Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (10): 1152-1161. Previous Articles     Next Articles

Original Articles

金属锡和三甲基氯硅烷存在下芳香醛、酮与醇的还原-偶联-醚化 反应

吴世晖;王存;高翔;陈元梅;丁宗彪   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:1999-10-15

The reduction-coupling-etherification of alcohols and aromatic aldehydes or ketones in the presence of tin and chlorotrimethylsilane

Wu Shihui;Wang Cun;Gao Xiang;Chen Yuanmei;Ding Zongbiao   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:1999-10-15

A reduction-coupling-etherification reaction between aromatic aldehydes or ketones (1) and alcohols (2) to yield corresponding diether (3) of pinacol in the presence of tin and chlorotrimethylsilane. The scope and limitations of this reaction were studied and a reasonable mechanism was proposed.

Key words: TIN, CHLOROSILANE, AROMATIC ALDEHYDE, KETONE, AROMATIC ALCOHOL, REDUCTION, COUPLED, ETHERIFICATION, REACTION MECHANISM

CLC Number: