Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (6): 901-906. Previous Articles     Next Articles

Original Articles

直缘乌头中新的C19—二萜生物碱的结构研究

陈东林;简锡贤;陈巧鸿;王锋鹏   

  1. 四川大学华西药学院天然药化教研室
  • 发布日期:2003-06-15

New C_(19)-Diterpenoid Alkaloids from the Roots of Aconitum transsecutum

Chen Donglin;Jian Xixian;Chen Qiaohong;Wang Fengpeng   

  1. Department of Chemistry of Medicinal Natural Products, West China College of Pharmacy, Sichuan University
  • Published:2003-06-15

Four new C_(19)-diterpenoid alkaloids, 8-O-ethylyunaconitine (1), A^-deethyl chasmanine (2), transconi-tine D (3) and transconitine E (4) , were isolated from the roots of Aconitum, transsectum, Diels. together with 11 known norditerpenoid alkaloids, yunaconitine, indaconitine, vilmorrianine A, vilmorrianine C, crasscualine A, geni- conitine, chasmanine, 8-deacetylyunaconitine, talatisamine, 14- acetyltalatisamine and chasmaconitine. Their structures were assigned on the basis of spectral data (IR, ~1H NMR, ~(13)C NMR, 2D-NMR and MS) .

Key words: aconitum transsectum, DITERPENES, ALKALOID, IR, 1HNMR, C13NMR, 2DNMR, MS

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