Recent Progress of Photocatalysis Based on Metal Halide Perovskites

doi:10.6023/A19080292

Abstract

photocatalytic pollutant degradation and the synthesis of chemical fuels or other high value-added products via photocatalysis have drawn plenty of attentions in green chemistry and renewable energy research. In recent years, metal-halide perovskites with superior photoelectric properties are successfully utilized into high-efficiency photocatalytic reactions in addition to conventional metal oxide semiconductor materials. In this paper, we reviewed the recent advances of metal-halide perovskite based photocatalyst, especially lead-halide perovskites in photocatalytic hydrogen production, photocatalytic degradation and CO₂ reduction. The reaction mechanisms and key challenges for metal halide perovskites photocatalyst are discussed and we prospect the further development of highly efficient and stable metal halide perovskite photocatalysis in the future.

Key words: metal halide perovskites, photocatalysis, photocatalytic hydrogen production, photocatalytic CO₂ reduction, photocatalytic synthesis

Cite this article

Li Xin, Zhang Taiyang, Wang Tian, Zhao Yixin. Recent Progress of Photocatalysis Based on Metal Halide Perovskites[J]. Acta Chimica Sinica, 2019, 77(11): 1075-1088.

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Figure 1. Schematic representation of the typical ABX3 crystal structure of halide perovskites. Reprinted with permission from ref. [22]. Copyright (2019) Royal Society of Chemistry.

Figure 2. Schematic illustration for natural (a) and artificial (b) photosynthesis. Reprinted with permission from ref. [82]. Copyright (2019) American Chemical Society.

Figure 3. (a) Schematic illustration of photoelectrochemical test of a Ni-coated perovskite photoanode in a PEC cell using standard three-electrode system. The photoanode is back illuminated from the FTO side. (b) Schematic energy diagram of TiO2, CH3NH3PbI3, spiro-MeOTAD, Au, and Ni. The energy levels of each material are given in eV. Reprinted with permission from ref. [87]. Copyright (2015) American Chemical Society. (c) Schematic illustration of the sandwich-like CH3NH3PbI3 photocathode for PEC H2 evolution in a standard three-electrode system. The photocathode is back illuminated from the ITO side. (d) Schematic energy diagram of each component in inverted CH3NH3PbI3 solar cell. Reprinted with permission from ref. [88]. Copyright (2018) John Wiley and Sons.

Figure 4. (a) Schematic illustration of the MAPbI3 powder in dynamic equilibrium with a saturated HI solution. (b) Constructed phase map as a function of [I?] and [H+]. Reprinted by permission from ref. [97]. Copyright (2016) Springer Nature. (c) Pb-Activated amine-assisted (PbAAA) reaction pathway for H2 generation on MAPbI3 surface in acidic solvent. Reprinted by permission from ref. [98]. Copyright (2018) American Chemical Society.

Figure 5. (a) Schematic illustration of the reaction mechanism for MAPbBr3 with Pt/Ta2O5 and PEDOT:PSS as the electron- and hole-transporting motifs, respectively. (b) Schematic energy level diagrams of MAPbBr3, Ta2O5, and PEDOT:PSS for HBr splitting reaction. Reprinted by permission from ref. [102]. Copyright (2019) American Chemical Society.

Figure 6. Schematic illustration of the energy band structure and possible transfer process of photo-induced carriers: (a) CsPbBr3 NC/MRGO and (b) CsPbBr3 NC/BZNW/MRGO hybrids under visible light irradiation. Reprinted by permission from ref. [108]. Copyright (2019) Royal Society of Chemistry.

Figure 7. The free energy diagrams of the most favored paths of CO2 reduction on pristine, Co-doped and Fe-doped cases. The ΔG of the rate-determining step for each case is listed. Reprinted by permission from ref. [109]. Copyright (2019) Royal Society of Chemistry.

Figure 8. Proposed reaction mechanism of the perovskite photoactivated polymerization of styrene. Reprinted with permission from ref. [116]. Copyright (2019) John Wiley and Sons.

Figure 9. (a) Scheme of the photocatalysis mechanism proposed. Reprinted with permission from ref. [125]. Copyright (2018) John Wiley and Sons. (b) Proposed photocatalytic cycle for epoxide alcoholysis reaction over Cs3Bi2Br9 with proper Lewis acids sites on surface. Reprinted with permission from ref. [59]. Copyright (2019) John Wiley and Sons.

Figure 10. (a) Crystal structure of cubic Cs2AgBiBr6. (b) Schematic diagram of the photoreduction of CO2 on the surface of Cs2AgBiBr6 NCs. Reprinted with permission from ref. [62]. Copyright (2018) John Wiley and Sons.

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