Synthesis of Polyvinyl Chloride-triethylene-tetramine Supported Palladium Complex and Its Catalytic Properties for Heck Reaction

Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (10): 924-928. Previous Articles Next Articles

Original Articles

聚氯乙烯三乙撑四胺负载钯配合物的制备及对Heck反应的催化性能

张磊，崔元臣*

(河南大学化学化工学院开封 475001)

投稿日期:2004-08-02 修回日期:2005-01-25 发布日期:2010-12-10
通讯作者: 崔元臣

Synthesis of Polyvinyl Chloride-triethylene-tetramine Supported Palladium Complex and Its Catalytic Properties for Heck Reaction

ZHANG Lei, CUI Yuan-Chen*

(College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001)

Received:2004-08-02 Revised:2005-01-25 Published:2010-12-10
Contact: CUI Yuan-Chen

Abstract

Polyvinyl chloride-triethylene-tetramine was synthesized from polyvinyl chloride via amination, then polyvinyl chloride-triethylene-tetramine supported palladium complex (PVC-TETA-Pd) was prepared and characterized by XPS, TG, DTA, TEM, etc. PVC-TETA-Pd has good thermal stability from room temperature to 250 ℃. TEM confirms that Pd particles are spherical and have uniform distribution with the size of 2～3 nm. The complex is an efficient catalyst for Heck arylation of acrylic acid and styrene with iodoarenes under atmospheric condition, even at the low temperature (40 ℃) or few amount of the catalyst (0.02 mol% Pd). PVC-TETA-Pd can be easily separated and used repeatedly. Yield of cinnamic acid was 80.1% for Heck reaction of acrylic acid with iodoarene even though the complex was used 12 times.

Key words: polyvinyl chloride, triethylene-tetramine, palladium, supported catalyst, Heck reaction

Cite this article

ZHANG Lei, CUI Yuan-Chen*. Synthesis of Polyvinyl Chloride-triethylene-tetramine Supported Palladium Complex and Its Catalytic Properties for Heck Reaction[J]. Acta Chimica Sinica, 2005, 63(10): 924-928.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

[1]	Dawei Zhang, Haiyang Zhao, Xiaotian Feng, Yucheng Gu, Xingang Zhang. Palladium-Catalyzed Cross-Coupling of Heteroaryl Bromides with gem-Difluoroallylborons [J]. Acta Chimica Sinica, 2024, 82(2): 105-109.
[2]	Weiyang Gao, Weichao Deng, Yang Gao, Renxiao Liang, Yixia Jia. Intermolecular Enantioselective Dearomative Oxidative Heck Reaction of Indoles [J]. Acta Chimica Sinica, 2024, 82(1): 1-4.
[3]	Yeqiang Han, Bingfeng Shi. Palladium(II)-Catalyzed Enantioselective Functionalization of C(sp³)—H Bonds^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1522-1540.
[4]	Yixiu Ge, Zaozao Qiu, Zuowei Xie. Pd-Catalyzed One-Pot Synthesis of Difunctionalized o-Carboranes via Construction of B—C and B—Heteroatom Bonds^※ [J]. Acta Chimica Sinica, 2022, 80(4): 432-437.
[5]	Yunfang Xu, Yang Li, Zitong Fu, Shaoyan Lin, Jie Zhu, Lei Wu. Palladium-catalyzed Stereoselective Synthesis of (Z)-[3]Dendralenes [J]. Acta Chimica Sinica, 2022, 80(10): 1369-1375.
[6]	Bo Zhou, Renxiao Liang, Zhongyan Cao, Pinghai Zhou, Yixia Jia. Palladium-Catalyzed Heck Reaction of Endocyclic Conjugated C=C Bonds of Pyrroles [J]. Acta Chimica Sinica, 2021, 79(2): 176-179.
[7]	Li Zhong-Yuan, Jing Kun, Li Qi-Li, Wang Guan-Wu. Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with 2-Aryloxypyridines [J]. Acta Chim. Sinica, 2019, 77(8): 729-734.
[8]	Yu Jun, Yang Yusen, Wei Min. Preparation and Catalytic Performance of Supported Catalysts Derived from Layered Double Hydroxides [J]. Acta Chimica Sinica, 2019, 77(11): 1129-1139.
[9]	Khan Ijaz, Li Hongfang, Wu Xue, Zhang Yong Jian. Asymmetric Decarboxylative Cycloaddition of Vinylethylene Carbonates with Aldehydes by Cooperative Catalysis of Palladium Complex and Chiral Squaramide [J]. Acta Chim. Sinica, 2018, 76(11): 874-877.
[10]	Zhou Xiao-Le, Su Yong-Liang, Wang Pu-Sheng, Gong Liu-Zhu. Asymmetric Allylic C-H Alkylation of 1,4-Dienes with Aldehydes [J]. Acta Chim. Sinica, 2018, 76(11): 857-861.
[11]	Feng Aihu, Yu Yang, Yu Yun, Song Lixin. Recent Progress in the Removal of Volatile Organic Compounds by Zeolite and Its Supported Catalysts [J]. Acta Chim. Sinica, 2018, 76(10): 757-773.
[12]	Li Baole, Liu Renrong, Liang Renxiao, Jia Yixia. Palladium/Amino Acid Co-Catalyzed Intramolecular α-Vinylation of Cyclohexanones [J]. Acta Chim. Sinica, 2017, 75(5): 448-452.
[13]	Zhang Zi-Jing, Tao Zhong-Lin, Arafate Adele, Gong Liu-Zhu. Asymmetric Carbonyl Allylation of Aldehydes with Allylic Alcohols under the Sequential Catalysis of Palladium Complex and Chiral Phosphoric Acid [J]. Acta Chim. Sinica, 2017, 75(12): 1196-1201.
[14]	Yuan Pei, Chen Jian, Pan Deng, Bao Xiaojun. Adsorption and Reaction Kinetic Studies of the Heterogeneous Catalytic Hydrogenation for Polystyrene [J]. Acta Chim. Sinica, 2016, 74(7): 603-611.
[15]	Tang Haoming, Huo Xiaohong, Meng Qinghua, Zhang Wanbin. Palladium-Catalyzed Allylic C—H Functionalization: The Development of New Catalytic Systems [J]. Acta Chim. Sinica, 2016, 74(3): 219-233.

聚氯乙烯三乙撑四胺负载钯配合物的制备及对Heck反应的催化性能

Synthesis of Polyvinyl Chloride-triethylene-tetramine Supported Palladium Complex and Its Catalytic Properties for Heck Reaction

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments