Determination of Small Molecular Aldehydes in Cigarette Smoke by Extraction and Derivatization in Single Drop

doi:10.6023/A1202221

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (12): 1332-1336.DOI: 10.6023/A1202221 Previous Articles Next Articles

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单液滴萃取衍生化技术用于烟气中小分子醛类物质的分析

朱逢君^a, 张菁^a, 郑赛晶^b, 刘百战^b, 郭寅龙^a

a 中国科学院上海有机化学研究所上海质谱中心上海 200032;
b 上海烟草(集团)公司上海 200082

投稿日期:2012-02-22 修回日期:2012-04-19 发布日期:2012-04-20
通讯作者: 张菁, 郭寅龙 E-mail:zhangjing@sioc.ac.cn; ylguo@sioc.ac.cn
基金资助:
国家自然科学基金(Nos. 20902104, 21072215, 21172250)资助项目

Determination of Small Molecular Aldehydes in Cigarette Smoke by Extraction and Derivatization in Single Drop

Zhu Fengjun^a, Zhang Jing^a, Zheng Saijing^b, Liu Baizhan^b, Guo Yinlong^a

a Shanghai Mass Spectrometry Center, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032;
b Shanghai Tobacco Group Company, Shanghai 200082

Received:2012-02-22 Revised:2012-04-19 Published:2012-04-20
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 20902104, 21072215, 21172250).

Extraction and derivatization in single drop (EDSD) coupled to matrix-assisted laser desorption/ionization Fourier transform ion cyclotron resonance mass spectrometry (MALDI-FTICR-MS) was utilized to determine small molecular aldehydes in single puff smoke. Through employing Girard's reagent T as derivatization reagent, small molecular aldehydes (SMAs) transformed into quaternary ammonium salt, and the sensitivity of analysis for SMAs was significantly improved. Using this method, acetaldehyde and acrolein in single puff smoke were easily determined. This approach with an automatic potential provided a simple, rapid, and accurate procedure for the determination of SMAs in smoke.

Key words: extraction and derivatization in single drop, Girard’s reagent T, cigarette smoke, aldehyde, quantification

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Zhu Fengjun, Zhang Jing, Zheng Saijing, Liu Baizhan, Guo Yinlong. Determination of Small Molecular Aldehydes in Cigarette Smoke by Extraction and Derivatization in Single Drop[J]. Acta Chimica Sinica, 2012, 70(12): 1332-1336.

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单液滴萃取衍生化技术用于烟气中小分子醛类物质的分析

Determination of Small Molecular Aldehydes in Cigarette Smoke by Extraction and Derivatization in Single Drop

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