Controllable Synthesis of Chitosan-Mediated Gold Nanoplate and the Growth Mechanisms

doi:10.6023/A1108121

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (03): 259-264.DOI: 10.6023/A1108121 Previous Articles Next Articles

Full Papers

壳聚糖介质金纳米盘的可控合成及生长机理

杨传孝, 孙向英, 刘斌

华侨大学材料科学与工程学院厦门 361021

投稿日期:2011-08-12 修回日期:2011-11-01 发布日期:2011-11-14
通讯作者: 杨传孝, 孙向英 E-mail:sunxy@hqu.edu.cn, cxyang@hqu.edu.cn
基金资助:
国家自然科学基金(No. 20955001)、国务院侨办科研基金(No. 09QZR05)和华侨大学基本科研业务费专项基金(No. JB-ZR1118)资助项目.

Controllable Synthesis of Chitosan-Mediated Gold Nanoplate and the Growth Mechanisms

Yang Chuanxiao, Sun Xiangying, Liu Bin

College of Materials Science and Engineering, Huaqiao University, Xiamen 361021

Received:2011-08-12 Revised:2011-11-01 Published:2011-11-14
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20955001), the Foundation of Overseas-Chinese Affairs Office of the State Council of China (No. 09QZR05) and the Fundamental Research Funds for the Huaqiao University (No. JB-ZR1118).

By chitosan as a stabilizer and reducing agent, the tunable surface plasmon resonance (SPR) absorption peak of gold nanoplate has been successfully fabricated by water bath heating of solution containing HAuCl₄, chitosan and gold nanoseeds. The SEM images indicated that the gold nanoplates were mainly composed of triangular and truncated triangular shape. The edge is about 170 nm. X-ray diffraction analyses indicated that the gold nameplates were pure single crystals with {111} planes as their basal planes. The growth mechanisms on synthesis of chitosan-mediated gold nanoplate were discussed. Under optimum conditions the SPR absorption peak of gold nanoplate in-plane dipolar is 920 nm. The experiment results showed that the near-infrared SPR absorption peak and the absorption intensity can be effectively controlled by controlling the amounts of chitosan and gold seeds, water bath temperature and bath time.

Key words: gold nanoplate, chitosan, surface plasmon resonance absorption

Cite this article

Yang Chuanxiao, Sun Xiangying, Liu Bin. Controllable Synthesis of Chitosan-Mediated Gold Nanoplate and the Growth Mechanisms[J]. Acta Chimica Sinica, 2012, 70(03): 259-264.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

1 Zhang, L.; Huang, C. Z.; Li, Y. F.; Li, Q. Cryst. Growth Des. 2009, 9, 3211.

2 Pérez-Juste, J.; Pastoriza-Santos, I.; Liz-Marzán, L. M.; Mulvaney, P. Coord. Chem. Rev. 2005, 249, 1870.

3 Wang, Y.; Li, Y. F.; Wang, J.; Sang, Y.; Huang, C. Z. Chem. Commun. 2010, (46), 1332.

4 Wang, J.; Wu, H.; Huang, C.-Z. Sci. China, Ser. B 2008, 38, 929 (in Chinese). (王健, 吴昊, 黄承志, 中国科学B 辑: 化学, 2008, 38, 929.)

5 Guo, B.; Shan, W.-W.; Luo, J.-S.; Tang, Y.-J.; Cheng, J.-P. Acta Chim. Sinica 2008, 66, 1435 (in Chinese). (郭斌, 单雯雯, 罗江山, 唐永建, 程建平, 化学学报, 2008, 66, 1435.)

6 Li, C.; Cai, W.; Cao, B.; Sun, F.; Li, Y.; Kan, C.; Zhang, L. Adv. Funct. Mater. 2006, 16, 83.

7 Chen, C.; Hsu, C.; Kuo, P. Langmuir 2007, 23, 6801.

8 Wang, L. Y.; Wu, X. Z.; Li, X. N.; Wang, L.; Pei, M. S.; Tao, X. T. Chem. Commun. 2010, (46), 8422.

9 Huang, H. Z.; Yang, X. R. Biomacromolecules 2004, 5,2340.

10 Wang, Y.; Li, Y. F.; Huang, C. Z. J. Phys. Chem. C 2009, 113, 4315.

11 Wu, L. L.; Shi, C. S.; Tian, L. F.; Zhu, J. J. Phys. Chem. C 2008, 112, 319.

12 Guo, R.; Zhang, L. Y.; Zhu, Z. S.; Jiang, X. Q. Langmuir 2008, 24, 3459.

13 Ding, Y.; Gu, G.; Xia, X. H.; Huo, Q. J. Mater. Chem. 2009, 19, 795.

14 Wang, W.; Cui, H. J. Phys. Chem. C 2008, 112, 10759.

15 Yang, K.; Wang, X.; Zhou, Z.; Xu, J.; Weng, J.; Zhang, Q. IET Nanobiotechnol. 2007, 1, 107.

16 Beeram, S. R.; Zamborini, F. P. ACS Nano 2010, 4(7), 3633.

17 Beeram, S. R.; Zamborini, F. P. J. Am. Chem. Soc. 2009, 131(33), 11689.

18 Aslan, K.; Lakowicz, J. R.; Geddes, C. D. J. Phys. Chem. B 2005, 109, 6247.

19 Zhang, L. Ph.D. Dissertation, Southwest University, 2010, 34 (in Chinese). (张力, 博士论文, 西南大学, 2010, 34.)

20 Salzemann, C.; Lisiecki, L.; Urban, J.; Pileni, M. P. Langmuir 2004, 20, 11772.

[1]	Yanyu Yang, Xing Wang, Decheng Wu. Chitosan-Based High-Mechanical Double-Network Hydrogels: Construction, Modulation and Applications [J]. Acta Chimica Sinica, 2021, 79(1): 1-9.
[2]	Song Guangjie, Wu Tiaodi, Liu Fuxin, Zhang Binyan, Liu Xiuhui. Electrochemical Detection of Xanthine and Study for the Inhibition of Uric Acid Based on Chitosan/Nitrogen Doped Reduced Graphene Oxide Modified Electrode [J]. Acta Chimica Sinica, 2020, 78(1): 82-88.
[3]	Li Tiantian, Zhao Jikuan, Li Yao, Quan Zhenlan, Xu Jie. Synthesis and Electrochemical Properties of Nitrogen-Doped Partially Graphitized Carbon/Cobalt Iron Oxides Composite [J]. Acta Chim. Sinica, 2017, 75(5): 485-493.
[4]	Ran Maoshuang, Shi Dongjian, Dong Hanxing, Chen Mingqing, Zhao Zengliang. Glucose Responsive Bio-based Polyelectrolyte Capsules by Layer-by-Layer Assembly: Synthesis and Properties [J]. Acta Chim. Sinica, 2015, 73(10): 1047-1054.
[5]	Liu Shuilian, Zhou Yang, Chen Fuhua, Zhu Shoujin, Su Feng, Li Suming. Rheological Properties, Drug Release Behavior and Cytocompatibility of Novel Hydrogels Prepared from Carboxymethyl Chitosan [J]. Acta Chim. Sinica, 2015, 73(1): 47-52.
[6]	Zhang Qian, Wu Shuyao, He Maowei, Zhang Ling, Liu Yang, Li Jinghong, Song Xi-Ming. Preparation and Bioelectrochemical Application of Gold Nanoparticles-Chitosan-Graphene Nanomaterials [J]. Acta Chimica Sinica, 2012, 70(21): 2213-2219.
[7]	Lin Youwen, Li Lifan, Li Guangwen. Preparation and Properties of Temperature and pH Sensitive Chitosan Supramolecular Gel Based on Host-guest Interaction of Cucurbit[8]uril [J]. Acta Chimica Sinica, 2012, 70(21): 2246-2250.
[8]	Gao Qikuan, Wang Kunjie, Wang Xicun. Study on Syntheses and Anticoagulant Action of Rare Earth Nano-oxides/TDI-CS Hybrid Materials [J]. Acta Chimica Sinica, 2012, 70(02): 207-211.
[9]	Zhang Jun, Li Yunping, Zhao Bangtun. Non-noble Metallic Fe Catalyst Systems for the Reductive Carbonylation of Nitrobenzene [J]. Acta Chimica Sinica, 2012, 70(01): 35-38.
[10]	ZHANG Li-Na, GUO Zhi-Hui, ZHENG Xing-Wang, WANG Rong, MENG Mei-Rong, QU Ying-Juan, LIU Quan-Hong, YAO Sha. Synthesis of Biocompatible Chitosan-doped SiO₂ Nanoparticles and Its Application for DNA Adsorption [J]. Acta Chimica Sinica, 2011, 69(20): 2486-2492.
[11]	ZHAO Qian, QIU Dong-Fang, WANG Xiao-Yan, LIU Tian-Xi. Morphology and Mechanical Properties of Chitosan/ Graphene Oxide Nanocomposites [J]. Acta Chimica Sinica, 2011, 69(10): 1259-1263.
[12]	CHEN Ri-Yao, CHEN Shen, ZHENG Xi, CHEN Xiao, ZHANG Ling, ZHANG Su-Zhen. Preparation and Characterization of CuTsPc-SA/mCS Bipolar Membrane [J]. Acta Chimica Sinica, 2010, 68(06): 576-582.
[13]	YANG Hu. A New Method for Measuring the Grafting Ratio of Chitosan-graft-polyacrylamide [J]. Acta Chimica Sinica, 2009, 67(8): 879-882.
[14]	. Preparation and Characterization of Novel Biodegradable Multifunctional Microspheres [J]. Acta Chimica Sinica, 2008, 66(19): 2178-2183.
[15]	FU, Ping YUAN, Ruo* CHAI, Ya-Qin YIN, Bing CAO, Shu-Rui CHEN, Shi-Hong LI, Wan-Yang . Glucose Biosensor Based on Chitosan-nano Gold/nano-Prussian Blue/L-cysteine Modified Gold Electrode [J]. Acta Chimica Sinica, 2008, 66(15): 1796-1802.

壳聚糖介质金纳米盘的可控合成及生长机理

Controllable Synthesis of Chitosan-Mediated Gold Nanoplate and the Growth Mechanisms

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments