Ruthenium(Ⅲ) Chloride Catalyzed Oxidation Reaction of Cyclohexane and Cyclohexanol in Ionic Liquid

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (7): 742-744. Previous Articles

三氯化钌催化下环己烷和环己醇在离子液体中的氧化反应研究

唐文明¹, 李朝军²

1. 贵州大学精细化工研究开发中心, 贵阳, 550025;
2. Department of Chemistry, Tulane University, New Orleans, LA 79118, USA

投稿日期:2003-06-30 修回日期:2003-08-30 发布日期:2014-02-18
通讯作者: 唐文明,E-mail:sdkyc@163.net E-mail:sdkyc@163.net;

Ruthenium(Ⅲ) Chloride Catalyzed Oxidation Reaction of Cyclohexane and Cyclohexanol in Ionic Liquid

TANG Wen-Ming¹, LI Chao-Jun²

1. Research and Development Center of Fine Chemicals, Guizhou University, Guiyang 550025;
2. Department of Chemistry, Tulane University, New Orleans, LA 79118, USA

Received:2003-06-30 Revised:2003-08-30 Published:2014-02-18

Abstract

The oxidation reaction of cyclohexane and cyclohexanol by tertiary butyl hydroperoxide in the presence of a catalytic amount of ruthenium(ⅡI) chloride in ionic liquid is reported. The product cyclohexanone was obtained. The higher conversion and selectivity were achieved for the oxidation of cyclohexanol. Both the catalyst and ionic liquid (bmim)⁺PF₆^- can be reused in the oxidation reaction of cyclohexanol.

Key words: ionic liquid, ruthenium chloride, catalysis, cyclohexane, cyclohexanol, oxidation

Cite this article

TANG Wen-Ming, LI Chao-Jun. Ruthenium(Ⅲ) Chloride Catalyzed Oxidation Reaction of Cyclohexane and Cyclohexanol in Ionic Liquid[J]. Acta Chimica Sinica, 2004, 62(7): 742-744.

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三氯化钌催化下环己烷和环己醇在离子液体中的氧化反应研究

Ruthenium(Ⅲ) Chloride Catalyzed Oxidation Reaction of Cyclohexane and Cyclohexanol in Ionic Liquid

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