Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (14): 1303-1306. Previous Articles     Next Articles

Original Articles

一种Q态纳米CdS的新型制备法——聚合物分散法

闫云辉,章伟光*,范军,纪欣   

  1. (华南师范大学化学与环境学院 广州 510631)
  • 投稿日期:2004-10-29 修回日期:2005-03-28 发布日期:2010-12-10
  • 通讯作者: 章伟光

New Approach to Prepare Q-CdS Nanoparticles: Polymer Dispersion Method

YAN Yun-Hui, ZHANG Wei-Guang*, FAN Jun, JI Xin   

  1. (College of Chemistry and Environment, South China Normal University, Guangzhou 510631)
  • Received:2004-10-29 Revised:2005-03-28 Published:2010-12-10
  • Contact: ZHANG Wei-Guang

Polymer dispersion method, a new approach to obtain Q-CdS nanoparticles, has been presented. Four kinds of monodisperse Q-CdS with different sizes were constructed by using water soluble polymer as dispersion agents and 2-mercaptoethanol or dodecyl mercaptan as surface modifier in polymer networks. UV-vis spectra and TEM were used to determine particle size and observe the size distribution, and fluorescence properties of Q-CdS with different sizes were studied. Obtained results indicated that different Q-CdS nanoparaticles with small size and narrow distribution were quickly prepared by polymer dispersion method, and these samples showed obvious quantum size effect on UV-vis and fluorescent spectra.

Key words: Q-CdS, polymer dispersion method, preparation, quantum size effect