The E-addition reaction of lithium trialkylalkynyl-borates with allyl acetate in the presence of Pd(PPh3)4

Acta Chimica Sinica ›› 1989, Vol. 47 ›› Issue (5): 499-501. Previous Articles Next Articles

Original Articles

钯催化的炔基硼酸锂盐与醋酸烯丙酯的E式加成反应

邓敏智;张华琪

中国科学院上海有机化学研究所

发布日期:1989-05-15

The E-addition reaction of lithium trialkylalkynyl-borates with allyl acetate in the presence of Pd(PPh3)4

DENG MINZHI;ZHANG HUAQI

Published:1989-05-15

Abstract

The title reaction gave E-allylated alkenes as the major products in 70-83% yields.

Key words: ACETIC ACID ESTER, CATALYSIS, ALKENE, BORATES, LITHIUM COMPOUNDS, TRIPHENYLPHOSPHINE, ISOMER, PALLADIUM, STEREOSELECTIVITY, ALKYNE P

CLC Number:

O621

Cite this article

DENG MINZHI;ZHANG HUAQI. The E-addition reaction of lithium trialkylalkynyl-borates with allyl acetate in the presence of Pd(PPh3)4[J]. Acta Chimica Sinica, 1989, 47(5): 499-501.

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钯催化的炔基硼酸锂盐与醋酸烯丙酯的E式加成反应

The E-addition reaction of lithium trialkylalkynyl-borates with allyl acetate in the presence of Pd(PPh3)4

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