Acta Chimica Sinica ›› 2009, Vol. 67 ›› Issue (19): 2210-2214. Previous Articles     Next Articles

Full Papers

RuCl3/O2催化的叔胺与2-硅氧基呋喃衍生物的偶联反应研究

陈德a   申有名  吴运东   何卫民a    何纯莲  向建南*,a   

  1. (a湖南大学化学生物传感与计量学国家重点实验室 长沙 410082) (b湖南师范大学医学院 长沙 410081)
  • 投稿日期:2009-03-13 修回日期:2009-05-21 发布日期:2009-06-30
  • 通讯作者: 向建南 E-mail:jnxiang@hnu.cn

RuCl3/O2 Catalyzed Coupling Reactions between Tertiary Amines and 2-Siloxyfurans

Chen, Dea     Shen, Youminga      Wu, Yundong        He, Weimina         He, Chunlianb        Xiang, Jiannan*,a   

  1. (a State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082) (b Medical College, Hunan Normal University, Changsha 410081)
  • Received:2009-03-13 Revised:2009-05-21 Published:2009-06-30
  • Contact: XIANG Jian-Nan E-mail:jnxiang@hnu.cn

Tertiary amines and 2-siloxyfurans were coupled to give the corresponding products 3 in good yields through the C—C bonds formation when RuCl3 was used as the catalyst under oxygen atomsphere. The structures of the target products 3 were characterized by 1H NMR, 13C NMR, IR, MS and HRMS.

Key words: ruthenium trichloride, oxygen, tertiary amine, coupling reaction