Organic Modification of Layered Double Hydroxides and Its Applications

doi:10.6023/A22110448

Acta Chimica Sinica ›› 2023, Vol. 81 ›› Issue (2): 207-216.DOI: 10.6023/A22110448 Previous Articles

Review

层状复合氢氧化物的有机改性方法及应用研究进展

杨娜^a^,^b^,^c, 马建中^a^,^b^,^c^,^*(), 石佳博^a^,^b^,^c^,^*(), 郭旭^d

a 陕西科技大学轻工科学与工程学院西安 710021
b 轻化工程国家级实验教学示范中心西安 710021
c 西安市绿色化学品与功能材料重点实验室西安 710021
d 哈尔滨工业大学环境学院哈尔滨 150001

投稿日期:2022-11-03 发布日期:2022-12-23
通讯作者: 马建中, 石佳博

作者简介:

杨娜, 现为陕西科技大学2020级生物质化学与材料工程专业博士研究生, 2018年7月获陕西科技大学轻化工程专业学士学位. 导师为马建中教授和石佳博副教授, 研究方向为超分子插层材料的构筑及其改性胶原纤维研究.

马建中, 现为陕西科技大学轻工科学与工程学院教授, 博士生导师. 1998年获浙江大学高分子化学与物理理学博士学位, 1999~2000年美国农业部东部地区研究中心访问学者. 研究方向: (1)水性高分子的设计与合成; (2)有机/无机纳米复合材料的关键技术; (3)轻纺化学产品的开发与应用. 研究成果获国家技术发明二等奖1项、国家科学技术进步二等奖1项, 何梁何利基金科学与技术创新奖1项.

石佳博, 现为陕西科技大学轻工科学与工程学院副教授、硕士生导师. 2017年获四川大学皮革化学与工程专业博士学位. 研究方向为制革/胶原化学和生物质纳米复合材料的基础与应用研究.

郭旭, 现为哈尔滨工业大学环境学院2021级土木工程专业博士研究生, 2021年获陕西科技大学轻工技术与工程专业硕士学位. 随后进入哈尔滨工业大学环境学院攻读博士学位, 研究方向为生物质衍生碳基复合电极的构筑及其电催化降解污染物的研究.

基金资助:
国家自然科学基金重点项目(21838007); 国家自然科学基金(22208201); 陕西省创新能力支撑计划(2021TD-16)

Organic Modification of Layered Double Hydroxides and Its Applications

Na Yang^a^,^b^,^c, Jianzhong Ma^a^,^b^,^c(), Jiabo Shi^a^,^b^,^c(), Xu Guo^d

a College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021
b National Demonstration Center for Experimental Light Chemistry Engineering Education, Xi’an 710021
c Xi’an Key Laboratory of Green Chemicals and Functional Materials, Xi’an 710021
d School of Environment, Harbin Institute of Technology, Harbin 150001

Received:2022-11-03 Published:2022-12-23
Contact: Jianzhong Ma, Jiabo Shi
Supported by:
National Natural Science Foundation of China (Key Program)(21838007); National Natural Science Foundation of China(22208201); Innovation Capability Support Program of Shaanxi Province(2021TD-16)

Layered double hydroxides (LDHs) have attracted wide attention in the fields of environment, energy and biomedicine owing to their tunable chemical composition, large specific surface area and good biocompatibility. However, the agglomeration of LDHs caused by the intermolecular forces during their synthesis process may lead to their uneven dispersion in the matrix, thereby limiting their further practical application. In this review, the organic modification methods of LDHs in recent years are summarized from the perspectives of surface modification and intercalation modification. Their emerging applications in diverse fields, such as flame retardancy, adsorption, catalysis, gas barrier, luminescence, energy storage and biomedicine are also described. Finally, future research directions and application fields of modified LDHs are highlighted.

Key words: layered double hydroxides, organic modification, surface modification, intercalating modification, application

Cite this article

Na Yang, Jianzhong Ma, Jiabo Shi, Xu Guo. Organic Modification of Layered Double Hydroxides and Its Applications[J]. Acta Chimica Sinica, 2023, 81(2): 207-216.

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Fig. & Tab. 9

Figure 1. Schematic diagram of LDHs

Figure 2. Schematic diagram of organic modification method of LDHs

Figure 3. Schematic diagram of flame retardant mechanism of GLDHs/EP composites with flame retardant properties[55]

Figure 4. Schematic representation of the selective removal of MG and CV by LDH@PDA@MPNs[60]

Figure 5. Schematic diagram of preparation of MoPS-NiFe-LDHs with electrocatalytic properties[67]

Figure 6. Schematic diagram of preparation of LDHs nanosheets with oxygen barrier performance[69]

Figure 7. Schematic diagram of drug sustained release based on LDHs[72]

Figure 8. Schematic diagram of preparation of fluorescent silicone resin nanocomposite with luminescent properties[75]

Figure 9. Schematic diagram of deposition of NiCo LDH intercalated with SDBS on CFC to improve its electrochemical performance[79]

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层状复合氢氧化物的有机改性方法及应用研究进展

Organic Modification of Layered Double Hydroxides and Its Applications

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