Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (08): 793-797. Previous Articles     Next Articles

Full Papers

磁性纳米氧化铁与CdTe量子点相互作用的光谱学研究

刘欣,郑成志,杨逸仙,梁建功,韩鹤友*   

  1. (华中农业大学理学院 农业微生物学国家重点实验室 武汉 430070)
  • 投稿日期:2009-08-19 修回日期:2009-11-23 发布日期:2009-12-23
  • 通讯作者: 韩鹤友 E-mail:hyhan@mail.hzau.edu.cn
  • 基金资助:

    200735;A08099;2007XCX003;200851430484;2008CDA080

Spectral Analysis on the Interaction between Magnetic Iron Oxide Nanoparticles and CdTe Quantum Dots

LIU Xin, ZHENG Cheng-Zhi, YANG Yi-Xian, LIANG Jian-Gong, HAN He-You   

  1. (State Key Laboratory of Agricultural Microbiology, College of Science, Huazhong Agricultural University, Wuhan 430070)
  • Received:2009-08-19 Revised:2009-11-23 Published:2009-12-23

The interaction between magnetic iron oxide nanoparticles (MION) and CdTe quantum dots (QDs) was studied by fluorescence and UV-visible absorption spectra. The results showed that the fluorescence of CdTe QDs was strongly quenched by MION. The quenching mechanism was discussed to be a static quenching process, which was proved by the quenching rate constant (Kq=7.68×1015 mol•L-1•s-1) and UV-vis absorption spectra. According to Lineweaver-Burk equations at different temperatures, the thermodynamic parameters (?H?=21.6 kJ•mol-1, ?S?=210.3 J•mol-1•K-1 and ?G?=-41.1 kJ•mol-1, 298 K) were obtained. It was found that the process of binding was a spontaneous process with an electrostatic interaction.

Key words: magnetic iron oxide nanoparticle, CdTe quantum dot, interaction, thermodynamic parameter