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Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (22): 2082-2088. Previous Articles     Next Articles

Original Articles

锌硅钼钨多元取代多金属含氧簇合物的合成、表征及其催化异丙醇气相反应的活性

华春燕1,2，李娟1,2，戴立益*,1,2，单永奎1   

  1. (1华东师范大学化学系 上海 200062)
    (2上海市分子催化和功能材料重点实验室 复旦大学化学系 上海 200433)
  • 投稿日期:2005-01-17 修回日期:2005-08-25 发布日期:2010-12-10
  • 通讯作者: 戴立益

Synthesis, Characterization of Zn-containing Tungstomolybdosilic Polyoxometalates and Their Catalytic Performancein Reaction of 2-Propanol

HUA Chun-Yan1,2, LI Juan1,2, DAI Li-Yi*,1,2, SHAN Yong-Kui1   

  1. (1 Department of Chemistry, East China Normal University, Shanghai 200062)
    (2 Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry,
    Fudan University, Shanghai 200433)
  • Received:2005-01-17 Revised:2005-08-25 Published:2010-12-10
  • Contact: DAI Li-Yi

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Zn-containing derivatives of H4SiMo12－nWnO40 (n＝2, 4, 6, 8, 10) were prepared under different pH according to the variation of n and characterized by elemental analysis, IR spectra, X-ray diffraction and XPS. The acid kind and intensity of the polyoxometalates were investigated by Py-IR and NH3-TPD, respectively. The polyoxometalates were used as heterogeneous catalysts in tested gaseous reaction of decomposition of isopropanol. The relationship between catalytic activity of the polyoxometalates and their component was discussed.

Key words: Keggin structure, polyoxometalate, isopropanol, zinc, catalysis