Characterization of Phenols in Cigarette Mainstream Smoke Condensate by Using Comprehensive Two-dimensional Gas Chromatography/Time-of-flight Mass Spectrometry

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (8): 804-810. Previous Articles Next Articles

全二维气相色谱/飞行时间质谱用于卷烟主流烟气中酚类化合物的表征

路鑫¹, 蔡君兰², 武建芳¹, 孔宏伟¹, 赵明月², 花瑞香¹, 刘建福³, 许国旺¹

1. 中国科学院大连化学物理研究所, 国家色谱研究分析中心, 大连, 116011;
2. 中国烟草总公司郑州烟草研究院, 郑州, 450000;
3. 长沙卷烟厂, 长沙, 410000

投稿日期:2003-07-04 修回日期:2003-12-28 发布日期:2014-02-18
通讯作者: 许国旺,E-mail:dicp402@mail.dlptt.ln.cn E-mail:dicp402@mail.dlptt.ln.cn
基金资助:
国家自然科学基金(No.20175028)和中国烟草专卖局科研基金资助项目.

Characterization of Phenols in Cigarette Mainstream Smoke Condensate by Using Comprehensive Two-dimensional Gas Chromatography/Time-of-flight Mass Spectrometry

LU Xin¹, CAI Jun-Lan², WU Jian-Fang¹, KONG Hong-Wei¹, ZHAO Ming-Yue², HUA Rui-Xiang¹, LIU Jian-Fu³, XU Guo-Wang¹

1. National Chromatographic Research and Analysis Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116011;
2. Chemistry Department, Zhengzhou Tobacco Research Institute of China National Tobacco Corporation, Zhengzhou 450000;
3. Changsha Tobacco Factory, Changsha 410000

Received:2003-07-04 Revised:2003-12-28 Published:2014-02-18

Abstract

A comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry (GC×GC/TOFMS) method has been developed for the characterization of phenols in mainstream cigarette smoke condensate. A commercially available blend type cigarette has been investigated by using the developed method. Auto data processing by TOFMS software combined with "structured chromatogram" was used to assign the components. 250 phenols were tentatively identified including 66 alkylphenol derivatives, 47 alkenylphenol derivatives, 57 naphthalenol derivatives, 17 phenylphenol derivatives, 32 methoxyphenol derivatives, 9 acylphenol derivatives and 15 hydroxybenzaldehyde derivatives. The distributing profiles of different phenol derivatives in two-dimensional chromatogram were discussed.

Key words: cigarette mainstream smoke condensate, phenol, comprehensive two-dimensional gas chromatography/time-of-flight mass spectrometry(GC×GC/TOFMS)

Cite this article

LU Xin, CAI Jun-Lan, WU Jian-Fang, KONG Hong-Wei, ZHAO Ming-Yue, HUA Rui-Xiang, LIU Jian-Fu, XU Guo-Wang. Characterization of Phenols in Cigarette Mainstream Smoke Condensate by Using Comprehensive Two-dimensional Gas Chromatography/Time-of-flight Mass Spectrometry[J]. Acta Chimica Sinica, 2004, 62(8): 804-810.

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全二维气相色谱/飞行时间质谱用于卷烟主流烟气中酚类化合物的表征

Characterization of Phenols in Cigarette Mainstream Smoke Condensate by Using Comprehensive Two-dimensional Gas Chromatography/Time-of-flight Mass Spectrometry

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