Preparation of the Ordered Mesoporous Carbon/Fe3O4 and Its Application for the Direct Electrochemistry of Hemoglobin

doi:10.6023/A1107302

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (05): 617-623 .DOI: 10.6023/A1107302 Previous Articles Next Articles

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有序中孔炭/四氧化三铁复合材料的制备及其用于血红蛋白的电化学研究

郑静^a,b, 赵家昌^a, 龚晨^a, 刘萍^a, 陈瑜^a, 黄焕^a, 何品刚^b, 方禹之^b

a 上海工程技术大学化学化工学院上海 201620;
b 华东师范大学化学系上海 200062

投稿日期:2011-07-30 修回日期:2012-01-12 发布日期:2012-03-17
通讯作者: 郑静 E-mail:kkzhengjing707@163.com
基金资助:
国家自然科学基金(No. 20675031)和上海市教委(No. 09YZ374)资助项目.

Preparation of the Ordered Mesoporous Carbon/Fe₃O₄ and Its Application for the Direct Electrochemistry of Hemoglobin

Zheng Jing^a,b, Zhao Jiachang^a, Gong Chen^a, Liu Ping^a, Chen Yu^a, Huang Huan^a, He Pingang^b, Fang Yuzhi^b

a College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620;
b Department of Chemistry, East China Normal University, Shanghai 200062

Received:2011-07-30 Revised:2012-01-12 Published:2012-03-17
Supported by:
Project supported by the National Natural Science Foundation of China (No. 20675031) and Innovation Program of Shanghai Municipal Education Commission (No. 09YZ374).

The novel magnetic composites of ordered mesoporous carbon/Fe₃O₄ were prepared with a micro-wetness impregnation method. The composites were characterized by transmission electron microscope and X-ray diffraction. Hemoglobin was immobilized onto the surface of the composites, and was shown to keep its biological activity well. The electrochemical behavior of Hb was studied, and a pair of well-defined, quasi-reversible cyclic voltammetric redox peaks was obtained, which was characteristics of Hb Fe(III)/Fe(II) redox couples. The formal potential (E⁰'), the electron transfer number (n), and transfer coefficient (α) were calculated to be －0.306 V, 1.226 and 0.51, respectively. The average apparent heterogeneous electron transfer rate constant (K_S) obtained for Hb was 0.0144 s^-1. Linear sweep voltammetric measurement of Hb indicated that the peak currents of Hb were linear to its concentration ranging from 3.00×10^-6 to 1.50×10^-4 mol/L with the detection limits of 0.270×10^-6 mol/L.

Key words: ordered mesoporous carbon, ferriferrous oxide, preparation, hemoglobin, direct electrochemistry

Cite this article

Zheng Jing, Zhao Jiachang, Gong Chen, Liu Ping, Chen Yu, Huang Huan, He Pingang, Fang Yuzhi. Preparation of the Ordered Mesoporous Carbon/Fe₃O₄ and Its Application for the Direct Electrochemistry of Hemoglobin[J]. Acta Chimica Sinica, 2012, 0(05): 617-623 .

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有序中孔炭/四氧化三铁复合材料的制备及其用于血红蛋白的电化学研究

Preparation of the Ordered Mesoporous Carbon/Fe₃O₄ and Its Application for the Direct Electrochemistry of Hemoglobin

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