Transition Metal Catalyzed Deoxydehydration of Alcohols

doi:10.6023/A18040138

Acta Chim. Sinica ›› 2018, Vol. 76 ›› Issue (7): 501-514.DOI: 10.6023/A18040138 Previous Articles Next Articles

Review

过渡金属催化的醇类脱氧脱水反应

李翠^a, 张琪^b, 傅尧^a

a 中国科学技术大学化学系合肥 230026;
b 合肥工业大学工业与装备技术研究院合肥 230009

发布日期:2018-05-14
通讯作者: 傅尧,E-mail:fuyao@ustc.edu.cn;Tel.:0086-0551-63606689 E-mail:fuyao@ustc.edu.cn
作者简介:李翠,中国科学技术大学在读硕士生;张琪,合肥工业大学工业与装备技术研究院讲师.主要从事有机化学与材料化学方向的理论计算研究,2013年获得国家杰出青年科学基金资助,2017年入选国家"万人计划"领军人才,获得国家自然科学二等奖(第二完成人)、闵恩泽能源化工奖杰出贡献奖等荣誉.
基金资助:
项目受国家自然科学基金（Nos.21325208，21572212，21732006，21702041）、国家科技部基金（No.2017YFA0303500）、中国科学院战略性先导项目（No.XDB20000000）、中央高校基本科研专项资金和教育部长江学者和创新团队发展计划资助.

Transition Metal Catalyzed Deoxydehydration of Alcohols

Li Cui^a, Zhang Qi^b, Fu Yao^a

a Department of Chemistry, University of Science and Technology of China, Hefei 230026;
b Institute of Industry & Equipment Technology, Hefei University of Technology, Hefei 230009

Published:2018-05-14
Contact: 10.6023/A18040138 E-mail:fuyao@ustc.edu.cn
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 21325208, 21572212, 21732006, 21702041), Ministry of Science and Technology of China (No. 2017YFA0303500), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDB20000000), Fundamental Research Funds for the Central Universities, and Program for Changjiang Scholars and Innovative Research Team in University.

In view of the depletion of fossil fuels, the development and utilization of environment-friendly and sustainable resources widely play an indispensable role in alleviating and resolving problems about resources and environment. Biomass could be utilized as biofuels and renewable platform chemicals. However, biomass-derived molecules are fairly oxygen-rich and hyperfunctionalized. Therefore, new synthetic routes for the regenerative production of chemicals, fuels, and energy from renewable biomass sources are currently investigated especially the routes of transforming high-oxygen-content biomassderived vicinal diols and poly vicinal alcohols into fuels and value-added chemicals. A range of reductive deoxygenation methods consisting of direct deoxygenation, pyrolysis, hydrogenolysis, decarbonylation, decarboxylation, hydrodeoxygenation, and deoxydehydration (DODH) are under investigation. In this review, we detail the recent-evolutionary and efficient strategies of transition metal-catalyzed DODH of vicinal diols into corresponding alkenes, including rhenium, molybdenum, vanadium, and ruthenium catalysts. Rhenium-catalyzed DODH reactions are very selective and active to provide high yields of olefin products, which keep important functionality in place as well as can be readily functionalized. Recent efforts in rhenium-mediated systems include the development of new rhenium catalysts, the application of cheaper and more available reductants, and growing mechanistic understandings owing to both theoretical and experimental studies. A new emerging trend within DODH is the development of heterogeneous rhenium-based catalysts which demonstrates their ability to rival and in some cases surpass their homogeneous counterparts. Furthermore, catalysts based on the transition metals molybdenum, vanadium and ruthenium show great potential as inexpensive alternatives to rhenium catalysts.

Key words: deoxydehydration, transition metal, vicinal diol, olefin, biomass derivatives

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Li Cui, Zhang Qi, Fu Yao. Transition Metal Catalyzed Deoxydehydration of Alcohols[J]. Acta Chim. Sinica, 2018, 76(7): 501-514.

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过渡金属催化的醇类脱氧脱水反应

Transition Metal Catalyzed Deoxydehydration of Alcohols

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