Synthesis and Reactivity of the Four-membered Heterometallacycles with M—Sn (M＝Mo or W) Bonds

doi:10.6023/A1103311B

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (21): 2567-2573.DOI: 10.6023/A1103311B Previous Articles Next Articles

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含钼(钨)锡键的四元金属有机杂环化合物的合成与反应研究

张晓燕¹，宋海滨²，唐良富*^,2

(¹东北大学秦皇岛分校材料科学与工程系秦皇岛河北 066004)
(²南开大学化学系元素有机化学国家重点实验室天津 300071)

投稿日期:2011-03-31 修回日期:2011-06-23 发布日期:2011-07-12
通讯作者: 唐良富 E-mail:lftang@nankai.edu.cn
基金资助:
国家自然科学基金

Synthesis and Reactivity of the Four-membered Heterometallacycles with M—Sn (M＝Mo or W) Bonds

Zhang Xiaoyan¹ Song Haibin² Tang Liangfu*^,2

(¹ Department of Materials Science and Engineering, Northeastern University at Qinhuangdao, Hebei 066004)
(² Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071)

Received:2011-03-31 Revised:2011-06-23 Published:2011-07-12

Four-membered heterometallacylic complex CH(3,5-Me₂Pz)₂Mo(CO)₃SnPh₃ (Pz＝pyrazol-1-yl) has been obtained by the reaction of Ph₃SnCH(3,5-Me₂Pz)₂ with Mo(CO)₆. Treatment of this complex and its tungsten analog with CNBu-t resulted in the reductive elimination reaction to give complexes CH₂(3,5- Me₂Pz)₂M(CO)₃(CNBu-t) (M＝Mo or W) with the loss of organotin fragment. In addition, reaction of this complex with PR₃ (R＝Ph, OMe or OPr-#em/em#) only yielded complexes CH(3,5-Me₂Pz)₂Mo(CO)₂(PR₃)SnPh₃. While the similar reaction with P(OPh)₃ led to the P—O/C exchange to give the reductive elimination product (PhO)₂PCH(3,5-Me₂Pz)₂Mo(CO)₃, besides the substituted reaction of the carbonyl group.

Key words: bis(pyrazol-1-yl)methane, heterometallacycle, group 6 metal carbonyl complex, organotin, crystal structure

CLC Number:

O621.25+8

Cite this article

ZHANG Xiao-Yan, SONG Hai-Bin, TANG Liang-Fu. Synthesis and Reactivity of the Four-membered Heterometallacycles with M—Sn (M＝Mo or W) Bonds[J]. Acta Chimica Sinica, 2011, 69(21): 2567-2573.

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含钼(钨)锡键的四元金属有机杂环化合物的合成与反应研究

Synthesis and Reactivity of the Four-membered Heterometallacycles with M—Sn (M＝Mo or W) Bonds

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[1]	Yang Liu, Fengqin Gao, Zhanying Ma, Yinli Zhang, Wuwu Li, Lei Hou, Xiaojuan Zhang, Yaoyu Wang. Co-based Metal-organic Framework for High-efficiency Degradation of Methylene Blue in Water by Peroxymonosulfate Activation [J]. Acta Chimica Sinica, 2024, 82(2): 152-159.
[2]	Tiantian Lü, Wen Ma, Dongsun Zhan, Yanmin Zou, Jilong Li, Meiling Feng, Xiaoying Huang. Two New Three-Dimensional Lanthanide Metal-organic Frameworks for the Highly Efficient Removal of Cs⁺ Ions^※ [J]. Acta Chimica Sinica, 2022, 80(5): 640-646.
[3]	Jinxu Zhao, Mingshu Zhang, Wenfa Chen, Xiaoming Jiang, Binwen Liu, Guocong Guo. KAg₃Ga₈S₁₄: An Mid- and Far-infrared Nonlinear Optical Material Exhibiting High Laser-induced Damage Threshold^※ [J]. Acta Chimica Sinica, 2022, 80(3): 259-264.
[4]	Rong Zhang, Jiangping Liu, Ziyi Zhu, Shumei Chen, Fei Wang, Jian Zhang. Synthesis, Structure and Characterization of Two Ferrocene Functionalized Cadmium Metal Organic Frameworks^※ [J]. Acta Chimica Sinica, 2022, 80(3): 249-254.
[5]	Jing Fang, Wenjuan Zhao, Minghao Zhang, Qianrong Fang. A Novel Amide-functionalized Covalent Organic Framework for Selective Dye Adsorption [J]. Acta Chimica Sinica, 2021, 79(2): 186-191.
[6]	Fu Jingru, Ben Teng. Fabrication of a Novel Covalent Organic Framework Membrane and Its Gas Separation Performance [J]. Acta Chimica Sinica, 2020, 78(8): 805-814.
[7]	Chen Guanghui, He Yanping, Zhang Lei, Zhang Jian. Syntheses and Structural Studies of a Series of Ti₄(embonate)₆-based Complexes [J]. Acta Chimica Sinica, 2020, 78(12): 1411-1417.
[8]	Wang Zhitao, Li Hui, Yan Shichen, Fang Qianrong. Synthesis of a Two-dimensional Covalent Organic Framework with the Ability of Conducting Proton along Skeleton [J]. Acta Chimica Sinica, 2020, 78(1): 63-68.
[9]	Dong Lu, Zheng Chunying, Zhou Pei, Shi Rufei, Li Hui. Advances in Crystallography of Coordination Complexes on Main Group Metals with Amino Acid Ligands [J]. Acta Chimica Sinica, 2014, 72(9): 981-1000.
[10]	Han Cong, Xu Zhe, Diao Chunhua, Chen Xin, Liu Jing, Guo Minjie, Fan Zhi. Self-assembly Behavior of Interlocked Helical Supramolecule of Cyclodextrin Modified by 2-Furanmethanethiol [J]. Acta Chimica Sinica, 2013, 71(03): 439-442.
[11]	Duan Xianying, Guo Libing, Wang Jianli. A Good Proton-conductive Polyoxometalate Complex {[Co(H₂O)₈][H(H₂O)₃](HINO)₄(PW₁₂O₄₀)}_n: Synthesis, Crystal Structure and Properties [J]. Acta Chimica Sinica, 2013, 71(01): 107-113.
[12]	Guo Qiong, Li Lianzhi, Dong Jianfang, Liu Hongyan, Xue Zechun, Xu Tao . Synthesis, Crystal Structure and Interactions with DNA and BSA of a Oxovanadium(IV) Complex [VO(o-Van-Asn)(Phen)]?1.5CH₃OH [J]. Acta Chimica Sinica, 2012, 70(15): 1617-1624.
[13]	Lu Yanmei, Ou Zhibin, Hu Wei, Le Xueyi. Structure, Antibacterial Activities and DNA Cleavage of a Copper(II) Complex with 2-(2'-Pyridyl)benzimidazole and L-Alaninate [J]. Acta Chimica Sinica, 2012, 70(08): 973-979.
[14]	Lu Dongfei, Di Youying, Dou Jianmin. Synthesis, Crystal Structure and Low-temperature Heat Capacities of Bis(n-undecylammonium)tetrachlorocadmiumate [J]. Acta Chimica Sinica, 2012, 70(07): 889-896 .
[15]	Tang Zhan, Yang Li, Qiao Xiaojing, Zhang Tonglai, Zhang Jianguo, Liang Yanhui. Synthesis, Crystal Structure and Thermal Analysis of Two New Energetic Compounds (AIM)NO₃ and (AIM)(HTNR)稨₂O [J]. Acta Chimica Sinica, 2012, 0(04): 471-478.