Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (2): 125-131.     Next Articles

Original Articles

Cr/MCM-41催化剂的结构特征及其纳米尺寸孔内聚乙烯的形成

何静;段雪;R.F. Howe   

  1. 北京化工大学应用化学系.北京(100029);Department of Physical Chemistry, The University of New;South Wales, Sydney
  • 发布日期:1999-02-15

Structural characterization of Cr/MCM-41 and polymerization of ethylene within its nanoscale channels

He Jing;Duan Xue;R.F. Howe   

  1. Beijing Univ Chem Technol, Dept Appl Chem.Beijing(100029)
  • Published:1999-02-15

The important characteristics of MCM-41 such as large BET surface area, high porosity, large-diameter channel apertures, controllable and narrowly distributed pore sizes make this material a very promising candidate for catalyst or catalyst support. In this work, the use of MCM-41 as a support for chromium, which is phillips' active site for olefin polymerization, and the potential application of Cr-modified MCM-41 in ethylene polymerization were investigated. The Cr/MCM-41 was characterized by XRD, N2 adsorption, FT-IR, Raman and NMR spectroscory. The XRD and N2 adsorption results showed that Cr/MCM-41 catalysts still possessed long-ordered structures, large surface ares and uniform pore diameters. Chromium species was well dispersed on the surface of MCM-41 until the chromium loading reached 7%. FT-IR and Raman spectra indicated that the well dispersed Cr species was present as isolated at low Cr loading, while as both isolated and polymerized at high loading. NMR spectra suggested Cr species was dispersed on the surface of MCM-41 probably by interacting with the hydroxyls. PE with a certain conformation can be formed within the nanoscale one-dimensional channels of MCM-41 without destroying the pore structure, which seemed to indicate an promising application of MCM-41 in nano-composites. The comparison between Cr/MCM-41 and Cr/SiO2 has also been made.

Key words: MOLECULAR SIEVE, STRUCTURAL BEHAVIOUR, CHROMIUM, CATALYTIC ACTIVITY, POLYETHYLENE, NANOPHASE MATERIALS, CATALYST

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