Synthesis and Spectra Analyses of Eu(III) Binary Complexes with Polycarboxylic Acid

doi:10.6023/A1107192

Acta Chimica Sinica ›› 2012, Vol. 0 ›› Issue (05): 679-682 .DOI: 10.6023/A1107192 Previous Articles

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多羧酸根铕二元配合物的合成及光谱分析

张尽力, 赵利平, 罗炫, 杜凯

中国工程物理研究院激光聚变研究中心绵阳 621900

投稿日期:2011-07-19 修回日期:2011-09-22 发布日期:2011-11-29
通讯作者: 杜凯 E-mail:zhangjinli19840212@163.com
基金资助:
国家高技术发展基金(No. 2011AA8043021)资助项目.

Synthesis and Spectra Analyses of Eu(III) Binary Complexes with Polycarboxylic Acid

Zhang Jinli, Zhao Liping, Luo Xuan, Du Kai

Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900

Received:2011-07-19 Revised:2011-09-22 Published:2011-11-29
Supported by:
Project was supported by the National High Technology Development Program of China (No. 2011AA8043021).

Using trimesic acid, mellitic acid and 1,2,3,4,5,6-cyclohexanehexacarboxylic acid as ligand, three Eu(III) binary complexes, Eu(BTC)·2H₂O, Eu₂(MTA)·4H₂O and Eu₂(CCA)·4H₂O were synthesized. Their chemical compositions were characterized by elemental analyses, IR and inductively coupled plasma atomic emission spectrometer (ICP) techniques, and the results showed an agreement with the proposed structures. The photophysical properties (excitation spectra, emission spectra, emission lifetime, emission quantum yield) were investigated by using luminescence spectroscopy at room temperature. The results showed that all the three complexes exhibit strong red fluorescence under ultraviolet light and the photoluminescence properties of Eu₂(MTA)·4H₂O (emission quantum yield＝10.25%, emission lifetime＝ 0.36 ms) was superior to the others. The phenomenon was interpreted by electron-effect and energymatching mechanism. Additionally, the thermal stability of the Eu(III) binary complexes was studied, and the main decomposition points of the complexes were higher than other β-diketonate complexes.

Key words: rare earth, Eu(III) complex, photoluminescence

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Zhang Jinli, Zhao Liping, Luo Xuan, Du Kai. Synthesis and Spectra Analyses of Eu(III) Binary Complexes with Polycarboxylic Acid[J]. Acta Chimica Sinica, 2012, 0(05): 679-682 .

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1 Ji, C.-H.; Zhang, P.; Han, P.-F. Bull. Chim. Sin. 2008, 10, 746 (in Chinese). (季彩宏, 张萍, 韩萍芳, 化学通报, 2008, 10, 746.)

2 Zhan, X.-H.; Zhao, X.-H.; Zhan, H.-H. New Chem. Mater.2007, 35, 2 (in Chinese). (湛雪辉, 赵学辉, 湛含辉, 化工新型材料, 2007, 35, 2.)

3 Han, H.; Chen, Z.-M.; Wang, S.-P. J. Hebei Normal Univ.2010, 31, 64 (in Chinese). (韩华, 陈志民, 王淑萍, 河北师范大学学报, 2010, 31,64.)

4 Wang, J.-Y.; Gao, Y.-Z.; Wang, T. Spectros. Spectral Anal.2008, 28, 2912 (in Chinese). (王继业, 高元哲, 王涛, 光谱学与光谱分析, 2008, 28,2912.)

5 Zhang, Q.-P.; Du, H.-Y.; Sun, J.-Y. New Chem. Mater.2007, 35, 20 (in Chinese). (张泉平, 杜海燕, 孙家跃, 化工新型材料, 2007, 35, 20.)

6 Zhou, Z.-C.; Ruan, J.-M.; Zou, J.-P. J. Chin. Soc. Rare Earths 2004, 22, 1 (in Chinese). (周忠诚, 阮建明, 邹俭鹏, 中国稀土学报, 2004, 22, 1.)

7 Wang, Z.-X.; Chen, H.; Tan, M.-J. Spectrosc. Spectral Anal.2005, 25, 1106 (in Chinese). (王正祥, 陈洪, 谭美军, 光谱学与光谱分析, 2005, 25,1106.)

8 Yuan, J.-X.; Hu, M.-L.; Chen, Y.-Q. Chin. Rare Earths2000, 21, 8 (in Chinese). (袁继新, 胡茂林, 程亚倩, 稀土, 2000, 21, 8.)

9 Zhao, G.-H.; Gao, J.-Z.; Zhao, J.; Teng, X.-L.; Kang, J.-W. Synth. React. Inorg. Met.-Org. Chem. 1998, 28, 1405.

10 Gao, J.-Z.; Zhao, G.-H.; Kang, J.-W. Talanta 1995, 42,1497.

11 Zhao, Y.-L.; Zhao, F.-Y. J. Chin. Soc. Rare Earth 2001, 19, 398 (in Chinese). (赵永亮, 赵凤英, 中国稀土学报, 2001, 19, 398.)

12 Zhang, X. J. Lumin. 2010, 130, 1060.

13 Weissan, S. I. J. Chem. Phys. 1942, 10, 214.

14 Dexter, D. L. J. Chem. Phys. 1953, 21, 836.

15 Yuan, J.-B.; Li, J.-H.; Leung, L. M. Acta Chim. Sinica 2004,62, 2282 (in Chinese). (袁继兵, 李嘉航, 梁万里, 化学学报, 2004, 62, 2282.)

16 Kazuki, N.; Yasuchika, H.; Hideki, K. J. Alloys Compd.2006, 408～412, 771.

17 Koen, B. Chem. Rev. 2009, 109, 4283.

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多羧酸根铕二元配合物的合成及光谱分析

Synthesis and Spectra Analyses of Eu(III) Binary Complexes with Polycarboxylic Acid

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