Syntheses and Characterization of Some Vanadium-contained Compounds and Investigation of Their Catalytic Activity on the Oxi-dation of Cyclohexane

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (18): 1881-1884. Previous Articles Next Articles

Original Articles

一些含钒杂多化合物的合成、表征及其在环己烷催化氧化反应中性能的比较

井淑波, 朱万春, 管景奇, 王振旅, 王国甲*

(吉林大学化学学院长春 130023)

投稿日期:2005-07-15 修回日期:2006-03-31 发布日期:2006-09-28
通讯作者: 王国甲

Syntheses and Characterization of Some Vanadium-contained Compounds and Investigation of Their Catalytic Activity on the Oxi-dation of Cyclohexane

JING Shu-Bo; ZHU Wan-Chun; GUAN Jing-Qi; WANG Zhen-Lü; WANG Guo-Jia*

(Chemistry College of Jinlin University, Changchun 130023)

Received:2005-07-15 Revised:2006-03-31 Published:2006-09-28
Contact: WANG Guo-Jia

Abstract

Some vanadium-contained compounds were prepared and characterized. We investigated their activity on the oxidation of cyclohexane and the decomposition of H₂O₂ and found that the coordinate surrounding of vanadium affect the activity of reaction strongly. When we use vanadium-substituted heteropoly compounds as catalyst, the decomposition of H₂O₂ can be restrained. Especially when vanadium was on the coordination site, such as H₄PMo₁₁VO₄₀, the catalyst showed excellent activity for the oxidation of cyclohexane with low speed of the decomposition of H₂O₂.

Key words: vanadium-contained compound, cyclohexane, oxidation

Cite this article

JING Shu-Bo; ZHU Wan-Chun; GUAN Jing-Qi; WANG Zhen-Lü; WANG Guo-Jia*. Syntheses and Characterization of Some Vanadium-contained Compounds and Investigation of Their Catalytic Activity on the Oxi-dation of Cyclohexane[J]. Acta Chimica Sinica, 2006, 64(18): 1881-1884.

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一些含钒杂多化合物的合成、表征及其在环己烷催化氧化反应中性能的比较

Syntheses and Characterization of Some Vanadium-contained Compounds and Investigation of Their Catalytic Activity on the Oxi-dation of Cyclohexane

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