Research Progress of Key Materials for Sodium-selenium Batteries

doi:10.6023/A20120576

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (5): 641-648.DOI: 10.6023/A20120576 Previous Articles Next Articles

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钠硒电池关键材料的研究进展

林碧霞^a, 黄颖珊^a, 陈帅^a, 邢震宇^a^,^b^,^*()

a 华南师范大学化学学院广州 510006
b 环境理论化学教育部重点实验室广州 510006

投稿日期:2020-12-20 发布日期:2021-02-22
通讯作者: 邢震宇

作者简介:

林碧霞, 2011年于华南师范大学取得硕士学位, 目前主要研究方向集中于纳米材料的制备及其在光电领域的应用.

邢震宇, 2012年吉林大学取得化学学士学位, 2016年美国Oregon State University取得化学博士学位, 之后在加拿大University of Waterloo从事博士后研究, 自2018年被引进华南师范大学工作. 主要研究方向集中于基于金属热反应的材料制备及其在能源存储领域的应用, 尤其在碳材料和硫化锂材料的制备方面取得了系统性的研究进展.

基金资助:
项目受国家自然科学基金青年基金(22002045); 广东省基础与应用基础研究基金自然科学基金项目(面上项目)(2020A1515011549); 广东省普通高校青年创新人才项目(2018KQNCX059)

Research Progress of Key Materials for Sodium-selenium Batteries

Bixia Lin^a, Yingshan Huang^a, Shuai Chen^a, Zhenyu Xing^a^,^b^,^*()

a School of Chemistry, South China Normal University, Guangzhou 510006, China
b Key Laboratory of Theoretical Chemistry of Environment, Ministry of Education, Guangzhou 510006, China

Received:2020-12-20 Published:2021-02-22
Contact: Zhenyu Xing
About author:
*E-mail: xingzhenyu@m.scnu.edu.cn
Supported by:
National Natural Science Foundation of China(22002045); Guangdong Basic and Applied Basic Research Foundation(2020A1515011549); Education Department of Guangdong Province(2018KQNCX059)

Sodium-selenium batteries show some advantages in stationary energy storage, benefitting from selenium cathode of high conductivity (1×10^–3 S/m), high volume-specific capacity (3253 mAh/cm³), as well as sodium anode of abundant resources and low cost. However, the serious shuttle effect and volume change of selenium cathode greatly limit the further development. Herein, basic mechanism and current problems of sodium-selenium batteries are summarized, and the current research progress are discussed in detail. In end, future development of sodium-selenium is proposed, in order to provide some new perspectives.

Key words: sodium-selenium battery, shuttle effect, stationary energy storage, cathode material

Cite this article

Bixia Lin, Yingshan Huang, Shuai Chen, Zhenyu Xing. Research Progress of Key Materials for Sodium-selenium Batteries[J]. Acta Chimica Sinica, 2021, 79(5): 641-648.

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Fig. & Tab. 18

Figure 1. Number of publications on sodium-selenium batteries in recent years

Figure 2. (a) CV curve; (b) charge and discharge curve; (c) in situ Raman spectra after discharging to 1.7, 1.3 and 0.5 V; (d) XRD results after discharging to 0.5 V of selenium cathode[14]

Figure 3. Schematic diagram of lattice conversion of selenium during charging and discharging[13]

Figure 4. Existing problems in sodium-selenium batteries

Figure 5. Schematic diagram of sodium dendrite formation in carbonate electrolyte by metal sodium anode[16]

Figure 6. (a) Schematic of the material synthesis process; (b) schematic diagram of Jackfruit-like structure constructed from porous carbon nanorods as hosts for selenium[14]

Figure 7. (a) Multiplier performance; (b) charge-discharge curve corresponding to multiplier performance; (c) cycling performance at current density of 2 C[14]

Figure 8. Schematic diagram of preparation of Se/carbon composites with tubular hollow structure[27]

Figure 9. Structure diagram of selenium/cellulose derived carbon nanosheet composite[28]

Figure 10. Schematic diagram of melt injection and steam permeation methods for Se/ graphene composites[30]

Figure 11. Schematic diagram of CNF/Se electrode synthesis process[31]

Figure 12. Schematic diagram of the synthesis process of single sheet carbon derived from selenium impregnated nanocellulose[32]

Figure 13. Schematic diagram of Se/NPCPs composite material synthesis[34]

Figure 14. Schematic diagram of the preparation process of fractional porous carbon with selenium-microporous-mesoporous structure[35]

Figure 15. Schematic diagram of N-HRMC/Se material synthesis[37]

Figure 16. Schematic diagram of the synthesis process of nitrogen- doped carbon coating iron carbide/selenium (Fe3C@C-Se)[11]

Figure 17. Schematic diagram of carbon material coated battery separator[31]

Material	Mass fraction of Se/%	Initial capacity/(mAh∙g^–1)	Capacity retention/(mAh∙g^–1)	Cycle	Rate	Ref.
Jackfruit-Se/C composite	54	616	399	600	2 C	[14]
Se@NCAs	47	599	407	800	0.5 A/g	[15]
Se-R800A	66.7	300	300	500	2 A/g	[29]
Fe₃C@C-Se	72.6	457 (3rd)	375	300	2 C	[11]
Se@N-HRMC	72.6	500 (3rd)	450	500	0.5 C	[37]
Se@N-MCPs	54	520 (4th)	460	500	1 A/g	[35]
VSeG	52.5	410	370	800	2 A/g	[30]
iPANI@NSHPC/Se	54	630	617	200	0.2 C	[33]
Se/HDHPC	56	619	400	500	0.5 C	[38]
Se@MCNFs	64	590	490	300	0.5 A/g	[26]
Se@CNFs-CNT	60	580	550	80	0.05 A/g	[39]

Table 1. Electrochemical performances of reported sodium-selenium batteries cathode materials in recent years

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钠硒电池关键材料的研究进展

Research Progress of Key Materials for Sodium-selenium Batteries

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