Iridium complex catalyzed hydrogen transfer reaction of unsaturated secondary alcohols

Acta Chimica Sinica ›› 1988, Vol. 46 ›› Issue (1): 93-95. Previous Articles Next Articles

Original Articles

铱配合物催化下不饱和仲醇的氢转移反应

林英瑞;马大为;陆熙炎

中国科学院上海有机化学研究所

发布日期:1988-01-15

Iridium complex catalyzed hydrogen transfer reaction of unsaturated secondary alcohols

LIN YINGRUI;MA DAWEI;LU XIYAN

Published:1988-01-15

Abstract

Complex IrH5[(Me2CH)3P]2 is an excellent catalyst for the hydrogen transfer reaction of unsatd. secondary alcs. to give saturated ketones. Thus, EtCOPr was obtained in 89% yield from MeCH:CHCH(OH)Et. The reaction mechanism is briefly discussed.

Key words: CATALYSIS, HYDROGEN, ALCOHOL, ALDEHYDES, TRANSITION METAL COMPLEX, KETONE, IRIDIUM COMPLEX, TRANSFER REACTIONS

CLC Number:

O629

Cite this article

LIN YINGRUI;MA DAWEI;LU XIYAN. Iridium complex catalyzed hydrogen transfer reaction of unsaturated secondary alcohols[J]. Acta Chimica Sinica, 1988, 46(1): 93-95.

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铱配合物催化下不饱和仲醇的氢转移反应

Iridium complex catalyzed hydrogen transfer reaction of unsaturated secondary alcohols

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