Acta Chimica Sinica ›› 2005, Vol. 63 ›› Issue (9): 819-826. Previous Articles     Next Articles

Original Articles

锂离子电池电极用规整中孔碳分子筛的电化学特性

邢伟1 2,张颖1,阎子峰*1,逯高清2   

  1. (1中国石油大学重质油国家重点实验室 CNPC催化重点实验室 东营 257061)
    (2 The Nanomaterials Centre, School of Engineering, University of Queensland, Brisbane 4072, Australia)
  • 投稿日期:2004-03-11 修回日期:2005-01-07 发布日期:2010-12-10
  • 通讯作者: 阎子峰

Electrochemical Characteristics of Ordered Mesoporous Carbon Used as Electrode Material in Li-ion Battery

XING Wei1,2, ZHANG Ying1, YAN Zi-Feng*1, LU Gao-Qing2   

  1. (1 State Key Laboratory for Heavy Oil Processing, Key Laboratory of Catalysis, CNPC, China Universtiy of Petroleum, Dongying 257061, China)
    (2 The Nanomaterials Centre, School of Engineering, University of Queensland, Brisbane 4072, Australia)
  • Received:2004-03-11 Revised:2005-01-07 Published:2010-12-10
  • Contact: YAN Zi-Feng

Ordered mesoporous carbon CMK-5 was comprehensively tested for the first time as electrode materials in lithium ion battery. The surface morphology, pore structure and crystal structure were investigated by Scanning Electronic Microscopy (SEM), N2 adsorption technique and X-ray diffraction (XRD) respectively. Electrochemical properties of CMK-5 were studied by galvanostatic cycling and cyclic voltammetry, and compared with conventional anode material graphite. Results showed that the reversible capacity of CMK-5 was 525 mAh/g at the third charge-discharge cycle and that CMK-5 was more compatible for quick charge-discharge cycling because of its special mesoporous structure. Of special interest was that the CMK-5 gave no peak on its positive sweep of the cyclic voltammetry, which was different from all the other known anode materials. Besides, X-ray photoelectron spectroscopy (XPS) and XRD were also applied to investigate the charge-discharge characteristics of CMK-5.

Key words: mesoporous carbon, anode material, lithium-ion battery, SEI film