Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (8): 812-818. Previous Articles     Next Articles

Original Articles

反式9, 10-二氢-9, 10-二苯基-9, 10-菲二醇包结性能的研究

郭文生;朱峰;玉占君;武跃;康文俊;吕扬;郭放;郑启泰   

  1. 辽宁师范大学化学系;佛山科学技术学院化学与化工系;中国医学科学院药物研究所
  • 发布日期:1998-08-15

Study on inclusion phenomena of trans-9, 10-dihydro-9, 10-diphenyl phenanthrene-9, 10-diol as host molecule

GUO WENSHENG;ZHU FENG;YU ZHANJUN;WU YUE;KANG WENJUN;LU YANG;GUO FANG;ZHENG QITAI   

  • Published:1998-08-15

A compound having chela shape, trans-9, 10-dihydro-9, 10-diphenyl phenanthrene-9, 10-diol(1), was synthesized. It could form the inclusion compounds with various small organic molecules such as DMF, DMSO, pyridine, piperidine, quinoline isoquinline. These inclusion compounds were confirmed by means of IR and powder XRD, and their host-guest molar ratio was determined by ^1H NMR. The results of four circle XRD for single crystal of the inclusion compound of the host molecule (1) with DMF shown that the host molecule (1) formed coordinatoclathrate with guest molecules.

Key words: SYNTHESIS, PHENANTHRENE P, X-RAY DIFFRACTION ANALYSIS, TRANSFORM, DIHYDRO-COMPOUNDS, DIPHENYL GROUP, CLATHRATES, CAGE STRUCTURE, DIHYDROXY GROUP, COORDINATION

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