Syntheses, characterization and third-order nonlinear optical properties of ruthenium(Ⅱ) polypyridine complexes

Acta Chimica Sinica ›› 2002, Vol. 60 ›› Issue (1): 65-70. Previous Articles Next Articles

Original Articles

钌(Ⅱ)多吡啶配合物的合成、表征及其三阶非线性光学性质研究

蒋才武;巢晖;李润华;李红;计亮年

中山大学超快速激光光谱国家重点实验室;中山大学化学与化学工程学院;中山大学超快速激光光谱国家重点实验室;中国科学院上海有机化学研究所生命有机国家重点实验室;南京大学配位化学国家重点实验室

发布日期:2002-01-15

Syntheses, characterization and third-order nonlinear optical properties of ruthenium(Ⅱ) polypyridine complexes

JIANG CAIWU;CHAO HUI;LI RUNHUA;LI HONG;JI LIANGNIAN

Published:2002-01-15

Abstract

Three ruthenium (Ⅱ) complexes containing imidazo[4, 5-f][1, 10] phenanthroline (IP) have been synthesized and characterized by EA, FAB-MS, ^1H NMR, UV-vis and electrochemistry. The cubic nonlinear refraction index n~2 and the nonlinear absorption coefficient α~2 of the ruthenium (Ⅱ) complexes are measured by Z-scan techniques and the third-order nonlinear susceptibility χ^(^3^), and hyperpolarizability γ of the complexes are calculated. The effects of molecular structure on the third- order nonlinear optical properties are discussed.

Key words: RUTHENIUM COMPLEX, P, GLYOXALINE P, PHENANTHROLINE P, NON LINEAR OPTICS, OPTICAL PROPERTIES, ELEMENTAL ANALYSIS, PROTON MAGNETIC RESONANCE SPECTROMETRY, ULTRAVIOLET SPECTROPHOTOMETRY, NSFC

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JIANG CAIWU;CHAO HUI;LI RUNHUA;LI HONG;JI LIANGNIAN. Syntheses, characterization and third-order nonlinear optical properties of ruthenium(Ⅱ) polypyridine complexes[J]. Acta Chimica Sinica, 2002, 60(1): 65-70.

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钌(Ⅱ)多吡啶配合物的合成、表征及其三阶非线性光学性质研究

Syntheses, characterization and third-order nonlinear optical properties of ruthenium(Ⅱ) polypyridine complexes

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