Acta Chimica Sinica ›› 1990, Vol. 48 ›› Issue (5): 489-493. Previous Articles     Next Articles

Original Articles

油松毛虫性引诱剂(5z,7e)-十二碳二烯醇及其乙酸酯和丙酸酯的合成

孙小静;王东;陈德恒   

  1. 中国科学院化学研究所;加拿大麦吉尔大学化学系
  • 发布日期:1990-05-15

Synthesis of (5Z, 7E)-dodecadien-1-ol and its acetate and propionate

SUN XIAOJING;WANG DONG;CHEN DEHENG   

  • Published:1990-05-15

Starting from allyltrimethylsilane and hexyne, the title pheromones were synthesized through alkylation, addition- hydroalumination and coupling reaction of vinyl iodide I with vinylalane II. The total yield was 20% with stereoselectivity of 94%.

Key words: ACETIC ACID ESTER, ALKYLATION, CONJUGATED DOUBLE BOND COMPOUNDS, COUPLING REACTION, ENOLS, STEREOISOMERISM, C12 COMPOUNDS, DENDROLIMUS TABULAEFORMIS, SEX ATTRACTANT, PROPIONATE

CLC Number: