Crystal Structure Characteristics of Isomer of Mixed Ligand Complex Cd(Ⅱ)-phenanthroline-malonate

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (16): 1569-1572. Previous Articles Next Articles

混合配体配合物镉(Ⅱ)-邻菲罗啉-丙二酸根异构体的结构特征研究

孙亚光¹, 魏德洲², 高恩君³, 丁茯⁴

1. 东北大学资源与土木工程学院, 沈阳, 110004;
2. 沈阳化工学院配位化学研究室, 沈阳, 110142;
3. 辽宁大学化学科学与工程学院, 沈阳, 110036

投稿日期:2003-09-08 修回日期:2004-04-20 发布日期:2014-02-17
通讯作者: ejgao@yahoo.com.cn
作者简介:高恩君:E-mail:ejgao@yahoo.com.cn
基金资助:
辽宁省自然科学基金(No.2002208)和沈阳化工学院中青年基金资助项目.

Crystal Structure Characteristics of Isomer of Mixed Ligand Complex Cd(Ⅱ)-phenanthroline-malonate

SUN Ya-Guang¹, WEI De-Zhou², GAO En-Jun³, DING Fu⁴

1. School of Resource & Civil Engineering, Northeastern University, Shenyang 110004;
2. Laboratory of Coordination Chemistry, Shenyang Institute of Chemical Technology, Shenyang 110142;
3. Institute of Chemical Science and Engineering, Liaoning Universi

Received:2003-09-08 Revised:2004-04-20 Published:2014-02-17

Abstract

The transparent colorless single crystal was obtained by reacting cadmium nitrate with phen and malonic acid (mal).The crystal structure was determined by X-ray diffraction.The crystal structure indicates that there are two compounds in one crystal cell and they are isomeric complexes with empirical formula C₂₇H₁₈O₄N₄Cd.They crystallize in triclinic system with space group P-1, a=0.14432(5) nm, b=0.15517(5) nm, c=0.16098(6) nm, α=107.048(6)°, β=98.989(6)°, γ=116.481(6)°, Z=2, F(000)=1287.D_c=1.453 g/cm³, μ=0.802 mm^-1, R¹ =0.0645, wR₂=0.1756.Difference between the two isomeric complexes is that in complex 1 Cd²⁺ is coordinated by one oxygen atom of every carboxylate and in complex 2 Cd²⁺ is coordinated by two oxygen atoms in a carboxylate group.Two isomeric complexes formed supramolecular structure through hydrogen bonds and π-π stacking.

Key words: Cd(Ⅱ), mixed ligand complex, crystal structure, isomer, supermolecular

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SUN Ya-Guang, WEI De-Zhou, GAO En-Jun, DING Fu. Crystal Structure Characteristics of Isomer of Mixed Ligand Complex Cd(Ⅱ)-phenanthroline-malonate[J]. Acta Chimica Sinica, 2004, 62(16): 1569-1572.

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混合配体配合物镉(Ⅱ)-邻菲罗啉-丙二酸根异构体的结构特征研究

Crystal Structure Characteristics of Isomer of Mixed Ligand Complex Cd(Ⅱ)-phenanthroline-malonate

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