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Acta Chimica Sinica ›› 2007, Vol. 65 ›› Issue (16): 1605-1611. Previous Articles     Next Articles

Original Articles

四-α-(2-甲基-8-喹啉氧基)酞菁金属配合物的合成、表征及光敏活性研究

薛金萍1, 刘宏1, 范长安2, 洪湖铭3, 陈耐生*,1, 黄金陵1   

  1. (1福州大学化学化工学院功能材料研究所 福州 350002)
    (2福建省三明市建宁消防大队 三明 354500)
    (3厦门太古飞机工程有限公司理化实验室 厦门 361006)
  • 投稿日期:2006-10-08 修回日期:2007-02-05 发布日期:2007-08-28
  • 通讯作者: 陈耐生

Synthesis, Characterization and Photosensitivity Study of Tetrakis-α-(2-methyl-8-quinolinoxy)metallophthalocyanines

XUE Jin-Ping1; LIU Hong1; FAN Chang-An2; HONG Hu-Ming3; CHEN Nai-Sheng*,1; HUANG Jin-Ling1   

  1. (1 Institute of Functional Materials, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou 350002)
    (2 Fujian Sanming Jianning Fire Company, Sanming 354500)
    (3 Laboratory of Physics and Chemistry, Taigu Aeroengineering Ltd., Xiamen 361006)
  • Received:2006-10-08 Revised:2007-02-05 Published:2007-08-28
  • Contact: Nai-Sheng CHEN

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Cobalt(II), nickel(II), copper(II) and zinc(II) coordination compounds of tetrakis-α-(2-methyl-8- quinolinoxy)phthalocyanine were synthesized by means of “DBU method”. The title complexes were characterized by elemental analysis, mass spectrum, UV-Vis and IR spectra. In addition, the rates of photo-generating singlet oxygen and the rate constants of photodynamic oxidation of amino-acid for the complexes were measured by irradiation of laser at 670 nm, and the relations between their structures and photosensitivities were discussed.

Key words: 2-methyl-8-quinolinoxy, metallophthalocaynine, synthesis, characterization, photosensitivity