Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications★

doi:10.6023/A26060211

Acta Chimica Sinica ›› 2026, Vol. 84 ›› Issue (8): 1326-1342.DOI: 10.6023/A26060211 Previous Articles Next Articles

Review

稀土配合物功能材料: 从分子设计和性能调控到前沿应用^★

宋福嘉^a, 苏平如^a, 唐瑜^a^,^b^,^*()

^a 兰州大学化学化工学院稀土功能材料教育部工程研究中心稀土功能材料教育部工程研究中心兰州 730000
^b 白云鄂博稀土资源研究与综合利用全国重点实验室包头稀土研究院包头 014030

投稿日期:2026-06-20 发布日期:2026-07-30
通讯作者: 唐瑜

作者简介:

宋福嘉, 兰州大学化学化工学院2025级博士研究生, 师从唐瑜教授. 主要研究兴趣为手性超分子组装体的构建及手性传递.

苏平如, 兰州大学青年研究员, 硕士生导师. 2020 年 12 月毕业于兰州大学无机化学专业, 获理学博士学位, 导师唐瑜教授; 2021 至 2023 年, 在深圳大学李霄鹏教授课题组从事博士后工作; 2023 年 8 月加入兰州大学化学化工学院, 从事无机化学教学科研工作. 研究方向为稀土配合物自组装及其应用.

唐瑜, 兰州大学二级萃英学者, 博士生导师. 教育部长江学者特聘教授, 国家高层次人才特支计划教学名师, 基金委稀土功能材料创新研究群体负责人, 中国化学会会士, 英国皇家化学会会士, 国务院政府特殊津贴专家. 兼任国务院学位委员会第八届化学学科评议组成员, 中国化学会副秘书长, 中国化学会无机化学学科委员会、科普工作委员会、女化学工作者委员会委员; Aggregate期刊顾问编委, Inorg. Chem. 副主编, Inorg. Chem. Front.、《中国稀土学报》(中、英文版) 、《高等学校化学学报》(中英文版)、《无机化学学报》和《结构化学》等期刊编委. 近期的研究工作主要集中在稀土配位化学和功能材料研究, 主持国家自然科学基金创新研究群体项目、重点项目和面上项目, 111 引智基地项目, 甘肃省重大专项、重点研发计划和企业合作项目等研究课题. 以通讯作者或第一作者在 Chem. Soc. Rev.、Acc. Chem. Res.、Natl. Sci. Rev.、CCS Chem.、Angew. Chem. Int. Ed.、J. Am. Chem. Soc.、Energy Environ. Sci.、Adv. Mater.、ACS Nano 和 Sci. China Chem. 等刊物发表论文 200 余篇.

^★For the VSI “Celebration of 80th Anniversary of Chemistry in Lanzhou University”

基金资助:
国家自然科学基金(22221001); 国家自然科学基金(22131007); 国家自然科学基金(22401119); 111引智计划项目(B20027); 甘肃省科技计划项目(24ZD13GA015); 甘肃省科技计划项目(23ZDGA012); 甘肃省科技计划项目(26JDRA008); 中央高校基本科研业务费专项资金项目(lzujbky-2025-jdzx13)

Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications^★

Fu-jia Song^a, Pingru Su^a, Yu Tang^a^,^b^,^*()

^a College of Chemistry and Chemical Engineering, Lanzhou University, Engineering Research Center of Rare Earth Functional Materials, Ministry of Education, Lanzhou 730000, China
^b State Key Laboratory of Baiyunobo Rare Earth Resource Researches and Comprehensive Utilization, Baotou Research Institute of Rare Earths, Baotou 014030, China

Received:2026-06-20 Published:2026-07-30
Contact: Yu Tang
About author:
^★“纪念兰州大学化学学科创建80周年”专辑
Supported by:
National Natural Science Foundation of China(22221001); National Natural Science Foundation of China(22131007); National Natural Science Foundation of China(22401119); 111 project(B20027); Science and Technology Program of Gansu Province(24ZD13GA015); Science and Technology Program of Gansu Province(23ZDGA012); Science and Technology Program of Gansu Province(26JDRA008); Fundamental Research Funds for the Central Universities(lzujbky-2025-jdzx13)

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Abstract

Rare earth elements exhibit outstanding optical, electrical, and magnetic properties owing to their unique 4f electronic configuration, and have found widespread applications in fields such as information technology, energy, and healthcare. Rare earth complexes formed by combining rare earth ions with organic ligands integrate the structural characteristics of both components, while offering considerable flexibility in molecular design. Furthermore, their distinctive assembly features enable the cross-scale construction and performance modulation of materials ranging from discrete complex molecules to functional materials, thus representing a crucial pathway toward the efficient utilization of rare earth resources. The rational design of ligands not only facilitates the precise construction of complex structures, but also enables the targeted regulation of their properties, which is of great significance for elucidating structure-property relationships and for developing novel materials for optoelectronics, sensing, catalysis, and energy-related applications. Despite remarkable progress, challenges remain in this field concerning the optimization of synthetic methodologies, the creation of new materials, and the enhancement of stability. This review summarizes the recent research advances made by our group, covering aspects from molecular design and property modulation to application exploration. Emphasis is placed on the precise synthesis and functional regulation achieved through strategies such as coordination-driven self-assembly, in situ coordination, and microstructure evolution, along with the demonstration of these materials in intelligent luminescent and photo-functional materials and devices. Finally, we analyze the opportunities and challenges confronting this field, with the aim of providing a reference for the development of precise synthetic methodologies for rare earth complex-based functional materials.

Key words: rare earth complexes, functional materials, precise synthesis, molecular design, property regulation

Cite this article

Fu-jia Song, Pingru Su, Yu Tang. Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications^★[J]. Acta Chimica Sinica, 2026, 84(8): 1326-1342.

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Fig. & Tab. 17

Figure 1. Schematic representation of precision synthesis and molecular/atomic-scale property modulation of rare-earth complex functional materials, and their applications in smart luminescent materials and light-conversion materials and devices

Figure 2. Synthetic route of EuL1 and its three detection channels

Figure 3. Schematic illustration of the construction strategies and self-assembly processes for (a) the Zn2Er4L24 supramolecular cage; and (b) the Zn4Er6L36 and Zn2Er8L48 supramolecular cages

Figure 4. (a) Schematic illustration of the self-assembly of Eu complexes; (b) SEM image of Eu-NPs; (c, d) TEM images of Eu-NPs; (e) Elemental mapping of Eu-NPs; (f, g) Luminescence spectra of Eu complexes in acetone/water; (h) Luminescence lifetimes of Eu complexes in acetone/D2O or acetone/H2O; (i) Total luminescence quantum yields (Φoverall) and energy transfer efficiencies from the ligand to Eu3+ (Φsen) of Eu complexes in acetone/water with different ratios

Figure 5. Schematic illustration of the hybrid assembly of the Eu-L complex with carbon dots (CDs) and the mechanism of pH-responsive fluorescence modulation

Figure 6. (a) Schematic illustration of [YbL3]3+-mediated self-assembly of CsPbBr3 nanocrystals into ordered three-dimensional cubic superstructures; (b) Negatively charged Ag nanoparticles (Ag-NPs) assemble around positively charged [EuL3]3+ via electrostatic interactions to form Eu/Ag-NPs, which simultaneously enhance fluorescence intensity and Raman signals while modulating luminescence lifetimes. The resulting assemblies are then coated onto a substrate and dried to form random two-dimensional patterns. A confocal fluorescence-Raman combined system is employed to read the PUF tags

Figure 7. (a) Schematic illustration of the methodology for constructing a series of functional materials based on rare-earth complexes; (b) Schematic illustration of the synthesis process of Fe3O4@mSiO2@MOF composites and the mechanism of K+ ion separation; (c) Encapsulation of Eu ions and HPBA into mesoporous silica to obtain SiO2-(Eu2+, Eu3+)-HPBA

Figure 8. (a) Schematic illustration of the assembly of CHOL-A/B into nanoparticles (NPs) and helical nanoribbons (HNRs), respectively; (b) Morphology of the assemblies formed from CHOL-A/B; (c) Schematic illustration of the CPL signal responses of HNRs-Eu and HNRs-Eu(L1)3 to temperature and humidity; (d~g) Fluorescence intensity variations and reversibility of HNRs-Eu and HNRs-Eu(L1)3 under different temperatures and water contents

Figure 9. (a) Schematic illustration of in situ coordination growth of MOF on the surface of nanomaterials; (b) Atomic-scale HAADF-STEM image of CeO2@NiFe-MOFs viewed along the [111] direction of CeO2; (c) Corresponding Fourier transform (FFT) pattern of (b); (d) Projected structural model of CeO2 within CeO2@NiFe-MOFs; (e) Atomic-resolution simulated image after FFT filtering; (f) High-resolution TEM image of CeO2@NiFe-MOFs; (g) Elemental mapping of the CeO₂@NiFe-MOF heterostructure; (h) Possible electron transfer pathways in the CeO2@NiFe-MOF heterostructure during the reaction process; (i) Schematic representation of the synthesis procedure for CeO2/CoS hybrid nanostructures. SEM and TEM images of the CoS precursor (j, m) and of 14.6 % CeO2/CoS (k, n); (l, o) High-resolution TEM images of 14.6 % CeO2/CoS; (p) Elemental mapping of 14.6 % CeO2/CoS

Figure 10. (a) Schematic illustration of the preparation of hollow Ni-Fe-Ce LDH microcapsules assisted by Ce-doped MIL-88A; (b, c) SEM images and (d) TEM image of 30 % Ce-NiFe-LDH microcapsules; (e) HAADF-STEM image of 30 % Ce-NiFe-LDH, and (f, g) HR-TEM images with the corresponding SAED patterns (insets); (h, i) HAADF-STEM images and elemental mapping of a single microcapsule and a magnified region of the microcapsule for 30 % Ce-NiFe-LDH

Figure 11. (a) Schematic illustration of the preparation of Ce1-xTixO2/CeO2; (b, c) SEM images of MOF(Ti) and MOF(Ce)/a-TiO2-0.8, respectively; (d) TEM image of MOF(Ce)/a-TiO2-0.8; (e) HAADF-STEM image and elemental mapping of MOF(Ce)/a-TiO2-0.8; (f) SEM image of CTO/CeO2-0.8; (g) TEM image of CTO/CeO2-0.8; (h) HR-TEM image and the corresponding SAED pattern of CTO/CeO2-0.8; (i) HAADF-STEM image and elemental mapping of CTO/CeO2-0.8; (j) Atomic-scale HAADF-STEM image of the CTO region in CTO/CeO2-0.8; (k) Corresponding FFT pattern of (j); (l) FFT-filtered atomic-resolution simulated image of CTO/CeO2-0.8; (m) Corresponding EDS elemental mapping of the CTO region in CTO/CeO2-0.8

Figure 12. (a) Schematic illustration of the formation of QDs-Eu(PBA)₃AA; (b) Fluorescence images showing dual-responsive optical recording and encryption, including the pattern design process and encryption-decryption mechanism; (c) Schematic illustration of the colorimetric fluorescent time-temperature indicator and its multifunctional applications; (d) Fluorescence images of encrypted information at different temperatures and times; (e) Illustration of text encoding using fluorescent colors

Figure 13. (a) Schematic illustration of the self-assembly of europium complexes into nanoparticles (Eu-NPs) and their co-assembly with dithienylethene into hybrid nanoparticles (Eu/O-DAE-NPs); (b) Schematic representation of the multi-stimuli-responsive properties of Eu-NPs and Eu/O-DAE-NPs; (c) Optical anti-counterfeiting platform based on the multi-stimuli-responsive Eu/DTE-NP system; (d) Schematic diagram of a (PUF) tag

Figure 14. Schematic illustration of the preparation of TPA-OS⊂CP5@CeOx materials and the controlled process of sonodynamic therapy (a) Schematic diagram of the preparation of TPA-OS⊂CP5@CeOx materials; (b) Schematic diagram of in vivo tumor therapy based on dual-organelle targeting and interface engineering-enhanced sonodynamic effects; (c) Chemical structures of CP5 and TPA-OS

Figure 15. (a) Synthesis route of HEAs/CeO2/C; (b) Photocatalytic hydrogen production rates of HEAs(10L)/CeO2/C, Pt/CeO2/C, Pd/CeO2/C, Ni/CeO2/C, Cu/CeO2/C, and Ag/CeO2/C; (c) Photocatalytic water-splitting hydrogen production rates of HEAs(xL)/CeO2/C (x=5, 7.5, 10, 12.5, 15, 20, 25, 30); (d) Photocatalytic hydrogen production stability of HEAs(10L)/CeO2/C

Figure 16. (a) Schematic illustration of rare-earth complexes for enhancing the UV and thermal stability of perovskite solar cells; (b) Schematic diagram of the 2D-3D hybrid perovskite structure and the drop-casting strategy using Eu-pyP to construct a 2D-3D gradient; (c) MAPbI3 thin film stitched with (ZnPc)0.5MAn−1PbnI3n+1 and the chemical structure of (ZnPc)0.5MAn−1PbnI3n+1

Figure 17. (a) Schematic illustration of bandgap engineering of λ-MnO2; (b) Mn PE enabling simultaneous selective lithium-ion capture and freshwater extraction; (c) Photograph of the large-scale prepared Mn PE; (d) Customized expanded evaporation unit

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稀土配合物功能材料: 从分子设计和性能调控到前沿应用^★

Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications^★

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稀土配合物功能材料: 从分子设计和性能调控到前沿应用★

Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications★

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Supporting Info.

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稀土配合物功能材料: 从分子设计和性能调控到前沿应用^★

Rare-Earth Complex Functional Materials: From Molecular Design and Property Modulation to Cutting-Edge Applications^★