Hydrogen Peroxide Sensor Based on Nano-Au Colloids Immobilized on 2,6-Pyridinedicarboxylic Acid Polymer

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (17): 1663-1667. Previous Articles

基于2,6-吡啶二甲酸聚合膜固定纳米金胶的过氧化氢传感器的研究

李春香¹, 阳明辉², 沈国励², 俞汝勤²

1. 湖南科技大学化学化工学院, 湘潭, 411201;
2. 湖南大学化学化工学院, 化学生物传感与计量学国家重点实验室, 长沙, 410082

投稿日期:2003-11-11 修回日期:2004-05-16 发布日期:2014-02-17
通讯作者: lichx33@etang.com
作者简介:李春香E-mail:lichx33@etang.com
基金资助:
国家自然科学基金(Nos.20075006,29975006)、湖南省自然科学基金(Nos.01JJY1003,01JJY2099)和博士点基金(No.20010532008)资助项目.

Hydrogen Peroxide Sensor Based on Nano-Au Colloids Immobilized on 2,6-Pyridinedicarboxylic Acid Polymer

LI Chun-Xiang¹, YANG Ming-Hui², SHEN Guo-Li², YU Ru-Qin²

1. Chemistry and Chemical Engineering College, Hunan University of Science and Technology, Xiangtan 411201;
2. State Key Laboratory of Chemo/Biosensing and Chemometrics, Chemistry and Chemical Engineering College, Hunan University, Changsha 410082

Received:2003-11-11 Revised:2004-05-16 Published:2014-02-17

Abstract

A sensitive amperômetric sensor for the determination of H₂O₂ has been constructed.Horseradish peroxidase was successfully immobilized on nano-Au colloids based on the thiol-tailed groups of cysteamine binded to the 2,6-pyridinedicarboxylic acid polymer.With the mediator of the hydroquinone in the solution, the sensor displayed excellent electrocatalytical response to the reduction of H₂O₂.Compared with enzyme-polymer modified sensor, the immobilization of enzyme was simple and the sensor exhibited a better stability and reproducibility.

Key words: nano-Au colloid, 2,6-pyridinedicarboxylic acid, cysteamine, polymer

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LI Chun-Xiang, YANG Ming-Hui, SHEN Guo-Li, YU Ru-Qin. Hydrogen Peroxide Sensor Based on Nano-Au Colloids Immobilized on 2,6-Pyridinedicarboxylic Acid Polymer[J]. Acta Chimica Sinica, 2004, 62(17): 1663-1667.

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基于2,6-吡啶二甲酸聚合膜固定纳米金胶的过氧化氢传感器的研究

Hydrogen Peroxide Sensor Based on Nano-Au Colloids Immobilized on 2,6-Pyridinedicarboxylic Acid Polymer

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