CdSeTe NSs/TiO2 NTs Photoelectric Catalytic Reduction of CO2

doi:10.6023/A12100830

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (03): 421-426.DOI: 10.6023/A12100830 Previous Articles Next Articles

Article

CdSeTe NSs/TiO₂NTs的制备及其光电催化还原CO₂的应用

井华, 王祜英, 徐金凤, 睢晓娜, 胡海涛, 李培强, 尹洪宗

山东农业大学化学与材料科学学院泰安 271018

投稿日期:2012-10-27 发布日期:2013-02-01
通讯作者: 李培强,尹洪宗 E-mail:chem_carbon@yahoo.cn,pqli@sdau.edu.cn
基金资助:
项目受国家青年自然科学基金(No.21203114)及山东省优秀中青年科学家科研奖励基金(No.BS2012NJ008)资助.

CdSeTe NSs/TiO₂ NTs Photoelectric Catalytic Reduction of CO₂

Jing Hua, Wang Huying, Xu Jinfeng, Sui Xiaona, Hu Haitao, Li Peiqiang, Yin Hongzong

College of Chemistry and Material Science, Shandong Agricultural University, Tai'an 271018

Received:2012-10-27 Published:2013-02-01
Supported by:
Project supported by the National Natural Science Foundation of China (No. 21203114) and the Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province (No. BS2012NJ008).

The TiO₂ NTs was prepared by means of anodic oxidation method at the applied voltage of 20 V. The electrolyte consisted of 0.8 wt% NH₄F, 1.6 wt% NaSO₄, and 10 wt% PEG400. After 3 h anodization, it was rinsed with twice-distilled water and dried in a nitrogen stream. And then the amorphous TiO₂ NTs were crystallized by annealing in oxygen atmosphere for 1.5 h at 500 ℃ at both heating and cooling rates of 1 ℃·min^-1. Subsequently, the TiO₂ NTs and CdSeTe precursor solution were placed in teflon-lined stainless reactor at 120 ℃ for 2 h. Then the CdSeTe modified TiO₂ NTs were dried at 80 ℃, at last, the modified TiO₂ NTs was treated at 500 ℃ for 2 h under nitrogen atmosphere with heating and cooling rate of 2 ℃·min^-1. The catalyst of CdSeTe NSs/TiO₂ NTs was gained finally. According to the SEM (Scanning electron microscope), TEM (Transmission electron microscopy) and HRTEM (High resolution transmission electron microscopy) testing, it showed that the CdSeTe was sheet morphology and grew on the TiO₂ NTs surface parallelly. XRD (X-ray diffraction) characterization revealed that CdSeTe NSs had preferential orientation along the (100) and (002) direction. Measured by UV-vis DRS (Ultraviolet-visible diffuse reflection spectrum), it got the band gap of the as-prepared catalyst material, 1.48 eV. Processing XPS (X-ray photoelectron spectroscopy) data by Linear extrapolation, we got its valence band located at 1.02 eV. So we could deduce that the conduction band minimum (CBM) was located at -0.46 eV. Under light irradiation, the photoelectrocatalytic reduction performance for CO₂ had a significant improvement compared with TiO₂ NTs, it expressed as the great increase of reduction current density. In the photoelectrocatalytic reduction of CO₂ process, methanol was the major product identified by gas chromatography, and the excellent reduction mechanism was explained from the following three aspects: energy band match, electron high transport ability and the stability of catalyst material.

Key words: CdSeTe, TiO₂ NTs, PEC reduction, CO₂, energy band match

Cite this article

Jing Hua, Wang Huying, Xu Jinfeng, Sui Xiaona, Hu Haitao, Li Peiqiang, Yin Hongzong. CdSeTe NSs/TiO₂ NTs Photoelectric Catalytic Reduction of CO₂[J]. Acta Chimica Sinica, 2013, 71(03): 421-426.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Guo, X. M.; Mao, D. S.; Lu, G. Z.; Wang, S. Acta Phys.-Chim. Sin. 2012, 28, 170. (郭晓明, 毛东森, 卢冠忠, 王嵩, 物理化学学报, 2012, 28, 170.)

[2] Ekambaram, B.; Chidambaram, G.; Zhang, J.; Linda, J. W. S.; David, M. Nature Chem. 2011, 3, 609.

[3] Oomman, K. V.; Maggie, P.; Thomas, J. L.; Craig, A. G. Nano Lett. 2009, 9, 731.

[4] Hiroyuki, T.; Kazuhide, K.; Haruo, I.; Osamu, I. J. Am. Chem. Soc. 2008, 130, 2023.

[5] Gabriel, M.; Douglas, W. S. J. Am. Chem. Soc. 2010, 132, 1796.

[6] Rakowski Dubois, M.; Dubois, D. L. Acc. Chem. Res. 2009, 42, 1974.

[7] Liu, Y. Y.; Huang, B. B.; Dai, Y.; Zhang, X. Y.; Qin, X. Y.; Jiang, M. H.; Myung, H. W. Acc. Chem. Res. 2009, 11, 210.

[8] Guo, X. M.; Mao, D. S.; Wang, S.; Wu, G. S.; Lu, G. Z. Acc. Chem. Res. 2009, 10, 1661.

[9] Michael, E. B.; Douglas, E. A.; William, E. S. Jr. Geology 1996, 24, 351.

[10] Inoue, T.; Fujishima, A.; Konishi, S.; Honda, K. Nature 1979, 277, 637.

[11] Panagiotopoulou, P.; Kondarides, D. I. J. Catal. 2004, 6, 327.

[12] Feng, L. R.; Lü, S. J.; Qiu, F. L. Acta Chim. Sinica 2002, 60, 463. (冯良荣, 吕绍洁, 邱发礼, 化学学报, 2002, 60, 463.)

[13] Shi, J. Y.; Chen, J.; Feng, Z. C.; Chen, T.; Lian, Y. X.; Wang, X. L.; Li, C. J. Phys. Chem. C 2007, 111, 693.

[14] Alberto, N.; Mattia, A.; Saveria, S.; Marcello, M.; Filippo, F.; Serena, C.; Claudia, L. B.; Rinaldo, P.; Vladimiro, D. S. J. Am. Chem. Soc. 2012, 134, 7600.

[15] Ahmed, E. R. M.; Sohrab, R. Energy Environ. Sci. 2011, 4, 1065.

[16] Zhang, Z. H.; Md, F. H.; Takakazu, T. Appl. Catal., B: Environ. 2010, 95, 423.

[17] Laura, A. S.; Lauren, A. W.; Michael, J. B.; James, R. M.; Jason, L. R.; Tony, L. W.; Sriram, K. D.; Leonard, C. F.; Sandra, J. R. J. Am. Chem. Soc. 2006, 128, 12299.

[18] Shun, S. L.; Tihana, M.; Chi-Hung, C.; Clemens, B.; Gregory, D. S. Adv. Mater. 2011, 23, 180.

[19] Tenne, R.; Hodes, G. Appl. Phys. Lett. 1980, 37, 428.

[20] Henglein, A. J. Phys. Chem. 1982, 86, 2291.

[21] Peng, J.; Fang, X. M.; Chen, Z. H.; Zhang, Z. G. Acta Phys.-Chim. Sin. 2012, 28, 232. (彭静, 方晓明, 陈志鸿, 张正国, 物理化学学报, 2012, 28, 232.)

[22] Liang, G. X.; Li, L. L.; Liu, H. Y.; Zhang, J. R.; Clemens, B.; Zhu, J. J. Chem. Commun. 2010, 46, 2974.

[23] Grégory, B.; Sudarsan, T.; Aude, B.; Pascale, B. G.; Daphna, F.; Guy, S.; FranÅoise, V.; Peter, R.; Isabelle, T. ChemPhysChem 2011, 12, 2247.

[24] Shen, Y. Y.; Li, L. L.; Lu, Q.; Ji, J.; Fei, R.; Zhang, J. R.; Abdel, H. E. S.; Zhu, J. J. Chem. Commun. 2012, 48, 2222.

[25] Li, P. Q.; Zhao, G. H.; Cui, X.; Zhang, Y. G.; Tang, Y. T. J. Phys. Chem. C 2009, 113, 2375.

[26] Xue, D. J.; Tan, J. H.; Hu, J. S.; Hu, W. P.; Guo, Y. G.; Wan, L. J. Adv. Mater. 2012, 24, 4528.

[27] Nataliya, P.; Andrei, S. S.; Markus, D.; Andrey, L. R. J. Phys. Chem. C 2008, 112, 15253.

[28] Tsvetkov, N.; Liudmila, L.; Oleg, S.; Byung, T. A. Energy Environ. Sci. 2011, 4, 1480.

[29] Debajeet, K. B.; Artur, B.; Rolf, E.; Giuseppino, F.; Thomas, G.; Edwin, C. C. Chem. Mater. 2011, 23, 2051.

CdSeTe NSs/TiO₂NTs的制备及其光电催化还原CO₂的应用

CdSeTe NSs/TiO₂ NTs Photoelectric Catalytic Reduction of CO₂

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yuhan Wu, Dongdong Zhang, Hongyu Yin, Zhengnan Chen, Wen Zhao, Yuhua Chi. Density Functional Theory Study of Janus In₂S₂X Photocatalytic Reduction of CO₂ under “Double Carbon” Target [J]. Acta Chimica Sinica, 2023, 81(9): 1148-1156.
[2]	Guoqing Cui, Yiyang Hu, Yingjie Lou, Mingxia Zhou, Yuming Li, Yajun Wang, Guiyuan Jiang, Chunming Xu. Research Progress on the Design, Preparation and Properties of Catalysts for CO₂ Hydrogenation to Alcohols [J]. Acta Chimica Sinica, 2023, 81(8): 1081-1100.
[3]	Ruxin Tian, Miao Yang, Guo Chen, Jiangshan Liu, Mengmei Yuan, Hong Yuan, Shuxin Ouyang, Tierui Zhang. Ru/Quartz Filter Paper: A Recyclable Photothermocatalytic Film for CO₂ Methanation^★ [J]. Acta Chimica Sinica, 2023, 81(8): 869-873.
[4]	Shaojuan Zeng, Xueqi Sun, Yinge Bai, Lu Bai, Shuang Zheng, Xiangping Zhang, Suojiang Zhang. Research Progress of CO₂ Capture and Separation by Functionalized Ionic Liquids and Materials^★ [J]. Acta Chimica Sinica, 2023, 81(6): 627-645.
[5]	Xiaohan Yu, Wei Huang, Yanguang Li. Controllable Synthesis and Photocatalytic Applications of Two-dimensional Covalent Organic Frameworks [J]. Acta Chimica Sinica, 2022, 80(11): 1494-1506.
[6]	Zitao Wang, Yaozu Liu, Yujie Wang, Qianrong Fang. A New Covalent Organic Framework Modified with Sulfonic Acid for CO₂ Uptake and Selective Dye Adsorption [J]. Acta Chimica Sinica, 2022, 80(1): 37-43.
[7]	Xusheng Wang, Xu Yang, Chunhui Chen, Hongfang Li, Yuanbiao Huang, Rong Cao. Graphene Quantum Dots Supported on Fe-based Metal-Organic Frameworks for Efficient Photocatalytic CO₂ Reduction^※ [J]. Acta Chimica Sinica, 2022, 80(1): 22-28.
[8]	Ruizhao Wang, Yunjie Zou, Sheng Hong, Mingkai Xu, Lan Ling. High-performance Pt_0.01Fe_0.05-g-C₃N₄ Catalyst for Photothermal Catalytic CO₂ Reduction [J]. Acta Chimica Sinica, 2021, 79(7): 932-940.
[9]	Chunhui Mu, Yixin Zhang, Wei Kou, Lianbin Xu. Nickel-Nitrogen-Doped Ordered Macro-/Mesoporous Carbon Supported Ag Nanoparticles for Efficient Electrocatalytic CO₂ Reduction [J]. Acta Chimica Sinica, 2021, 79(7): 925-931.
[10]	Sun Jingjing, Wu Qiurong, Weng Wenqiang, Liu Xiaoqin, Tan Peng, Sun Linbing. Smart Light-responsive CO₂ Adsorbents for Regulating Strong Active Sites [J]. Acta Chimica Sinica, 2020, 78(10): 1082-1088.
[11]	Zhang Xuhan, Deng Bowen, Fan Haidong, Huang Wenhui, Zhang Yanwei. Photo-thermochemical CO₂ Splitting Based on Zinc-germanium Binary Oxide [J]. Acta Chimica Sinica, 2020, 78(10): 1120-1126.
[12]	Peng Zhengkang, Ding Huimin, Chen Rufan, Gao Chao, Wang Cheng. Research Progress in Covalent Organic Frameworks for Energy Storage and Conversion [J]. Acta Chim. Sinica, 2019, 77(8): 681-689.
[13]	Chen Zhiyao, Liu Jiewei, Cui Hao, Zhang Li, Su Chengyong. Applications of Porphyrin Metal-Organic Frameworks in CO₂ Capture and Conversion [J]. Acta Chim. Sinica, 2019, 77(3): 242-252.
[14]	Liang Shan, Zong Minhua, Lou Wenyong. Recent Advances in Enzymatic Catalysis for Preparation of High Value-Added Chemicals from Carbon Dioxide [J]. Acta Chimica Sinica, 2019, 77(11): 1099-1114.
[15]	Li Xin, Zhang Taiyang, Wang Tian, Zhao Yixin. Recent Progress of Photocatalysis Based on Metal Halide Perovskites [J]. Acta Chimica Sinica, 2019, 77(11): 1075-1088.

CdSeTe NSs/TiO2NTs的制备及其光电催化还原CO2的应用