Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (1): 53-58. Previous Articles     Next Articles

Original Articles

聚苯胺-LiNi铁氧体复合纳米微粒的原位合成及其键合机制

蒋静1, 李良超*,1, 徐烽1, 颜冲2   

  1. (1浙江师范大学化学系 物理化学研究所 金华 321004)
    (2中国计量学院东磁研究院 杭州 310018)
  • 投稿日期:2006-03-30 修回日期:2006-04-29 发布日期:2007-01-14
  • 通讯作者: 李良超

In Situ Synthesis of Polyaniline-LiNi Ferrite Nanocomposite and Its Bonding Mechanism

JIANG Jing1; LI Liang-Chao*,1; XU Feng1; YAN Chong2   

  1. (1 Department of Chemistry, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004)
    (2 Dongyang Magnetic Institute, Chinese Institute of Metrology, Hangzhou 310018)
  • Received:2006-03-30 Revised:2006-04-29 Published:2007-01-14
  • Contact: LI Liang-Chao

Polyaniline-LiNi ferrite (LiNi0.5Fe2O4) nanocomposites were synthesized by in situ aqueous polymerization of aniline in the presence of ferrite. The structure, morphologies and magnetic properties of samples were characterized by X-ray diffraction (XRD), infrared spectra (FTIR), Raman spectra, UV-Vis spectra, transmission electron microscope (TEM) and vibrating sample magnetometer (VSM) techniques. The results indicated that the nanocomposites under applied magnetic field exhibited the hysteresis loops of the ferrimagnetic nature at room temperature. The ferrite particles had the core effect on the polymerization of aniline. The bonding interaction existed between ferrite particles and polyaniline in the composites, and the bonding mechanism was investigated.

Key words: LiNi ferrite, polyaniline, nanocomposite, magnetic property, bonding mechanism