Acta Chimica Sinica ›› 2010, Vol. 68 ›› Issue (18): 1802-1806. Previous Articles     Next Articles

Full Papers

介电失配度对沸石电流变液界面极化的影响

周威*,1,赵孔双2,孙宇梅1,赵进1   

  1. (1北京工商大学化学与环境工程学院 北京 100048)
    (2北京师范大学化学学院 北京 100875)
  • 投稿日期:2010-01-21 修回日期:2010-03-18 发布日期:2010-05-15
  • 通讯作者: 周威 E-mail:zhouw@th.btbu.edu.cn
  • 基金资助:

    荷电膜参数的介电谱解析和实时监测方法的探索研究

The Effect of Dielectric Mismatch Degree on Interface Polarization of Zeolite Electrorheological Liquid

Zhou Wei*,1 Zhao Kongshuang2 Sun Yumei1 Zhao Jin1   

  1. (1 School of Chemistry and Environmental Engineering, Beijing Technology and Business University, Beijing 100048)
    (2 College of Chemistry, Beijing Normal University, Beijing 100875)
  • Received:2010-01-21 Revised:2010-03-18 Published:2010-05-15
  • Contact: Zhou Wei E-mail:zhouw@th.btbu.edu.cn

The dielectric properties of two electrorheological liquid (ERL) systems, NaA zeolite/silicone oil and NaA zeolite/coal oil, were measured by dielectric spectroscopy, and an obvious dielectric relaxation at about 105 Hz can be observed in each of systems. The single relaxation Cole-Cole equation was used to fit the dielectric parameters of the systems, and the results indicated that NaA zeolite/silicone oil possessed larger dielectric increment (). Furthermore, for both of the two systems, the relationship between the volume fraction (φ) and dielectric increment obeyed the linear function=4εmφ (εm, the permittivity of oil medium). By means of calculating and analyzing the dielectric mismatch parameter between zeolite particle and oil medium, the contribution of εm to the interface polarization intensity of ERL was clarified. Moreover, the effect of adsorbed water on the interface polarization of zeolite ERL was researched as well. The results indicated that the permittivity of zeolite particle was enhanced and the relaxation time was reduced in the presence of adsorbed water, however, no change was found in of zeolite ERL with adsorbed water. Based on the dielectric mismatch theory, the adsorbed water was proved to be positive to the interface polarization rate of zeolite ERL.

Key words: zeolite, electrorheological liquid, dielectric spectroscopy, dielectric mismatch, interface polarization