Aromatic Iodine Assisted Self-assembly of Zn(Ⅱ) and Cd(Ⅱ) Complexes of 7-Iodo-8-hydroxyquinoline-5-sulfonate

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (20): 2055-2061. Previous Articles Next Articles

芳香碘基辅助的配位超分子自组装——锌(Ⅱ)、镉(Ⅱ)与7-碘-8-羟基喹啉-5-磺酸配合物的合成和结构

张锋^1,2, 桑石云¹, 张阳阳¹, 张向东¹, 李一志², 陈慧兰², 刘祁涛¹

1. 辽宁大学化学科学与工程学院, 沈阳, 110036;
2. 南京大学配位化学国家重点实验室, 南京, 210093

投稿日期:2003-08-01 修回日期:2004-04-22 发布日期:2014-02-17
通讯作者: 刘祁涛,E-mail:qtliu@lnu.edu.cn. E-mail:qtliu@lnu.edu.cn
基金资助:
国家自然科学基金(No.29971014)、教育部归国博士启动基金(1998[679])和辽宁省科委自然科学基金(No.9910500506)资助项目.

Aromatic Iodine Assisted Self-assembly of Zn(Ⅱ) and Cd(Ⅱ) Complexes of 7-Iodo-8-hydroxyquinoline-5-sulfonate

ZHANG Feng^1,2, SANG Shi-Yun¹, ZHANG Yang-Yang¹, ZHANG Xiang-Dong¹, LI Yi-Zhi², CHEN Hui-Lan², LIU Qi-Tao¹

1. Institute of Chemical Science and Engineering, Liaoning University, Shenyang 110036;
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Received:2003-08-01 Revised:2004-04-22 Published:2014-02-17

Abstract

Two complexes [Zn(IHQS)(H₂O)₃]₂·4H₂O (1) and [Cd(IHQS)(H₂O)₂]_n·2nH₂O (2) (IHQS=7-iodo-8-hydroxyquinoline-5-sulfonate) have been synthesized and investigated by X-ray diffraction method. Both 1 and 2 are composed of a pair of coordination enantiomers. Compound 1 exhibits a coupled dimer coordination of the [Zn-(IHQS)(H₂O)₃] enantiomer pair by a complementary sulfonato-coordination to the octahedral Zn(Ⅱ) centers, and the dimer further forms a unique 2D-layer structure by double hydrogen interactions between the sulfonato group and the coordination water molecule. Compound 2 has a linear 1D-coordination polymer structure, which is formed by the [Cd-(IHQS)(H₂O)₃] enantiomer pair through a bis-complementary sulfonato-coordination mode. The aromatic iodo group demonstrated novel C—I…H (quinoline ring) and C—I…O (sulfonate) weak interactions, which are important for supporting these structures. The results provided an interesting example of the molecular shape-fitting and space-matching weak interactions involving the iodo, sulfonato, and quinoline moieties. Compound 1 is in monoclinic C2/c space group with a=2.2243(7) nm, b=1.0053(3) nm, c=1.3468(4) nm, β=102.267(5)°, V=2.9428(16) nm³, and Z=4. Compound 2 is in triclinic P1- space group with a=0.6949(2) nm, b=1.0183(3) nm, c=1.0989(3) nm, α=76.069(5)°, β=75.294(5)°, γ=84.747(5)°, V=0.7295(4) nm³ and Z=2.

Key words: 7-iodo-8-hydroxyquinoline-5-sulfonate, metal complex, weak interaction, crystal structure

Cite this article

ZHANG Feng, SANG Shi-Yun, ZHANG Yang-Yang, ZHANG Xiang-Dong, LI Yi-Zhi, CHEN Hui-Lan, LIU Qi-Tao. Aromatic Iodine Assisted Self-assembly of Zn(Ⅱ) and Cd(Ⅱ) Complexes of 7-Iodo-8-hydroxyquinoline-5-sulfonate[J]. Acta Chimica Sinica, 2004, 62(20): 2055-2061.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Yamauchi, O.; Odani, A.; Takani, M. J. Chem. Soc.,Dalton Trans. 2000, 3411.
[2] Blake, A. J.; Devillanova, F. A.; Gould, R. O.; Li, W. S.;Lippolis, V.; Parsons, S.; Radek, C.; Schroder, M. Chem.Soc. Rev. 1998, 27, 195.
[3] Aragoni, M. C.; Arca, M.; Devillanova, F. A.; Garau, A.;Isaia, F.; Lippolis, V.; Verani, G. Coord. Chem. Rev. 1999,184, 271.
[4] Deplano, P.; Ferraro, J. R.; Mercuri, M. L.; Trogu, E. F.Coord. Chem. Rev. 1999, 188, 71.
[5] DuMont, W. W.; Rut he, F. Coord. Chem. Rev. 1999, 189,101.
[6] Horn, C. J.; Blake, A. J.; Champness, N. R.; Garau, A.;Lippolis, V.; Wilson, C.; Schroder, M. Chem. Commun.2003, 312.
[7] Zhang, F.; Liu, Q. T. Chin. J. Inorg. Chem. 2000, 16,204(in Chinese).(张锋,刘祁涛,无机化学学报,2000,16,204.)
[8] Zhang, F.; Song, X. M.; Liu, Q. T. Chem. J. Chin. Univ.2000, 9, 1348 (in Chinese).(张锋,宋溪明,刘祁涛,高等学校化学学报,2000,9,3148.)
[9] Zhang, F.; Yajima, T.; Odani, A.; Yamauchi, O. Inorg.Chim. Acta 1998, 278, 136.
[10] Zhang, F.; Yajima, T.; Masuda, H.; Odani, A.; Yamauchi,O. Inorg. Chem. 1997, 36, 5777.
[11] Zhang, F.; Odani, A.; Masuda, H.; Yamauchi, O. Inorg.Chem. 1996, 35, 7148.
[12] Garay, F.; Solis, V. M. J. Electroanal. Chem. 2003, 544,1.
[13] Tsakovski, S.; Benkhedda, K.; Ivanova, E.; Adams, S. C.Anal. Chim. Acta 2002, 453, 143.
[14] Zhu, L. Z.; Qi, Z. H.; Lu, Z. S.; Jing, H.; Qi, W. B.Microchem. J. 1996, 53,361.
[15] (a) Chen, C. H.; Cai, J.; Liao, C. Z.; Feng, X. L.; Chen,X. M.; Ng, S. W. Inorg. Chem. 2002, 19, 4967.
(b) Cai, J.; Chen, C. H.; Feng, X. L.; Chen, X. M. J.Chem. Soc., Dalton Trans. 2001, 1137.
[16] Zhang, F.; Li, Y. Z.; Gao, X.; Chen, H. L.; Liu, Q. T.;Odani, A.; Yamauchi, O. Chem. Lett. 2004, 33, 556.
[17] Zhang, F.; Zhang, Y. Y.; Gao, X.; Zhang, X. D.; Li, Y.Z.; Chen, H. L.; Liu, Q. T. Chem. J. Chin. Univ. 2004,25, 1422 (in Chinese).(张锋,张阳阳,高旭,张向东,李一志,陈慧兰,刘祁涛,高等学校化学学报,2004,25,1422.)
[18] Sheldrick, G. H. SHELXTL, Structure Determination Software Programs, Version 5.10, Brucker Analytical X-ray Systems Inc.,USA, 1997.
[19] Pauling, L. The Nature of the Chemical Bond, Comell University Press, Ithaca, 1960, p. 260.

芳香碘基辅助的配位超分子自组装——锌(Ⅱ)、镉(Ⅱ)与7-碘-8-羟基喹啉-5-磺酸配合物的合成和结构

Aromatic Iodine Assisted Self-assembly of Zn(Ⅱ) and Cd(Ⅱ) Complexes of 7-Iodo-8-hydroxyquinoline-5-sulfonate

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Lei Yang, Jiaoyang Ge, Fangli Wang, Wangyang Wu, Zongxiang Zheng, Hongtao Cao, Zhou Wang, Xueqin Ran, Linhai Xie. A Theoretical Study on the Effective Reduction of Internal Reorganization Energy Based on the Macrocyclic Structure of Fluorene [J]. Acta Chimica Sinica, 2023, 81(6): 613-619.
[3]	Xuelu Ma, Meng Li, Ming Lei. Trinuclear Transition Metal Complexes in Catalytic Reactions [J]. Acta Chimica Sinica, 2023, 81(1): 84-99.
[4]	Shimin Zhu, Xin Huang, Xie Han, Simin Liu. Recognition and Luminescence Properties of N^C^N Pt(II) Complexes with Macrocyclic Host Cucurbit[10]uril [J]. Acta Chimica Sinica, 2022, 80(8): 1066-1070.
[5]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[6]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[7]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[8]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[9]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[10]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[11]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[12]	Cui Bin-Bin, Tang Jian-Hong, Zhong Yu-Wu. Resistive Memory Materials Based on Transition-Metal Complexes [J]. Acta Chim. Sinica, 2016, 74(9): 726-733.
[13]	Zhang Yiwe, Ma Xuelu, Zhang Xin, Lei Ming. Theoretical Study on N-N Activation by Thiolate-bridged Dinuclear Dinitrogen Transition-metal Complexes [J]. Acta Chim. Sinica, 2016, 74(4): 340-350.
[14]	Dong Lu, Zheng Chunying, Zhou Pei, Shi Rufei, Li Hui. Advances in Crystallography of Coordination Complexes on Main Group Metals with Amino Acid Ligands [J]. Acta Chimica Sinica, 2014, 72(9): 981-1000.
[15]	Zhou Li, Xu Lijin, Gong Hanyuan. Pattern and Protonation Effect of Benzene Dicarboxylate Anion Species in Self-assembly System [J]. Acta Chimica Sinica, 2014, 72(4): 447-455.