Nitrogen-Doped Carbon Nanocages as High-Rate Anode for Lithium Ion Batteries

doi:10.6023/A15040289

Acta Chim. Sinica ›› 2015, Vol. 73 ›› Issue (10): 1013-1017.DOI: 10.6023/A15040289 Previous Articles Next Articles

Communication

高倍率锂离子电池负极材料:氮掺杂碳纳米笼

吕之阳^a, 冯瑞^a, 赵进^a, 范豪^a, 徐丹^a, 吴强^a, 杨立军^a, 陈强^a,b, 王喜章^a,b, 胡征^a

a 南京大学化学化工学院介观化学教育部重点实验室南京 210093;
b 常州南京大学高新技术研究院常州 213164

投稿日期:2015-04-28 发布日期:2015-07-23
通讯作者: 王喜章 E-mail:wangxzh@nju.edu.cn
基金资助:
项目受国家自然科学基金(Nos.21473089,51232003,21373108,21173115,21203092),“973”项目(No.2013CB932902),苏州市科技计划(No.ZXG2013025)和常州市科技支撑计划(No.CE20130032)资助.

Nitrogen-Doped Carbon Nanocages as High-Rate Anode for Lithium Ion Batteries

Lyu Zhiyang^a, Feng Rui^a, Zhao Jin^a, Fan Hao^a, Xu Dan^a, Wu Qiang^a, Yang Lijun^a, Chen Qiang^a,b, Wang Xizhang^a,b, Hu Zheng^a

a Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093;
b High Technology Research Institute of Nanjing University, Changzhou 213164

Received:2015-04-28 Published:2015-07-23
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21473089, 51232003, 21373108, 21173115, 21203092), “973” programs (No. 2013CB932902), Suzhou Program (No. ZXG2013025) and Changzhou Technology Support Program (No. CE20130032).

The specific power or rate capability of lithium-ion batteries (LIBs) today is insufficient for electric vehicles requiring fast charging and high power output. Compared with great progresses in the high-rate cathodes of LIBs, the development of matchable high-rate anodes still becomes a huge challenge. Carbonaceous materials have been widely used as the anodes of commercial LIBs due to the good conductivity, low cost and environmental friendliness. The nanostructured carbon materials could achieve the high surface area for electrolyte penetration and the short solid-state ion diffusion length for rapid ion transport. Moreover, carbon nanomaterials avoid the large volume change during lithiation/delithiation, which is grave problem for the other high capacity anode materials including Si-based materials and metal oxides. In addition, heteroatom-doping can provide further space for the optimization of lithium storage performance. Herein, we reported the nitrogen-doped carbon nanocages (NCNC) as high-performance anode materials for lithium ion batteries, prepared by an in-situ generated magnesium oxide template method (from decomposition of basic magnesium carbonate) and pyridine as carbon source at growth temperatures of 700, 800, and 900 ℃. The morphology, structure, and electrochemical performances were investigated by transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), nitrogen adsorption/desorption equipment, and constant current discharge/charge tests. For example, NCNC800, prepared at 800 ℃, has a high specific surface area (1197 m²·g^-1), high nitrogen content (8.2 at%), good conductivity (46 S·m^-1) and mesopores structure. As an anode material for LIBs, NCNC800 delivers a steady charge capacity of ca. 900 mAh·g^-1 at a low current density of 0.1 A·g^-1 after 20 cycles activation, and stabilizes at ca. 135 mAh·g^-1 even over 500 cycles at a high rate of 20.0 A·g^-1, which are superior to graphene and graphite. These good electrochemical performances, such as high steady charge capacity, high-rate capability and excellent cyclability, can be ascribed to the unique structure of NCNC, which is beneficial to the electrolyte penetration, Li-ion diffusion, electron conduction, and structural stability during lithium ions intercalation/deintercalation. This unique carbon nanomaterial provides a new alternative of anode materials for high-performance LIBs.

Key words: nitrogen-doped carbon nanocages, lithium-ion battery, anode material, high-rate

Cite this article

Lyu Zhiyang, Feng Rui, Zhao Jin, Fan Hao, Xu Dan, Wu Qiang, Yang Lijun, Chen Qiang, Wang Xizhang, Hu Zheng. Nitrogen-Doped Carbon Nanocages as High-Rate Anode for Lithium Ion Batteries[J]. Acta Chim. Sinica, 2015, 73(10): 1013-1017.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Armand, M.; Tarascon, J. M. Nature 2008, 451, 652.

[2] Xu, Y.; Guo, J.; Wang, C. J. Mater. Chem. 2012, 22, 9562.

[3] Goodenough, J. B.; Park, K. S. J. Am. Chem. Soc. 2013, 135, 1167.

[4] Shen, L. F.; Uchaker, E.; Zhang, X. G.; Cao, G. Z. Adv. Mater. 2012, 24, 6502.

[5] Kang, B.; Ceder, G. Nature 2009, 458, 190.

[6] Wu, X. L.; Jiang, L. Y.; Cao, F. F.; Guo, Y. G.; Wan, L. J. Adv. Mater. 2009, 21, 2710.

[7] Wang, L.; He X, Sun W.; Wang, J.; Li, Y.; Fan, S. Nano Lett. 2012, 12, 5632.

[8] Ye, Y.; Zhu, J. Y.; Yao, Y. N.; Wang, Y. G.; Wu, P.; Tang, Y. W.; Zhou, Y. M.; Lu, T. H. Acta Chim. Sinica 2015, 73, 151. (叶亚, 朱婧怡, 姚依男, 王雨果, 吴平, 唐亚文, 周益明, 陆天虹, 化学学报, 2015, 73, 151.)

[9] Manthiram, A. J. Phys. Chem. Lett. 2011, 2, 176.
[10] Li, H.; Wang, Z. X.; Chen, L. Q.; Huang, X. J. Adv. Mater. 2009, 21, 4593.
[11] Zhu, G. N.; Liu, H. J.; Zhuang, J. H.; Wang, C. X.; Wang, Y. G.; Xia, Y. Y. Energy Environ. Sci. 2011, 4, 4016.
[12] Zhang, Y.; Hu, X.; Xu, Y.; Ding, M. Acta Chim. Sinica 2013, 71, 1341. (张永龙, 胡学步, 徐云兰, 丁明亮, 化学学报, 2013, 71, 1341.)
[13] Zhang, F. Ph.D. Dissertation, Jilin University, Jilin, 2009 (张峰, 博士论文, 吉林大学, 吉林, 2009).
[14] Ng, S. H.; Wang, J.; Guo, Z. P.; Chen, J.; Wang, G. X.; Liu, H. K. Electrochim. Acta 2005, 51, 23.
[15] Li, C. C.; Yin, X. M.; Chen, L. B.; Li, Q. H.; Wang, T. L. J. Phys. Chem. C 2009, 113, 13438.
[16] Han, F. D.; Yao, B.; Bai, Y. J. J. Phys. Chem. C 2011, 115, 8923.
[17] Wu, Z. S.; Ren, W.; Xu, L.; Xu, L.; Li, F.; Cheng, H. M. ACS Nano 2011, 5, 5463.
[18] Fang, Y.; Lv, Y.; Che, R.; Wu, H.; Zhang, X.; Gu, D.; Zheng, G.; Zhao, D. J. Am. Chem. Soc. 2013, 135, 1524.
[19] Yang, L. J.; Jiang, S. J.; Zhao, Y.; Zhu, L.; Chen, S.; Wang, X. Z.; Wu, Q.; Ma, J.; Ma, Y. W.; Hu, Z. Angew. Chem., Int. Ed. 2011, 50, 7132.
[20] Zhao, Y.; Yang, L. J.; Chen, S.; Wang, X. Z.; Ma, Y. W.; Wu, Q.; Jiang, Y.; Qian, W. J.; Hu, Z. J. Am. Chem. Soc. 2013, 135, 1201.
[21] Ma, Y. W.; Sun, L. Y.; Huang, W.; Zhang, L. R.; Zhao, J.; Fan, Q. L.; Huang, W. J. Phys. Chem. C 2011, 115, 24592.
[22] Long, Q.; Chen, W. M.; Wang, Z. H.; Shao, Q. G.; Li, X.; Yuan, L. X.; Hu, X. L.; Zhang, W. X.; Huang, Y. H. Adv. Mater. 2012, 24, 2047.
[23] Shin, W. H.; Jeong, H. M.; Kim, B. G.; Kang, J. K.; Choi, J. W. Nano Lett. 2012, 12, 2283.
[24] Xie, K.; Qin, X. T.; Wang, X. Z.; Wang, Y. N.; Tao, H. S.; Wu, Q.; Yang, L. J.; Hu, Z. Adv. Mater. 2012, 24, 347.
[25] Chen, S.; Bi, J. Y.; Zhao, Y.; Yang, L. J.; Zhang, C.; Ma, Y. W.; Wu, Q.; Wang, X. Z.; Hu, Z. Adv. Mater. 2012, 24, 5593.
[26] Feng, R.; Wang, L. W.; Lyu, Z. Y.; Wu, Q.; Yang, L. J.; Wang, X. Z.; Hu, Z. Acta Chim. Sinica 2014, 72, 653. (冯瑞, 王立伟, 吕之阳, 吴强, 杨立军, 王喜章, 胡征, 化学学报, 2014, 72, 653.)
[27] Kaskhedikar, N. A.; Maier, J. Adv. Mater. 2009, 21, 2664.
[28] Wen, L.; Liu, C. M.; Song, R. S.; Luo, H. Z.; Shi, Y.; Li, F.; Chen, H. M. Acta Chim. Sinica 2014, 72, 333. (闻雷, 刘成名, 宋仁升, 罗洪泽, 石颖, 李峰, 成会明, 化学学报, 2014, 72, 333.)
[29] Liu, N.; Hu, L.; McDowell, M. T.; Jackson, A.; Cui, Y. ACS Nano 2011, 5, 657.
[30] Hou, J. H.; Cao, C. B.; Idrees, F.; Ma, X. L. ACS Nano 2015, 9, 2556.
[31] Song, H. W.; Yang, G. Z.; Wang, C. X. ACS Appl. Mater. Interfaces 2014, 6, 21661.
[32] Wu, Z. S.; Ren, W.; Wen, L.; Gao, L.; Zhao, J. P.; Chen, Z. P.; Zhou, G. M.; Li, F.; Cheng, H. M. ACS Nano 2010, 4, 3187.
[33] Lyu, Z. Y.; Xu, D.; Yang, L. J.; Che, R. C.; Feng, R.; Zhao, J.; Li, Y.; Wu, Q.; Wang, X. Z.; Hu, Z. Nano Energy 2015, 12, 657.

高倍率锂离子电池负极材料:氮掺杂碳纳米笼

Nitrogen-Doped Carbon Nanocages as High-Rate Anode for Lithium Ion Batteries

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xiaoyu Gu, Jin Li, Qian Sun, Chaoyang Wang. Microcalorimetry Analysis of Thermal Runaway Process in Lithium-ion Batteries [J]. Acta Chimica Sinica, 2024, 82(2): 146-151.
[2]	Jia Yanggang, Chen Shijie, Shao Xia, Cheng Jie, Lin Na, Fang Daolai, Mao Aiqin, Li Canhua. Preparation and High-performance Lithium-ion Storage of Cobalt-free Perovskite High-entropy Oxide Anode Materials [J]. Acta Chimica Sinica, 2023, 81(5): 486-495.
[3]	Yalan Zhang, Zhixiang Yuan, Hao Zhang, Jianjun Zhang, Guanglei Cui. Research Progress of High-energy-density Solid-state Lithium Ion Batteries Employing Ni-rich Ternary Cathodes [J]. Acta Chimica Sinica, 2023, 81(12): 1724-1738.
[4]	Wanying Chang, Yingying Tan, Jingyi Wu, Yingjie Liu, Jinhai Cai, Chunyan Lai. Study on the Properties of Polyethylene Oxide Based Solid State Electrolyte Enhanced by Three-Dimensional Structured Li_6.28La₃Zr₂Al_0.24O₁₂ [J]. Acta Chimica Sinica, 2023, 81(12): 1708-1715.
[5]	Shuang Zhang, Chengfei Yang, Yubo Yang, Ningning Feng, Gang Yang. Electrochemical Behaviors of Li_xMO (x=0.79, 0.30, 0.08; M=Ni/Co/Mn) Recycled from Spent Li-ion Batteries as Cathodic Catalyst for Lithium-Oxygen Battery [J]. Acta Chimica Sinica, 2022, 80(9): 1269-1276.
[6]	Wenchao Bi, Linfeng Zhang, Jian Chen, Ruixue Tian, Hao Huang, Man Yao. Lithiation Mechanism and Performance of Monoclinic ZnP₂ Anode Materials [J]. Acta Chimica Sinica, 2022, 80(6): 756-764.
[7]	Shouxiao Chen, Junke Liu, Weichen Zheng, Guozhen Wei, Yao Zhou, Juntao Li. Electron/ion Conductor Double-coated LiNi_0.8Co_0.1Mn_0.1O₂ Li-ion Battery Cathode Material and Its Electrochemical Performance [J]. Acta Chimica Sinica, 2022, 80(4): 485-493.
[8]	Kai Qiu, Mingxia Yan, Shouwang Zhao, Shengli An, Wei Wang, Guixiao Jia. Theoretical Study on the Structural Stability and Oxygen Ion Oxidation of Al-doped Lithium-ion Battery Layered Cathode Li(Li_0.17Ni_0.17Al_0.04Fe_0.13Mn_0.49)O₂ [J]. Acta Chimica Sinica, 2021, 79(9): 1146-1153.
[9]	Ping Xu, Xihua Zhang, En Ma, Fu Rao, Chunwei Liu, Peifan Yao, Zhi Sun, Jingwei Wang. Selective Recovery of Lithium from Spent Lithium-ion Batteries Synergized by Carbon and Sulfur Elements [J]. Acta Chimica Sinica, 2021, 79(8): 1073-1081.
[10]	Zhi Chang, Yu Qiao, Huijun Yang, Han Deng, Xingyu Zhu, Ping He, Haoshen Zhou. Applications of Metal-organic Frameworks (MOFs) Materials in Lithium-ion Battery/Lithium-metal Battery Electrolytes [J]. Acta Chimica Sinica, 2021, 79(2): 139-145.
[11]	Tang Gong-ao, Mao Kun, Zhang Jing, Lyu Pin, Cheng Xueyi, Wu Qiang, Yang Lijun, Wang Xizhang, Hu Zheng. Hierarchical Nitrogen-doped Carbon Nanocages as High-rate Long-life Cathode Material for Rechargeable Magnesium Batteries [J]. Acta Chimica Sinica, 2020, 78(5): 444-450.
[12]	Wang Shan, Fan Xiaoyong, Cui Yu, Gou Lei, Wang Xingang, Li Donglin. Three-dimensional Porous Current Collector for Lithium Storage Enhancement of NiO Electrode [J]. Acta Chim. Sinica, 2019, 77(6): 551-558.
[13]	Wang Xiaoyu, Zhang Yu, Ma Lei, Wei Liangming. Recent Development on Binders for Silicon-Based Anodes in Lithium-Ion Batteries [J]. Acta Chim. Sinica, 2019, 77(1): 24-40.
[14]	Wang Ling, Yang Guorui, Wang Jianan, Wang Silan, Peng Shengjie, Yan Wei. Research Progress on Electrospun Materials for Sodium-Ion Batteries [J]. Acta Chim. Sinica, 2018, 76(9): 666-680.
[15]	Deng Bangwei, Sun Daming, Wan Qi, Wang Hao, Chen Tao, Li Xuan, Qu Meizhen, Peng Gongchang. Review of Electrolyte Additives for Ternary Cathode Lithium-ion Battery [J]. Acta Chim. Sinica, 2018, 76(4): 259-277.