Chemical Modification of Carbon Nanotubes and Tribological Properties as Lubricant Additive

Acta Chimica Sinica ›› 2004, Vol. 62 ›› Issue (14): 1367-1372. Previous Articles

碳纳米管的化学修饰以及作为润滑油添加剂的摩擦学性能研究

陈传盛, 陈小华, 刘天贵, 杨东, 张刚, 易国军

湖南大学材料科学与工程学院, 长沙, 410082

投稿日期:2003-10-09 修回日期:2004-03-18 发布日期:2014-02-17
通讯作者: 陈小华,E-mail:Hudacxh@sohu.com;jxccs1934@yahoo.com.cn;Tel:0731-8822663. E-mail:Hudacxh@sohu.com;jxccs1934@yahoo.com.cn
基金资助:
国家自然科学基金(Nos.50372020,59972031)和湖南省自然科学基金(No.01JJY2052)及湖南大学重大基金资助项目.

Chemical Modification of Carbon Nanotubes and Tribological Properties as Lubricant Additive

CHEN Chuan-Sheng, CHEN Xiao-Hua, LIU Tian-Gui, YANG Dong, ZHANG Gang, YI Guo-Jun

College of Materials Science and Engineering, Hunan University, Changsha 410082

Received:2003-10-09 Revised:2004-03-18 Published:2014-02-17

Abstract

The multi-walled carbon nanotubes were purified by sulfuric acid and nitric acid.The surface of carbon nanotubes was modified with stearic acid.The tribological behavior of stearic acid coated carbon nanotubes as lubricant additive was investigated.The results showed that the surface of carbon nanotubes was coated with a modified layer of stearic acid.It was proved that a covalent bond was formed by chemical reaction between hydroxylic groups on the surface of carbon nanotubes and carboxylic groups of stearic acid.Stearic acid coated carbon nanotubes as additive effectively improved the friction-reduction and antiwear ability of lubricant.

Key words: carbon nanotube, surface modification, lubricant additive, tribological property

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CHEN Chuan-Sheng, CHEN Xiao-Hua, LIU Tian-Gui, YANG Dong, ZHANG Gang, YI Guo-Jun. Chemical Modification of Carbon Nanotubes and Tribological Properties as Lubricant Additive[J]. Acta Chimica Sinica, 2004, 62(14): 1367-1372.

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[1] Jiang, X.-Y.; Wang, X.-Y.; Chen, Y.-Z. Acta Petrolel Sinica 2002, 18, 61 (in Chinese).(蒋小明,王小勇,陈月珠,石油学报,2002,18,61.)
[2] Zhang, Z.-F.; Liu, W.-M.; Que, Q.-J. Wear 2001, 248, 48.
[3] Chen, S.; Liu, W.-M.; Ou, Z.-W.; Xu, B.-S. Tribology 2001, 21, 344 (in Chinese).(陈爽,刘维民,欧忠文,徐滨士,摩擦学报,2001,21,
[4] Treacy, M. M. J.; Ebbesen, T. W.; Gibsom, J. M. Nature 1996, 381, 678.
[5] Salvetat, J. P.; Bonard, J. M.; Thomson, N. H. Appl. Phys. 1999, 69, 255.
[6] Comwell, C. F.; Wille, L. T. J. Chem. Phys. 1998, 109, 763.
[7] Jiang, Q.; Liu, B.-C.; Qu, M.-Z.; Zhou, G.-M. Acta Chim. Sinica 2002, 60, 1539 (in Chinese).(江奇,刘宝春,瞿美臻,周固民,化学学报,2002,60,1539. )
[8] Chen, W.-X.; Tu, J.-P.; Ma, X.-C.; Xu, Z.-D. Acta Chim. Sinica 2002, 60, 1722 (in Chinese).(陈卫祥,涂江平,马晓春,徐铸德,化学学报,2002,60,1722. )
[9] Zhu, S.-W.; Jia, Z.-J. Function Material 2000, 31, 119 (inChinese).(朱绍文,贾志杰,功能材料,2000,31,119.)
[10] Wang, L.-Y.; Tu, J.-P.; Yang, Z.-Y.; Zhang, X.-B.; Chen, W.-X.; Lu, H.-M. Chin. J. Nonferrous Metals 2001,11, 367 (in Chinese).(王浪云,涂江平,杨志友,张孝彬,陈卫祥,卢焕明,中国有色金属学报,2001,11,367.)
[11] Chen, X.-H.; Li, D.-Y.; Li, X.-Q.; Zhang, Z.-H.; Wang,J.-X.; Li, W.-Z. Tribology 2002, 22, 6 (in Chinese).(陈小华,李得意,李学谦,张振华,王健雄,李文铸,摩擦学报,2002,22,6.)
[12] Cao, M.-S.; Liu, H.-T.; Li, C.-S.; Chen, Y.-J. Chin. Surf. Eng. 2002, 57, 32 (in Chinese).(曹茂盛,刘海涛,李辰砂,陈玉金,中国表面工程,2002,57,32.)
[13] Tan, P.-H.; Zhang, S.-L.; Yue, K.-T. J. Raman. Spectrosc. 1997, 28, 369.
[14] Ma, W.-Y.; Tian, Q.; Cao, M.-S.; Gao, Z.-J.; Chen, Y.J.; Zhu, J. China Powder Science and Technology 2002, 2, 30 (in Chinese).(马文有,田秋,曹茂盛,高正娟,陈玉金,朱静,中国粉体技术,2002,2,30.)
[15] Gupta, B. K.; Bhushan, B. Lu ubr. Eng. 1994, 50, 524.
[16] Dou, L.-X.; Gong, H.-D.; Lu, Z.-J.; Cui, Z.-P.; Liu, J.D.; Wang, B. Lubrication and Confinement 2002, 5, 23 (in Chinese).(豆立新,龚华栋,吕振坚,崔占平,刘健栋,王斌,润滑与密封,2002,5,23.)

碳纳米管的化学修饰以及作为润滑油添加剂的摩擦学性能研究

Chemical Modification of Carbon Nanotubes and Tribological Properties as Lubricant Additive

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