池正极材料中无法实现可逆脱嵌. 主流无机电极材料普遍存在只能在较小电流密度下循环、动力学缓慢、制备工艺复杂等问题. 相较而言, 有机电极材料具有理论比容量高、结构多样易调控、资源丰富、环境友好、受离子半径和电荷影响小等优点, 被认为是一种有潜力的电极材料. 综述了近年来用于非水系镁二次电池有机正极材料的研究进展, 讨论了不同类型有机正极材料的电荷存储机制及电化学性能, 并总结了其面临的挑战、解决策略以及未来的发展方向.

关键词： 镁二次电池; 体积比容量; 正极材料; 有机电极材料; 氧化还原机制

本文引用格式

薛晓兰 , 张洋 , 石美瑜 , 李天琳 , 黄天龙 , 戚继球 , 委福祥 , 隋艳伟 , 金钟 . 有机电极材料在非水系金属镁二次电池中的研究进展[J]. 化学学报, 2022 , 80(12) : 1618 -1628 . DOI: 10.6023/A22090385

Abstract

Nonaqueous magnesium secondary batteries have attracted tremendous attention owing to their natural abundance, low cost, high theoretical volumetric specific capacities of 3833 mAh/cm3, and free of dendrite formation. However, the high polarity of Mg2+ ion results in the strong electrostatic interaction between Mg2+ ions and the anions of cathode materials, which makes it difficult to realize reversible insertion and de-insertion of Mg2+ ion in most cathode materials used in lithium ion batteries. At present, the research of cathode materials for magnesium secondary batteries is mainly focused on inorganic compounds. Unfortunately, such cathode materials suffer from problems of working at low current density, slow reaction kinetics, and complicated synthesis process. In comparison, organic electrode materials have been recognized as promising electrode materials for electrochemical energy storage systems because organic materials composed of naturally abundant chemical elements of C, H, O, N, S, etc., can be easily synthesized from renewable resources with low-cost at mild conditions. More importantly, organic materials with chemical diversity and structural flexibility can be purposefully synthesized. What’s more, the capacity, oxidation/reduction potentials, solubility, electron transfer rates, and mechanical properties can be regulated by introducing various groups or heteroatoms. Furthermore, compared to inorganic electrode materials with sluggish kinetics, organic electrode materials usually store ions through ion coordination mechanism, which is not limited by the type and size of ions and can be applied to different energy storage systems such as lithium ion batteries, sodium ion batteries, potassium ion batteries, multivalent-ion batteries, and supercapacitors. Herein, the recent progress of various organic- based materials for nonaqueous magnesium secondary batteries is summarized and the general redox mechanism is presented. Finally, the problems and challenges, resolution strategies and future development directions of organic electrode materials are briefly summarized and discussed.

Key words： magnesium secondary battery; theoretical volumetric specific capacity; cathode material; organic electrode material; redox mechanism

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