Synthesis and Fluorescence Study of the Novel PbS@P(NIPAM-co-TSt) Complexes

doi:10.6023/A12030028

Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (16): 1704-1708.DOI: 10.6023/A12030028 Previous Articles Next Articles

Full Papers

PbS@P(NIPAM-co-TSt)功能复合物的合成及其荧光性能研究

王成志, 李润, 成浩, 姜韬, 殷明, 陈欣, 江金强, 刘晓亚

江南大学化学与材料工程学院无锡 214122

投稿日期:2012-03-20 发布日期:2012-06-11
通讯作者: 江金强, 刘晓亚
基金资助:
项目受国家自然科学基金(Nos. 20704017, 50973044)和2010年度新世纪优秀人才支持计划(NCET-10-0452)资助.

Synthesis and Fluorescence Study of the Novel PbS@P(NIPAM-co-TSt) Complexes

Wang Chengzhi, Li Run, Cheng Hao, Jiang Tao, Yin Ming, Chen Xin, Jiang Jinqiang, Liu Xiaoya

School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122

Received:2012-03-20 Published:2012-06-11
Supported by:
Project supported by the National Natural Science Foundation of China (Nos. 20704017, 50973044) and the Program for New Century Excellent Talents in University (NCET-10-0452).

Nowadays, the environmental sensitive polymer complexes play a more and more important role in the field of science study. Herein we demonstrate that the alkylisothiouronium-containing styrene monomer (TSt) was synthesized via 4-vinylbenzyl chloride and thiourea, which could be copolymerized with NIPAM to synthesize the temperature sensitive polymer of P(NIPAM-co-TSt) by radical polymerization. Then, the PbS complexes of PbS@P(NIPAM-co-TSt) were prepared on the basis of the interaction between alkylisothiouronium and Pb(AcO)₂·3H₂O in the aqueous solution of weakly alkaline. Its chemical structure was characterized by detail. For example, Fourier transformation infrared (FTIR), nuclear magnetic resonance (¹H NMR), XRD (X-ray diffraction) and fluorescence spectrum to ensure the synthesis of PbS@P(NIPAM-co-TSt) complex. Besides, nanometer granularity apparatus, dynamic light scattering (DLS) and transmission electron microscope (TEM) were employed to survey the size and physiognomy of polymer micelles and complexes. The photoluminescence properties were also studied. It was found that PbS@P(NIPAM-co-TSt) complex exhibits characteristic fluorescence intensity, which was promoted by the PbS nanoparticles. Meanwhile, its fluorescence intensity increased along with the temperature, which very consists with the LCST (lower critical solution temperature) characteristic of PNIPAM. The results indicated that its fluorescene intensity would go up with the addition of the complex’s concentration and the raising of the temperature. The diameter of PbS@P(NIPAM-co-TSt) complex can also be reduced obviously by introducing the PbS nanoparticles to the system. What is more, its diameter had a declining trend when the temperature exceeded the LCST of it and kept stable in the end. Thus, on the one hand, these kinds of complexes possess the properties in both polymers and nanoparticles, such as PbS. On the other hand, we think that such environmental sensitive complexes must have a bright future, and also could make a lot of potential applications as optical materials in a great many areas, such as biological, medical science, cells, chemistry and so on.

Key words: alkylisothiouronium, PNIPAM, nanoparticles, complexes, temperature sensitive

Cite this article

Wang Chengzhi, Li Run, Cheng Hao, Jiang Tao, Yin Ming, Chen Xin, Jiang Jinqiang, Liu Xiaoya. Synthesis and Fluorescence Study of the Novel PbS@P(NIPAM-co-TSt) Complexes[J]. Acta Chimica Sinica, 2012, 70(16): 1704-1708.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

References

[1] Priester, C.; Lannoo, M. Curr. Opin. Solid State Mater. Sci. 1997, 2, 716.

[2] Nikodem, T.; Dominik, J.; Han, M. Y.; Julius, V. G. Prog. Polym. Sci. 2009, 34, 393.

[3] Poznyak, S. K.; Talapin, D. V.; Shevchenko, E. V.; Weller, H. Nano Lett. 2004, 4, 693.

[4] Michael, T. Ann. Phys. 2004, 13, 5.

[5] Zhang, B. B.; Xing, D.; Lin, C.; Guo, F. F.; Zhao, P.; Wen, X. J.; Bao, Z. H.; Shi, D. L. J. Nanopart. Res. 2011, 13, 2407.

[6] Lee, D. K.; Lee, Y.-k. Macromol. Res. 2010, 10, 1007.

[7] Chen, Y.; Rosenzweig, Z. Anal. Chem. 2002, 74, 5132.

[8] Koh, W.-k.; Saudari, S. R.; Fafarman, A. T.; Kagan, C. R.; Murray, C. B. Nano Lett. 2011, 11, 4764.

[9] Wang, C.-W.; Oskooei, A.; Sinton, D.; Moffitt, M. G. Langmuir 2010, 26, 716.

[10] Wang, M. F.; Felorzabihi, N.; Guerin, G.; Haley, J. C.; Scholes, G. D.; Winnik, M. A. Macromolecules 2007, 40, 6377.

[11] Wang, M. F.; Zhang, M.; Qian, J. S.; Zhao, F.; Shen, L.; Scholes, G. D.; Winnik, M. A. Langmuir 2009, 25, 11732.

[12] Yu, X. Y.; Liao, J. Y.; Qiu, K. Q.; Kuang, D. B.; Su, C. Y. Acs Nano 2010, 10, 1021.

[13] Zhu, L. J.; Shi, Y. F.; Tu, C. L.; Wang, R. B.; Pang, Y.; Qiu, F.; Zhu, X. Y.; Yan, D. Y.; He, L.; Jin, C. Y.; Zhu, B. S. Langmuir 2010, 26, 8875.

[14] Yang, Y.-C.; Lu, H.-H.; Wang, W.-T.; Liau, I. Anal. Chem. 2011, 83, 8267.

[15] Yusuf, H.; Kim, W.-G.; Lee, D. H.; Guo, Y. Y.; Moffitt, M. G. Langmuir 2007, 23, 868.

[16] Wang, C.-W.; Oskooei, A.; Sinton, D.; Moffitt, M. G. Langmuir 2010, 26, 716.

[17] Agrawal, M.; Rubio-Retama, J.; Zafeiropoulos, N. E.; Gaponik, N.; Gupta, S.; Cimrova, V.; Lesnyak, V.; Lopez-Cabarcos, E.; Tzavalas, S.; Rojas-Reyna, R.; Eychmuller, A.; Stamm, M. Langmuir 2008, 24, 9820.

[18] Hou, Y.; Ye, J.; Gui, Z.; Zhang, G. Z. Langmuir 2008, 24, 9682.

[19] Janczewski, D.; Tomczak, N.; Han, M.-Y. Macromolecules 2009, 42, 1801.

[20] Guo, J.; Yang, W. L.; Wang, C. C.; He, J.; Chen, J. Y. Chem. Mater. 2006, 18, 5554.

[21] Ye, J.; Hou, Y.; Zhang, G. Z.; Wu, C. Langmuir 2008, 24, 2727.

[22] Ye, F. M.; Wu, C. F.; Jin, Y. H.; Chan, Y.-H.; Zhang, X. J.; Chiu, D. T. J. Am. Chem. Soc. 2011, 133, 8146.

[23] Lao, U. L.; Mulchandani, A.; Chen, W. J. Am. Chem. Soc. 2006, 128, 14756.

[24] Shu, Q. Z.; Chen, X.; Chen, K. H.; Jiang, J. Q.; Ni, Z. B.; Zhang, H. W.; Liu, X. Y.; Chen, M. Q. Acta Phys.-Chim. Sin. 2010, 26, 2845. (舒巧珍, 陈欣, 陈开花, 江金强, 倪忠斌, 张红武, 刘晓亚, 陈明清, 物理化学学报, 2010, 26, 2845.)

[25] Carrot, G.; Scholz, S. M.; Plummer, C. J. G.; Hilborn, J. G.; Hedrick, J. L. Chem. Mater. 1999, 11, 3571.

[26] Nair, P. S.; Radhakrishnan, T.; Revaprasadu, N.; Kolawole, G. A.; O'Brien, P. Chem. Commun. 2002, (6), 564. Dong, Y. M.; Lu, J. M.; Xu, Q. F. J. Macromol. Sci. 2008, 45, 37.

PbS@P(NIPAM-co-TSt)功能复合物的合成及其荧光性能研究

Synthesis and Fluorescence Study of the Novel PbS@P(NIPAM-co-TSt) Complexes

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Xuelu Ma, Meng Li, Ming Lei. Trinuclear Transition Metal Complexes in Catalytic Reactions [J]. Acta Chimica Sinica, 2023, 81(1): 84-99.
[2]	Qi Zhang, Mengyun Jiang, Tianyi Liu, Yixun Zeng, Shengwei Shi. Thin Films and Devices of Evaporable Spin Crossover Complexes [J]. Acta Chimica Sinica, 2022, 80(9): 1351-1363.
[3]	Xufa He, Kangle Jia, Longfei Yu, Mingjie Liu, Xiaoshan Zheng, Huanling Li, Jinlan Xin, Linjia Huang. pH-Responsive Pickering Emulsions Synergistically Stabilized by Maleopimaric Acid and Alumina Nanoparticles [J]. Acta Chimica Sinica, 2022, 80(6): 765-771.
[4]	Ruomei Liu, Yanhui Feng, Zhuo Li, Shan Lu, Tianyong Guan, Xingjun Li, Yan Liu, Zhuo Chen, Xueyuan Chen. A Novel Near-infrared Responsive Lanthanide Upconversion Nanoplatform for Drug Delivery Based on Photocleavage of Cypate^※ [J]. Acta Chimica Sinica, 2022, 80(4): 423-427.
[5]	Jinyuan Zhao, Qian Zhang, Jian Wang, Qi Zhang, Heng Li, Yaping Du. Advances in the Scavenging Materials for Reactive Oxygen Species [J]. Acta Chimica Sinica, 2022, 80(4): 570-580.
[6]	Junmin Chen, Chengqian Cui, Hanlin Liu, Guodong Li. Study on the Selective Hydrogenation of Quinoline Catalyzed by Composites of Metal-Organic Framework and Pt Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(4): 467-475.
[7]	Yanran Li, Zigui Wang, Zhaohui Tang. Water Soluble IR-780 Polymer for Mitochondria-Targeted Photodynamic Therapy^※ [J]. Acta Chimica Sinica, 2022, 80(3): 291-296.
[8]	Jinghuang Chen, Tian Meng, Lie Wu, Hengchong Shi, Fan Yang, Jian Sun, Xiurong Yang. Study on Synthesis and Antibacterial Properties of AgNPs@ZIF-67 Composite Nanoparticles^※ [J]. Acta Chimica Sinica, 2022, 80(2): 110-115.
[9]	Ju Huang, Zhen Li, Zhihong Liu. Functionalized Upconversion Nanoparticles for Disassembly of β‑Amyloid Aggregation with Near-Infrared Excitation [J]. Acta Chimica Sinica, 2021, 79(8): 1049-1057.
[10]	Heqi Gao, Di Jiao, Hanlin Ou, Jingtian Zhang, Dan Ding. High Performance Aggregation-Induced Emission Nanoprobes for Image-Guided Cancer Surgery [J]. Acta Chimica Sinica, 2021, 79(3): 319-325.
[11]	Xiaomeng Zhang, Xiya Li, Wanfeng Xiong, Hongfang Li, Rong Cao. Ultrafine Platinum Nanoparticles Derived from Supramolecular Crystal for Catalytic Hydrogenation of Nitroarenes [J]. Acta Chimica Sinica, 2021, 79(2): 180-185.
[12]	Tiankun Zhao, Peng Wang, Mingyu Ji, Shanjia Li, Mingjun Yang, Xiuying Pu. Post-Synthetic Modification Research of Salan Titanium bis-Chelates via Sonogashira Reaction [J]. Acta Chimica Sinica, 2021, 79(11): 1385-1393.
[13]	Wang Peipei, Liang Tao, Zuo Miaomiao, Li Zhen, Liu Zhihong. A Ratiometric Upconversion Nanoprobe for Detection of HNO Based on Luminescence Resonance Energy Transfer [J]. Acta Chimica Sinica, 2020, 78(8): 797-804.
[14]	Yan Tao, Liu Zhenhua, Song Xinyue, Zhang Shusheng. Construction and Development of Tumor Microenvironment Stimulus-Responsive Upconversion Photodynamic Diagnosis and Treatment System [J]. Acta Chimica Sinica, 2020, 78(7): 657-669.
[15]	Jin Fengming, Dong Hongwei, Zhao Yan, Zhuang Shengli, Liao Lingwen, Yan Nan, Gu Wanmiao, Zha Jun, Yuan Jinyun, Li Jin, Deng Haiteng, Gan Zibao, Yang Jinlong, Wu Zhikun. Module Replacement of Gold Nanoparticles by a Pseudo-AGR Process [J]. Acta Chimica Sinica, 2020, 78(5): 407-411.