Advances in Porous Organic Cages for Energy Conversion and Storage

doi:10.6023/A25030098

Acta Chimica Sinica ›› 2025, Vol. 83 ›› Issue (6): 624-638.DOI: 10.6023/A25030098 Previous Articles Next Articles

Review

多孔有机笼用于能源转换及储存的研究进展

崔雨琪^†, 李军玉^†, 孙建科^*()

北京理工大学化学与化工学院原子分子簇科学教育部重点实验室北京 102488

投稿日期:2025-03-28 发布日期:2025-05-15

作者简介:

崔雨琪, 2022年北京理工大学在读硕士研究生, 主要研究方向为多孔有机笼复合材料的制备及其催化性能研究.

李军玉, 2024年北京理工大学在读博士研究生, 主要研究方向为多孔有机笼复合材料的制备及其催化性能研究.

孙建科, 博士, 北京理工大学化学与化工学院教授, 博士生导师. 长期从事功能多孔材料与团簇催化化学方面的交叉研究工作, 在高效合成多孔(笼)材料并将其用于绿色催化、复合团簇仿生催化、仿生通道等领域取得了一系列研究成果. 迄今在Nature、Nat. Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Chem. Soc. Rev.、Acc. Chem. Res.、Acc. Mater. Res.、CCS Chem.等国际著名期刊杂志发表SCI论文70余篇, 多篇入选ESI高被引论文.

基金资助:
国家自然科学基金(22471018); 国家自然科学基金(22071008)

Advances in Porous Organic Cages for Energy Conversion and Storage

Yuqi Cui, Junyu Li, Jianke Sun^*()

Key Laboratory of Cluster Science, Ministry of Education of China, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 102488

Received:2025-03-28 Published:2025-05-15
Contact: *E-mail: jiankesun@bit.edu.cn
About author:
^†These authors contributed equally to this work
Supported by:
National Natural Science Foundation of China(22471018); National Natural Science Foundation of China(22071008)

The national transition toward sustainable energy solutions necessitates the development of advanced materials and technologies for efficient energy conversion and storage. Addressing this demand requires innovative approaches to overcome existing limitations in energy systems, including the need for high-capacity storage, rapid charge transfer, and long term stability. In this context, research on innovative energy storage carriers and mass/charge transfer mechanisms has become a pivotal focus at the forefront of materials science and energy technology. Porous organic cages (POCs), a unique class of low crystalline density porous materials, have attracted significant interest due to their well-defined molecular structures, discrete nanopore cavities and high porosity. These properties make them highly effective for applications in gas adsorption/separation and catalysis. Unlike traditional extended framework materials such as metal organic frameworks (MOFs) or covalent organic frameworks (COFs), POCs are discrete and solution-processable molecules that offer superior solubility and structural tunability, which can be easily designed as various functional composites, broadening their applicability in emerging energy technologies. A particularly promising avenue for POCs lies in energy conversion and storage. Recent studies have demonstrated that functionalized POCs can serve as efficient charge transport materials, facilitating electron and ion movement in energy storage applications. Despite their immense potential, several challenges must be addressed before POCs can be widely adopted in commercial energy technologies. Key challenges include improving the scalability of POC synthesis, optimizing their stability under operational conditions, and enhancing their conductivity for broader energy applications. Furthermore, fundamental research is needed to better understand the charge transport mechanisms within POC-based materials, which will be crucial for advancing their practical implementation. This review provides a comprehensive overview of the design and synthesis strategies of POCs, summarizes recent advancements in their energy-related applications, and discusses the challenges and future research directions in the field. By offering theoretical insights into the strategic development of POCs for energy conversion and storage, this work aims to drive further innovation in sustainable energy technologies, contributing to the ongoing efforts to address global energy challenges.

Key words: porous organic cage, synthesis, photocatalysis, electrocatalysis, energy storage and conversion

Cite this article

Yuqi Cui, Junyu Li, Jianke Sun. Advances in Porous Organic Cages for Energy Conversion and Storage[J]. Acta Chimica Sinica, 2025, 83(6): 624-638.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 10

Figure 1. (a) The chemical structure of D3h-organic cage Cage-2[24]. Copyright 2007 The American Chemical Society. (b) The chemical structure of quadrangular prismatic TPE-based cage Cage-3[25]. (c) The synthesis of tetragonal prismatic porphyrin cage TPPCage8＋[27]. Copyright 2018 The American Chemical Society

Figure 2. (a) The synthesis of cuboctahedral [12＋8] cages Cage-6a/b[38]. Copyright 2014 Wiley-VCH. (b) The synthesis of giant boronic ester cage Cage-7[39]. Copyright 2021 Wiley-VCH. (c) The synthesis of rectangular prismatic cage COP-5[42]. Copyright 2011 The American Chemical Society

Figure 3. (a) The synthesis of octahedral cage Cd6La12[48]. Copyright 2011 The Royal Society of Chemistry. (b) The synthesis of [12＋8] organic cage Cage-9[49]. Copyright 2013 The Royal Society of Chemistry. (c) The synthesis of [4＋4] organic cage Cage-12[52]. Copyright 2018 Wiley-VCH. (d) Structure diagram of CC1, CC2 and CC3 determined by X-ray crystallography[45]. (e) The synthesis of organic cages Cage-11a/b[51]

Figure 4. (a) Schematic illustration of the construction of PdNPs@C4R/g-C3N4 composite for photocatalytic hydrogen evolution. (b) The comparison of H2 production for g-C3N4 with different Pd NP loading amounts. (c) The comparison of photocatalytic hydrogen evolution rate for different catalysts[56]. Copyright 2020 The American Chemical Society

Figure 5. (a) Photo-isomers of the photochromic organic cage TAE-DTE[64]. (b) The photocatalytic CO2 reduction performance of TAE-DTE-O under visible light (left) and full range light (right)[64]. Copyright 2021 The Royal Society of Chemistry. (c) The design strategy of catalyst FePB-2(P)[66]. (d) The catalytic activity of FePB-2(P) in CO2-saturated CH3CN[66]. (e) TON per[Fe] comparison of photocatalytic CO2RR for different catalysts in CO2-saturated DMF[66]. Copyright 2022 Wiley-VCH

Figure 6. (a) Schematic diagram of the flow-cell. (b) The comparison of current density between Cu-nr/CC3 and Cu-nr at different potentials. (c) The FE of C2＋ products and (d) H2 at different potentials over Cu-nr/CC3 and Cu-nr. (e) Comparison of FE of products over different catalysts at －0.9 V potential[69]. Copyright 2022 Wiley-VCH

Figure 7. (a) The schematic diagram of Au clusters introducing porphyrin cages to regulate ROS. (b) The yield of CEES oxidation comparison of Au⊂TPPCage•Cl and TPPCage•Cl. (c) Schematic illustration of the dual catalytic functionality of Au⊂TPPCage•POM. (d) The yield of DECP hydrolysis comparison of Au⊂TPPCage•POM and K8[Nb6O19][74]. Copyright 2024 Science China Press

Figure 8. (a) The synthetic procedure of the porous cage electrolyte Li-RCC1-ClO4 from RCC1-Cl[14]. (b) Ion conductivity of the Li-RCC1-ClO4 SSE with different LiClO4 contents[14]. (c) The LSV results comparison of PEO-LiClO4 and PEO/Li-RCC1-ClO4[14]. Copyright 2022 Springer Nature. (d) The guest-host structure of C60@POC[82]. (e) Charge/discharge curves of C60@POC with/without irradiation[82]. (f) The Nyquist plots comparison of POC and C60@POC with/without irradiation[82]. Copyright 2022 The Royal Society of Chemistry

Figure 9. (a) The encapsulation procedure of ⅡC-1@Na2S5[87]. (b) The rate performance and (c) cycling performance and coulombic efficiency for ⅡC-1@Na2S5 LSB[87]. Copyright 2022 Elsevier. (d) The comparison of the Li＋ and polysulfide ion sieving selectivity and cycling performance of batteries equipped with CC3/PP and bare PP separators at 1 C over 500 cycles[86]. (e) Rate performance at various C-rates for CC3/PP and PP[86]. Copyright 2022 The American Chemical Society

Figure 10. (a) Structure diagram based on protonated molecular cage salt proton conductor[94]. (b) The schematic illustration of preparation of the Nafion-Cage 3 composite membrane[96]. Copyright 2018 The American Chemical Society

References 99

[1]	Chu, S.; Majumdar, A. Nature 2012, 488, 294.
[2]	Liu, C.; Li, F.; Ma, L. P.; Cheng, H. M. Adv. Mater. 2010, 22, E28.
[3]	Reddy, A. L. M.; Gowda, S. R.; Shaijumon, M. M.; Ajayan, P. M. Adv. Mater. 2012, 24, 5045.
[4]	Gebresilassie Eshetu, G.; Armand, M.; Scrosati, B.; Passerini, S. Angew. Chem., Int. Ed. 2014, 53, 13342. doi: 10.1002/anie.201405910 pmid: 25303401
[5]	Peng, Z. K.; Ding, H. M.; Chen, R. F.; Gao, C.; Wang, C. Acta Chim. Sinica 2019, 77, 681 (in Chinese).
	(彭正康, 丁慧敏, 陈如凡, 高超, 汪成, 化学学报, 2019, 77, 681.) doi: 10.6023/A19040118
[6]	Mastalerz, M. Acc. Chem. Res. 2018, 51, 2411.
[7]	Cui, J. W.; Liu, S. H.; Tan, L. X.; Sun, J. K. Acc. Mater. Res. 2025, https://doi.org/10.1021/accountsmr.4c00402
[8]	Zhang, S. Y.; Kochovski, Z.; Lee, H. C.; Lu, Y.; Zhang, H.; Zhang, J.; Sun, J. K.; Yuan, J. Y. Chem. Sci. 2019, 10, 1450. doi: 10.1039/c8sc04375b pmid: 30809362
[9]	Li, J. Y.; Yang, X. D.; Chen, F. X.; Sun, J. K. Mater. Chem. Front. 2023, 7, 5355.
[10]	Chen, J. L.; Ma, Z. H.; Li, Y. F.; Cao, S. W.; Zhuang, Q. Chin. J. Org. Chem. 2023, 43, 120 (in Chinese).
	(陈嘉麟, 马郅蘅, 李禹沣, 曹思炜, 庄强, 有机化学, 2023, 43, 120.) doi: 10.6023/cjoc202207020
[11]	Wilms, M.; Melendez, L. V.; Hudson, R. J.; Hall, C. R.; Ratnayake, S. P.; Smith, T.; Gaspera, E. D.; Bryant, G.; Connell, T. U.; Gómez, D. E. Angew. Chem., Int. Ed. 2023, 62, e202303501.
[12]	Lu, Z. Y.; Lu, X. T.; Zhong, Y. H.; Hu, Y. F.; Li, G. K.; Zhang, R. K. Anal. Chim. Acta 2019, 1050, 146.
[13]	Tan, L. X.; Zhou, J. H.; Sun, J. K.; Yuan, J. Y. Nat. Commun. 2022, 13, 1471.
[14]	Li, J.; Qi, J.; Jin, F.; Zhang, F.; Zheng, L.; Tang, L.; Huang, R.; Xu, J.; Chen, H.; Liu, M.; Qiu, Y.; Cooper, A. I.; Shen, Y.; Chen, L. Nat. Commun. 2022, 13, 2031.
[15]	Liu, S. H.; Zhao, K.; Zhou, J. H.; Dong, K.; Ai, H.; Liu, P.; Cui, J. W.; Zhang, Y. H.; Puigmartí-Luis, J.; Sun, J. K. Angew. Chem., Int. Ed. 2025, 64, e202421523.
[16]	Jin, Y. H.; Voss, B. A.; Jin, A.; Long, H.; Noble, R. D.; Zhang, W. J. Am. Chem. Soc. 2011, 133, 6650.
[17]	Chen, L.; Reiss, P. S.; Chong, S. Y.; Holden, D.; Jelfs, K. E.; Hasell, T.; Little, M. A.; Kewley, A.; Briggs, M. E.; Stephenson, A.; Thomas, K. M.; Armstrong, J. A.; Bell, J.; Busto, J.; Noel, R.; Liu, J.; Strachan, D. M.; Thallapally, P. K.; Cooper, A. I. Nat. Mater. 2014, 13, 954.
[18]	Xu, T. T.; Wu, B.; Hou, L. X.; Zhu, Y. R.; Sheng, F. M.; Zhao, Z.; Dong, Y.; Liu, J. D.; Ye, B. J.; Li, X. Y.; Ge, L.; Wang, H. T.; Xu, T. W. J. Am. Chem. Soc. 2022, 144, 10220.
[19]	Liu, S. H.; Zhou, J. H.; Wu, C.; Zhang, P.; Cao, X.; Sun, J. K. Nat. Commun. 2024, 15, 2478.
[20]	Yang, X. C.; Sun, J. K.; Kitta, M.; Pang, H.; Xu, Q. Nat. Catal. 2018, 1, 214.
[21]	Giri, N.; Del Pópolo, M. G.; Melaugh, G.; Greenaway, R. L.; Rätzke, K.; Koschine, T.; Pison, L.; Gomes, M. F. C.; Cooper, A. I.; James, S. L. Nature 2015, 527, 216.
[22]	Wu, Z. Y.; Lee, S.; Moore, J. S. J. Am. Chem. Soc. 1992, 114, 8730.
[23]	Gu, X.; Gopalakrishna, T. Y.; Phan, H.; Ni, Y.; Herng, T. S.; Ding, J.; Wu, J. S. Angew. Chem., Int. Ed. 2017, 56, 15383.
[24]	Zhang, C.; Chen, C. F. J. Org. Chem. 2007, 72, 9339. pmid: 17958375
[25]	Zhang, C.; Wang, Z.; Tan, L. X.; Zhai, T. L.; Wang, S.; Tan, B. E.; Zheng, Y. S.; Yang, X. L.; Xu, H. B. Angew. Chem., Int. Ed. 2015, 54, 9244. doi: 10.1002/anie.201502912 pmid: 26089125
[26]	Dale, E. J.; Vermeulen, N. A.; Thomas, A. A.; Barnes, J. C.; Juríček, M.; Blackburn, A. K.; Strutt, N. L.; Sarjeant, A. A.; Stern, C. L.; Denmark, S. E.; Stoddart, J. F. J. Am. Chem. Soc. 2014, 136, 10669.
[27]	Shi, Y.; Cai, K.; Xiao, H.; Liu, Z. C.; Zhou, J. W.; Shen, D. K.; Qiu, Y. Y.; Guo, Q. H.; Stern, C.; Wasielewski, M. R.; Diederich, F.; Goddard, W. A.; Stoddart, J. F. J. Am. Chem. Soc. 2018, 140, 13835. doi: 10.1021/jacs.8b08555 pmid: 30265801
[28]	Belser, P.; Cola, L. D.; Zelewsky, A. v. J. Chem. Soc., Chem. Commun. 1988, 1057.
[29]	McMurry, T. J.; Hosseini, M. W.; Garrett, T. M.; Hahn, F. E.; Zelideth, E. Reyes; Raymond, K. N. J. Am. Chem. Soc. 1987, 109, 7196.
[30]	Bhat, A. S.; Elbert, S. M.; Zhang, W. S.; Rominger, F.; Dieckmann, M.; Schröder, R. R.; Mastalerz, M. Angew. Chem., Int. Ed. 2019, 58, 8819.
[31]	Zhang, L.; Jin, Y.; Tao, G. H.; Gong, Y.; Hu, Y.; He, L.; Zhang, W. Angew. Chem., Int. Ed. 2020, 59, 20846.
[32]	Jelfs, K. E.; Wu, X.; Schmidtmann, M.; Jones, J. T. A.; Warren, J. E.; Adams, D. J.; Cooper, A. I. Angew. Chem., Int. Ed. 2011, 50, 10653. doi: 10.1002/anie.201105104 pmid: 21928449
[33]	Ono, K.; Johmoto, K.; Yasuda, N.; Uekusa, H.; Fujii, S.; Kiguchi, M.; Iwasawa, N. J. Am. Chem. Soc. 2015, 137, 7015.
[34]	Wang, Q.; Yu, C.; Zhang, C. X.; Long, H.; Azarnoush, S.; Jin, Y. H.; Zhang, W. Chem. Sci. 2016, 7, 3370. doi: 10.1039/c5sc04977f pmid: 29997831
[35]	Wang, Q.; Zhang, C. X.; Noll, B. C.; Long, H.; Jin, Y. H.; Zhang, W. Angew. Chem., Int. Ed. 2014, 53, 10663. doi: 10.1002/anie.201404880 pmid: 25146457
[36]	Lee, S.; Yang, A.; Moneypenny, T. P.; Moore, J. S. J. Am. Chem. Soc. 2016, 138, 2182.
[37]	Kataoka, K.; James, T. D.; Kubo, Y. J. Am. Chem. Soc. 2007, 129, 15126.
[38]	Zhang, G.; Presly, O.; White, F.; Oppel, I. M.; Mastalerz, M. Angew. Chem., Int. Ed. 2014, 53, 1516. doi: 10.1002/anie.201308924 pmid: 24403008
[39]	Hähsler, M.; Mastalerz, M. Chem. - Eur. J. 2021, 27, 233.
[40]	Inomata, T.; Konishi, K. Chem. Commun. 2003, 1282.
[41]	Taesch, J.; Heitz, V.; Topić, F.; Rissanen, K. Chem. Commun. 2012, 48, 5118.
[42]	Zhang, C. X.; Wang, Q.; Long, H.; Zhang, W. J. Am. Chem. Soc. 2011, 133, 20995.
[43]	Quan, M. L. C.; Cram, D. J. J. Am. Chem. Soc. 1991, 113, 2754.
[44]	Skowronek, P.; Gawronski, J. Org. Lett. 2008, 10, 4755. doi: 10.1021/ol801702j pmid: 18837551
[45]	Tozawa, T.; Jones, J. T.; Swamy, S. I.; Jiang, S.; Adams, D. J.; Shakespeare, S.; Clowes, R.; Bradshaw, D.; Hasell, T.; Chong, S. Y.; Tang, C.; Thompson, S.; Parker, J.; Trewin, A.; Bacsa, J.; Slawin, A. M.; Steiner, A.; Cooper, A. I. Nat. Mater. 2009, 8, 973.
[46]	Mastalerz, M. Chem. Commun. 2008, 4756.
[47]	Tian, J.; Thallapally, P. K.; Dalgarno, S. J.; McGrail, P. B.; Atwood, J. L. Angew. Chem., Int. Ed. 2009, 48, 5492.
[48]	Sun, J. L.; Warmuth, R. Chem. Commun. 2011, 47, 9351.
[49]	Skowronek, P.; Warżajtis, B.; Rychlewska, U.; Gawroński, J. Chem. Commun. 2013, 49, 2524.
[50]	Schneider, M. W.; Hauswald, S.; Hans-Jochen; Stoll, R.; Mastalerz, M. Chem. Commun. 2012, 48, 9861.
[51]	Schneider, M. W.; Oppel, I. M.; Mastalerz, M. Chem. - Eur. J. 2012, 18, 4156.
[52]	Lauer, J. C.; Zhang, W. S.; Rominger, F.; Schroder, R. R.; Mastalerz, M. Chem. - Eur. J. 2018, 24, 1816.
[53]	An, P.; Zhang, Q. H.; Yang, Z.; Wu, J. X.; Zhang, J. Y.; Wang, Y. J.; Li, Y. M.; Jiang, G. Y. Acta Chim. Sinica 2022, 80, 1629 (in Chinese).
	(安攀, 张庆慧, 杨状, 武佳星, 张佳颖, 王雅君, 李宇明, 姜桂元, 化学学报, 2022, 80, 1629.) doi: 10.6023/A22080362
[54]	Sun, P. P.; Zhang, J. Y.; Song, Y. H.; Mo, Z.; Chen, Z. G.; Xu, H. Acta Phys.-Chim. Sin. 2024, 40, 2311001.
[55]	Strmcnik, D.; Lopes, P. P.; Genorio, B.; Stamenkovic, V. R.; Markovic, N. M. Nano Energy 2016, 29, 29.
[56]	Zhang, J. H.; Wei, M. J.; Lu, Y. L.; Wei, Z. W.; Wang, H. P.; Pan, M. ACS Appl. Energy Mater. 2020, 3, 12108.
[57]	You, B.; Sun, Y. Acc. Chem. Res. 2018, 51, 1571.
[58]	Smith, P. T.; Benke, B. P.; An, L.; Kim, Y.; Kim, K.; Chang, C. J. ChemElectroChem 2021, 8, 1653.
[59]	Zhao, C. X.; Liu, J. N.; Wang, J.; Ren, D.; Li, B. Q.; Zhang, Q. Chem. Soc. Rev. 2021, 50, 7745.
[60]	Smith, P. T.; Kim, Y.; Benke, B. P.; Kim, K.; Chang, C. J. Angew. Chem., Int. Ed. 2020, 59, 4902.
[61]	Qin, L. B.; Sun, F.; Li, M. Y.; Fan, H.; Wang, L. K.; Tang, Q.; Wang, C. D.; Tang, Z. H. Acta Phys. -Chim. Sin. 2025, 41, 100008 (in Chinese).
	(秦露冰, 孙芳, 李美银, 范浩, 王立开, 唐青, 王春栋, 唐正华, 物理化学学报, 2025, 41, 100008.)
[62]	An, L.; Narouz, M. R.; Smith, P. T.; De La Torre, P.; Chang, C. J. Angew. Chem., Int. Ed. 2023, 62, e202305719.
[63]	Chen, H. Y.; Zhu, H. L.; Liao, P. Q.; Chen, X. M. Acta Phys.-Chim. Sin. 2024, 40, 2306046 (in Chinese).
	(陈慧滢, 朱浩林, 廖培钦, 陈小明, 物理化学学报, 2024, 40, 2306046.)
[64]	Singh, A.; Verma, P.; Samanta, D.; Dey, A.; Dey, J.; Maji, T. K. J. Mater. Chem. A 2021, 9, 5780.
[65]	Li, H.; Geng, L. F.; Si, S. H.; Cheng, H. F.; Yang, Z. J.; Wei, J. J. Chem. Eng. J. 2023, 474, 145431.
[66]	An, L.; De La Torre, P.; Smith, P. T.; Narouz, M. R.; Chang, C. J. Angew. Chem., Int. Ed. 2023, 62, e202209396.
[67]	Hu, Y. M.; Huang, S.; Wayment, L. J.; Wu, J. Y.; Xu, Q. C.; Chang, T. Y.; Chen, Y. P.; Li, X. N.; Andi, B.; Chen, H. X.; Jin, Y. H.; Zhu, H.; Du, M. L.; Lu, S. L.; Zhang, W. Cell Rep. Phys. Sci. 2023, 4, 101285.
[68]	Liu, X.; Liu, C.; Song, X.; Ding, X.; Wang, H.; Yu, B.; Liu, H.; Han, B.; Li, X.; Jiang, J. Chem. Sci. 2023, 14, 9086.
[69]	Chen, C.; Yan, X.; Wu, Y.; Liu, S.; Zhang, X.; Sun, X.; Zhu, Q.; Wu, H.; Han, B. Angew. Chem., Int. Ed. 2022, 61, e202202607.
[70]	Sun, N.; Wang, C.; Wang, H.; Yang, L.; Jin, P.; Zhang, W.; Jiang, J. Angew. Chem., Int. Ed. 2019, 58, 18011.
[71]	Sun, N. N.; Qi, D. D.; Jin, Y. C.; Wang, H. L.; Wang, C. M.; Qu, C.; Liu, J. M.; Jin, Y. H.; Zhang, W.; Jiang, J. Z. CCS Chem. 2022, 4, 2588.
[72]	Li, C.; Cui, J. W.; Zhou, J. H.; Xu, Y. Q.; Sun, J. K. Catal. Sci. Technol. 2024, 14, 1558.
[73]	Zhang, F.; Ma, J.; Tan, Y.; Yu, G.; Qin, H. X.; Zheng, L. R.; Liu, H. B.; Li, R. ACS Catal. 2022, 12, 5827.
[74]	Cui, J. W.; Li, C.; Zhao, K.; Liu, S. H.; Zhao, X. J.; Wu, Y.; Li, D.; Sun, J. K. Sci. China: Chem. 2024, 67, https://doi.org/10.1007/s11426-024-2396-9.
[75]	Armand, M.; Tarascon, J. M. Nat. Rev. Mater. 2008, 451, 652.
[76]	Tarascon, J. M.; Armand, M. Nat. Rev. Mater. 2001, 414, 359.
[77]	Manthiram, A.; Yu, X. W.; Wang, S. F. Nat. Rev. Mater. 2017, 2, 16103.
[78]	Bruce, P. G.; Scrosati, B.; Tarascon, J. M. Angew. Chem., Int. Ed. 2008, 47, 2930.
[79]	Rojaee, R.; Shahbazian Yassar, R. ACS Nano 2020, 14, 2628. doi: 10.1021/acsnano.9b08396 pmid: 32083832
[80]	Bera, S.; Goujon, N.; Melle Franco, M.; Mecerreyes, D.; Mateo Alonso, A. Chem. Sci. 2024, 15, 14872.
[81]	Petronico, A.; Moneypenny, T. P., 2nd; Nicolau, B. G.; Moore, J. S.; Nuzzo, R. G.; Gewirth, A. A. J. Am. Chem. Soc. 2018, 140, 7504. doi: 10.1021/jacs.8b00886 pmid: 29860840
[82]	Zhang, X.; Su, K. Z.; Mohamed, A. G. A.; Liu, C. P.; Sun, Q. F.; Yuan, D. Q.; Wang, Y. M.; Xue, W. H.; Wang, Y. B. Energy Environ. Sci. 2022, 15, 780.
[83]	Zhu, G.; Tian, X.; Tai, H. C.; Li, Y. Y.; Li, J.; Sun, H.; Liang, P.; Angell, M.; Huang, C. L.; Ku, C. S.; Hung, W. H.; Jiang, S. K.; Meng, Y.; Chen, H.; Lin, M. C.; Hwang, B. J.; Dai, H. Nature 2021, 596, 525.
[84]	He, J. W.; Jiao, L.; Cheng, X. Y.; Chen, G. H.; Wu, Q.; Wang, X. Z.; Yang, L. J.; Hu, Z. Acta Chim. Sinica 2022, 80, 896 (in Chinese).
	(何家伟, 焦柳, 程雪怡, 陈光海, 吴强, 王喜章, 杨立军, 胡征, 化学学报, 2022, 80, 896.) doi: 10.6023/A22030117
[85]	Xu, Y.; Zhang, S.; Wang, M.; Meng, Y.; Xie, Z.; Sun, L.; Huang, C.; Chen, W. J. Am. Chem. Soc. 2023, 145, 27877.
[86]	Li, H.; Huang, Y.; Zhang, Y.; Zhang, X.; Zhao, L.; Bao, W.; Cai, X.; Zhang, K.; Zhao, H.; Yi, B.; Su, L.; Cheetham, A. K.; Jiang, S.; Xie, J. Nano Lett. 2022, 22, 2030.
[87]	Zhang, L.; Jia, Y.; Meng, F. S.; Sun, L.; Cheng, F.; Shi, Z. Q.; Jiang, R. Y.; Song, X. Y. J. Alloys Compd. 2022, 923, 166488.
[88]	Rong, Y.; Hu, Y.; Mei, A.; Tan, H.; Saidaminov, M. I.; Seok, S. I.; McGehee, M. D.; Sargent, E. H.; Han, H. Science 2018, 361, eaat8235.
[89]	Yang, Y.; Lin, F. Y.; Zhu, C. T.; Chen, T.; Ma, S. P.; Luo, Y.; Zhu, L.; Guo, X. Y. Acta Chim. Sinica 2020, 78, 217 (in Chinese). doi: 10.6023/A19110411
	(杨英, 林飞宇, 朱从潭, 陈甜, 马书鹏, 罗媛, 朱刘, 郭学益, 化学学报, 2020, 78, 217.) doi: 10.6023/A19110411
[90]	Kim, H. S.; Seo, J. Y.; Park, N. G. ChemSusChem 2016, 9, 2528.
[91]	Gao, F.; Luo, C.; Wang, X. J.; Zhan, C. L.; Li, Y.; Li, Y. M.; Meng, Q. B.; Yang, M.; Su, K. Z.; Yuan, D. Q.; Zhu, R.; Zhao, Q. Adv. Funct. Mater. 2023, 33, 2211900.
[92]	Jiao, K.; Xuan, J.; Du, Q.; Bao, Z.; Xie, B.; Wang, B.; Zhao, Y.; Fan, L.; Wang, H.; Hou, Z.; Huo, S.; Brandon, N. P.; Yin, Y.; Guiver, M. D. Nature 2021, 595, 361.
[93]	Wang, A. L.; Sun, Y.; Liang, Z. X.; Chen, S. L. Acta Chim. Sinica 2009, 67, 2554 (in Chinese).
	(王爱丽, 孙瑜, 梁志修, 陈胜利, 化学学报, 2009, 67, 2554.)
[94]	Liu, M.; Chen, L.; Lewis, S.; Chong, S. Y.; Little, M. A.; Hasell, T.; Aldous, I. M.; Brown, C. M.; Smith, M. W.; Morrison, C. A.; Hardwick, L. J.; Cooper, A. I. Nat. Commun. 2016, 7, 12750.
[95]	Yang, Z.; Zhang, N.; Lei, L.; Yu, C.; Ding, J.; Li, P.; Chen, J.; Li, M.; Ling, S.; Zhuang, X.; Zhang, S. JACS Au 2022, 2, 819.
[96]	Han, R.; Wu, P. ACS Appl. Mater. Interfaces 2018, 10, 18351.
[97]	Sun, J. K.; Sobolev, Y. I.; Zhang, W. Y.; Zhuang, Q.; Grzybowski, B. A. Nature 2020, 579, 73.
[98]	Zhang, S. Y.; Miao, H.; Zhang, H. M.; Zhou, J. H.; Zhuang, Q.; Zeng, Y. J.; Gao, Z. M.; Yuan, J. Y.; Sun, J. K. Angew. Chem. Int. Ed. 2020, 59, 22109.
[99]	Tan, L. X.; Ren, S. Y.; Sun, J. K. J. Solid State Chem. 2024, 333, 124605.

多孔有机笼用于能源转换及储存的研究进展

Advances in Porous Organic Cages for Energy Conversion and Storage

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 10

References 99

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yanjun Wang, Ruixin Wang, Puxi Yang, Huizhi Chen, Defu Guo, Guangpeng Gao, Xiaofang Li. Research on the Synthesis, Structure and Interactions with Acid of Novel Calixfuran Macrocycle [J]. Acta Chimica Sinica, 2025, 83(6): 588-595.
[2]	Yiliang Zhang, Weilong Wu, Wenlei Xu, Yuqin Fu, Hui Guo, Zhiqiang Lu. Click-Inspired Functionalization of Glycans: Rational Design and Efficient Synthesis of C3-OH Specific Derivatives [J]. Acta Chimica Sinica, 2025, 83(5): 445-452.
[3]	Xue Yang, Yanling Liu, Xia Chen, Xiaoyu Zhou, Ailing Wang, Hailong Liu. Oxalyl Monoamide Ligand-Promoted Palladium-Catalyzed Suzuki Coupling Reactions in Aqueous Media at Low Doses [J]. Acta Chimica Sinica, 2025, 83(4): 354-359.
[4]	Qianyao Yu, Ming Meng, Jingfang Yao, Shanshan Du, Yunkun Qi. Two Step Synthesis of Octreotide-doxorubicin Conjugates Based on Disulfide Bond Linker [J]. Acta Chimica Sinica, 2025, 83(4): 341-353.
[5]	Lingling Ma, Lin Ling, Yaming Wu, Yuxue Li, Long Lu. Theoretical Study on the Mechanism of Continuous Preparation of 1,3,5-Triethory-2,4,6-Trinitrobenzene [J]. Acta Chimica Sinica, 2025, 83(4): 360-368.
[6]	Yingqi Wang, Jiayi Chang, Min Li, Hong Liang, Zhiheng Li, Wenfu Xie, Qiang Wang. Photoelectrocatalytic Urea Synthesis via co-Reduction of CO₂ and $NO_{2}^{-}$ over Metallic Surface Modified TiO₂ [J]. Acta Chimica Sinica, 2025, 83(3): 247-255.
[7]	Guokai Li, Binfeng Zhu, Tao Hu, Ruifeng Fan, Weiqing Sun, Zhenxiu He, Jingchao Chen, Baomin Fan. Photoredox Dealkylative Acylation of Tertiary Amines [J]. Acta Chimica Sinica, 2025, 83(3): 199-205.
[8]	Guowei Hu, Xiaohuan Wang, Zhipeng Yuan, Yaer Xinba, Hexige Wuliji. Effect of Ag Doping on the Photocatalytic Performance of Bismuth Ferrite-based Compounds [J]. Acta Chimica Sinica, 2025, 83(3): 229-236.
[9]	Yu Zhang, Rui Zhang, Zijian Wang, Xiao Wang, Shuyan Song, Hongjie Zhang. Current Advances of Solid Acid Catalysts [J]. Acta Chimica Sinica, 2025, 83(2): 152-169.
[10]	Jian Kang, Zixuan Shi, Jingmei Li. Preparation of Highly Antimicrobial Composites and Study of Photocatalytic Antimicrobial Properties Driven by LED Light [J]. Acta Chimica Sinica, 2024, 82(9): 962-970.
[11]	Yunusi Reziguli, Abuduwaili Kadierya, Shiwei Luo, Abudu Rexit Abulikemu. Synthesis of N-Benzylidene Benzylamine from Dibenzylamine and Derivatization under Electrochemical Conditions [J]. Acta Chimica Sinica, 2024, 82(8): 843-848.
[12]	Yi Li, Beibei Weng, Jingwen Zhao, Ran Du. Controlled Synthesis of Noble Metal Aerogels and Their Applications in Electrocatalysis and Surface-Enhanced Raman Scattering [J]. Acta Chimica Sinica, 2024, 82(7): 805-818.
[13]	Kangkui Li, Xianyang Long, Yue Huang, Shifa Zhu. Recent Advances in Visible Light Induced Radical 1,2-Functionalization of Alkynes [J]. Acta Chimica Sinica, 2024, 82(6): 658-676.
[14]	Haoning Zheng, Jinyu Liu. Research Progress on Organocatalytic Functionalization of Indole in the Carbocyclic Ring [J]. Acta Chimica Sinica, 2024, 82(6): 641-657.
[15]	Nannan Wang, Yuzhen Chen. CoNi-MOF-74/NF Derived CoNi@C/NF Hybrid for Efficient Electrosynthesis of Organics [J]. Acta Chimica Sinica, 2024, 82(6): 621-628.