Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis

doi:10.6023/A12110850

Acta Chimica Sinica ›› 2013, Vol. 71 ›› Issue (01): 40-43.DOI: 10.6023/A12110850 Previous Articles Next Articles

Communications

聚乙二醇负载的二茂铁噁唑啉配体的合成及其应用

刘洪强^a,b, 时磊^a, 陈庆安^a, 王磊^b, 周永贵^a

a 中国科学院大连化学物理研究所大连 116023;
b 淮北师范大学淮北市 235000

投稿日期:2012-11-01 发布日期:2012-12-10
通讯作者: 王磊, 周永贵 E-mail:ygzhou@dicp.ac.cn; leiwang@chnu.edu.cn
基金资助:
项目受国家自然科学基金(Nos. 21202162 and 21125208)和国家重大基础研究项目(No. 2010CB833300)资助.

Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis

Liu Hongqiang^a,b, Shi Lei^a, Chen Qingan^a, Wang Lei^b, Zhou Yonggui^a

a Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
b Huaibei Normal University, Huaibei 235000, China

Received:2012-11-01 Published:2012-12-10
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21202162 & 21125208) and the National Basic Research Program of China (No. 2010CB833300).

1. Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis.PDF(1499KB)

Abstract

A simple synthesis of ferrocenyloxazoline derived chiral N,P ligands and N,S ligands immobilized on a MeO- PEG-support is described. The metal complexes of chiral ligands have been successfully applied to 1,3-dipolar cycloaddition reaction of azomethine ylides and asymmetric allylic substitution reaction, providing the products with up to 97% ee and 90% ee, respectively. The MeO-PEG-supported metal complex catalysts can be recycled easily and reused.

Key words: PEG, ferrocenyloxazoline ligands, asymmetric catalysis

Cite this article

Liu Hongqiang, Shi Lei, Chen Qingan, Wang Lei, Zhou Yonggui. Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis[J]. Acta Chimica Sinica, 2013, 71(01): 40-43.

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聚乙二醇负载的二茂铁噁唑啉配体的合成及其应用

Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis

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