Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol

Acta Chimica Sinica ›› 1996, Vol. 54 ›› Issue (10): 988-996. Previous Articles Next Articles

Original Articles

铁邻菲咯啉、8-羟基喹啉配合物/Y型分子筛的制备、表征及催化苯酚羟化的研究

齐兴义;王国甲;叶兴凯;吴越

吉林大学化学系;中国科学院长春应用化学研究所

发布日期:1996-10-15

Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol

QI XINGYI;WANG GUOJIA;YE XINGKAI;WU YUE

Published:1996-10-15

Abstract

Iron phenanthroline-and 8-hydroxyquinoline complexes/Y zeolite, denoted as FePhen/Y and FeOx/Y respectively, were prepared; The formation of the metal complexes mentioned above within the cages of Y zeolite and their crystal structures were determined by elemental analyses, diffuse reflectance UV-Vis, SEM, BET, and XRD methods. The influence of experimental parameters upon phenol conversion and product selectivities were investigated as well.

Key words: ELEMENTAL ANALYSIS, CRYSTAL STRUCTURE, MOLECULAR SIEVE, METAL COMPLEX, HYDROXY QUINOLINES, PHENANTHROLINE, DTA, XRD, SEM, BET ISOTHERM (=BRUNAUER-EMETT-TELLER ISOTHERM)

CLC Number:

O611.662

Cite this article

QI XINGYI;WANG GUOJIA;YE XINGKAI;WU YUE. Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol[J]. Acta Chimica Sinica, 1996, 54(10): 988-996.

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铁邻菲咯啉、8-羟基喹啉配合物/Y型分子筛的制备、表征及催化苯酚羟化的研究

Studies on preparation of iron phenanthroline and 8-hydroxyquinoline complexes/Y zeolite, characterization and catalytic hydroxylation of phenol

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