A quantum scattering theoretical study on the  compound-state formation and the rotational-state  distribution of the product for the three-dimensional  state-to-state H+H~2(v, j)→H~2(v', j')+H reaction

Acta Chimica Sinica ›› 1999, Vol. 57 ›› Issue (6): 553-556. Previous Articles Next Articles

Original Articles

三维H+H~2(v, j)→H~2(v', j')+H反应中复合态生成及产物转动态分布的量子散射理论研究

吕文彩;蔡政亭;邓从豪

山东大学理论化学研究室.济南(250100)

发布日期:1999-06-15

A quantum scattering theoretical study on the compound-state formation and the rotational-state distribution of the product for the three-dimensional state-to-state H+H~2(v, j)→H~2(v', j')+H reaction

Lu Wencai;Cai Zhengting;Deng Conghao

Shandong Univ, Theoret Chem Lab.Jinan(250100)

Published:1999-06-15

Abstract

This paper reports the three-dimensional state-to-state reaction probabilities for the H+H~2(v, j)→H~2(v', j')+H system calculated by LCAC-SW (linear combination of arrangement channels-scattering wavefunction) approach. The compound-state formation (or energy resonance structure) of this system is analyzed. The results of the rotational-state distribution for the product of this reaction show that the energy resonance is due to the interference effect between the translational motion of the system and the internal state of the reactant.

Key words: HYDROGEN, ROTATIONAL STATE

CLC Number:

O641

Cite this article

Lu Wencai;Cai Zhengting;Deng Conghao. A quantum scattering theoretical study on the compound-state formation and the rotational-state distribution of the product for the three-dimensional state-to-state H+H~2(v, j)→H~2(v', j')+H reaction[J]. Acta Chimica Sinica, 1999, 57(6): 553-556.

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三维H+H~2(v, j)→H~2(v', j')+H反应中复合态生成及产物转动态分布的量子散射理论研究

A quantum scattering theoretical study on the compound-state formation and the rotational-state distribution of the product for the three-dimensional state-to-state H+H~2(v, j)→H~2(v', j')+H reaction

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三维H+H~2(v, j)→H~2(v', j')+H反应中复合态生成及产物转动 态分布的量子 散射理论研究

A quantum scattering theoretical study on the compound-state formation and the rotational-state distribution of the product for the three-dimensional state-to-state H+H~2(v, j)→H~2(v', j')+H reaction

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

三维H+H~2(v, j)→H~2(v', j')+H反应中复合态生成及产物转动态分布的量子散射理论研究