Preparation and Electrochemical Lithium Storage of Titanium Dioxide@Multi-walled Carbon Nanotubes(TiO2@MWNTs) Nanocomposites

doi:10.6023/A1105275

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (01): 15-20.DOI: 10.6023/A1105275 Previous Articles Next Articles

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TiO₂@MWNTs纳米复合材料的制备及其储锂性能

陈琳^a, 申来法^b, 聂平^a, 苏晓飞^a, 张校刚^b, 李洪森^b

a. 新疆大学化学化工学院, 乌鲁木齐 830046;
b. 南京航空航天大学材料科学与技术学院, 南京 210016

投稿日期:2011-05-27 修回日期:2011-08-02 发布日期:2012-02-25
通讯作者: 张校刚 E-mail:azhangxg@163.com
基金资助:
国家自然科学基金(Nos.20873064,21173120)以及中国高校博士点专项基金(No.20060287026).

Preparation and Electrochemical Lithium Storage of Titanium Dioxide@Multi-walled Carbon Nanotubes(TiO₂@MWNTs) Nanocomposites

Chen Lin^a, Shen Laifa^b, Nie Ping^a, Su Xiaofei^a, Zhang Xiaogang^b, Li Hongsen^b

a. College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046;
b. College of Material Science and Engineering, Nanjing University of Aeronautics and Astronautics, Nanjing 210016

Received:2011-05-27 Revised:2011-08-02 Published:2012-02-25
Supported by:
Project supported by the National Natural Science Foundation of China(Nos.20873064,21173120),Specialized Research Fund for the Doctoral Program of Higher Education of China(No.20060287026).

The TiO₂@MWNTs nanocomposites have been prepared by a simple one-step solvothermal method using low-cost TiOSO4 as the raw material in the presence of MWNTs.X-ray diffraction(XRD), scan electron microscopy(SEM),transmission electron microscopy(TEM),nitrogen adsorption-desorption and thermogravimetric-differential scanning calorimeter(TG-DSC)analysis were performed to characterize the structures and morphologies of the TiO₂@MWNTs composites.Their lithium storage properties were investigated with galvanostatic charge/discharge measurements when the composites was used as anode materials for lithium-ion batteries(LIBs).The nitrogen adsorption-desorption curve and pore size distribution verified that the TiO₂@MWNTs nanocomposites had rich hierarchical pores and large specific surface area.Compared with pristine TiO₂,these TiO₂@MWNTs nanocomposites exhibited much higher rate capability and even better capacity retention.The reversible capacity of the nanocomposites electrode is up to 200 mAh· g^-1 and remain at 182 mAh· g^-1 at 1 C after 100 cycles.The reversible capacity is about 100 mAh· g^-1 even at the high rate of 10 C.

Key words: lithium-ion battery, anode material, TiO₂@MWNTs nanocomposites, solvothermal

Cite this article

Chen Lin, Shen Laifa, Nie Ping, Su Xiaofei, Zhang Xiaogang, Li Hongsen. Preparation and Electrochemical Lithium Storage of Titanium Dioxide@Multi-walled Carbon Nanotubes(TiO₂@MWNTs) Nanocomposites[J]. Acta Chimica Sinica, 2012, 70(01): 15-20.

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TiO₂@MWNTs纳米复合材料的制备及其储锂性能

Preparation and Electrochemical Lithium Storage of Titanium Dioxide@Multi-walled Carbon Nanotubes(TiO₂@MWNTs) Nanocomposites

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TiO2@MWNTs纳米复合材料的制备及其储锂性能