Research Progress on Triphase Interface Electrocatalytic Carbon Dioxide Reduction

doi:10.6023/A20110540

Acta Chimica Sinica ›› 2021, Vol. 79 ›› Issue (4): 369-377.DOI: 10.6023/A20110540 Previous Articles Next Articles

Review

三相界面电催化二氧化碳还原研究进展

马一宁^a, 施润^a^,^*(), 张铁锐^a^,^b^,^*()

a 中国科学院理化技术研究所中国科学院光化学转换与功能材料重点实验室北京 100190
b 中国科学院大学材料科学与光电工程中心北京 100049

投稿日期:2020-11-25 发布日期:2021-01-14
通讯作者: 施润, 张铁锐

作者简介:

马一宁, 中国科学院理化技术研究所硕士研究生, 本科毕业于山东大学化学与化工学院化学基地班, 2020年进入中国科学院大学攻读材料学硕士学位. 目前在理化所张铁锐课题组从事电催化二氧化碳还原催化剂的设计与合成方面研究.

施润, 中国科学院理化技术研究所项目副研究员, 本科毕业于天津工业大学材料科学与工程学院, 2018年在中国科学院大学取得材料学博士学位. 目前在理化所张铁锐课题组从事能源催化相关研究, 致力于新型光、电催化材料界面特性及反应体系的设计制备, 并将其用于高性能分解水产氢及二氧化碳还原等重要的催化反应之中.

张铁锐, 中国科学院理化技术研究所研究员、博士生导师, 中国科学院光化学转化与功能材料重点实验室主任. 吉林大学化学学士, 吉林大学有机化学博士. 之后, 在德国、加拿大和美国进行博士后研究. 2009年底回国受聘于中国科学院理化技术研究所. 主要从事能量转换纳米催化材料方面的研究, 在Nat. Commun., Adv. Mater., Angew. Chem. Int. Ed., JACS, Chem. Soc. Rev.等期刊上发表SCI论文200余篇, 被引用17000多次, H指数71, 并入选2018~2020科睿唯安“全球高被引科学家”; 申请国家发明专利42项(已授权33项). 2017年当选英国皇家化学会会士.

基金资助:
北京市自然科学基金(2194089); 国家自然科学基金(21902168)

Research Progress on Triphase Interface Electrocatalytic Carbon Dioxide Reduction

Yining Ma^a, Run Shi^a^,^*(), Tierui Zhang^a^,^b^,^*()

a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
b Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Received:2020-11-25 Published:2021-01-14
Contact: Run Shi, Tierui Zhang
About author:
* E-mail: shirun@mail.ipc.ac.cn;
E-mail: tierui@mail.ipc.ac.cn
Supported by:
Beijing Natural Science Foundation(2194089); National Natural Science Foundation of China(21902168)

Electrocatalytic carbon dioxide reduction is the focus and nodus of energy chemistry and catalytic science. As a basic concept in physical chemistry, gas-solid-liquid triphase interface model has been widely studied in electrocatalytic carbon dioxide reduction reaction in recent years, showing many advantages compared with traditional solid-liquid biphase systems. In this review, we discuss the research progress of triphase interface eletrocatalytic carbon dioxide reduction, focused on the classification as well as the principle of triphase interface eletrocatalytic systems. Then, carbon dioxide electroreduction properties of various triphase systems including underwater superaerophilic and gas diffusion layer systems are discussed, with special attention on the influence factors, such as the interfacial diffusion and interfacial wettability of reactants. Finally, we summarize and prospect the existing problems and the future development direction of electrocatalytic carbon dioxide reduction based on triphase systems.

Key words: triphase interface, carbon dioxide reduction, electrocatalysis, mass transfer, wettability

Cite this article

Yining Ma, Run Shi, Tierui Zhang. Research Progress on Triphase Interface Electrocatalytic Carbon Dioxide Reduction[J]. Acta Chimica Sinica, 2021, 79(4): 369-377.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 6

Figure 1. Overview of reaction pathways for CO2 reduction towards different products. CO2, blue; C1 products, yellow; C2 product, red.

Figure 2. Two classical designs of a triphase interface electrocatalytic CO2 reduction system: (a) Underwater superaerophilic system. (b) Gas-diffusion-layer system.

Figure 3. (a) The contact angle of gas product from CO2 reduction. (b) The contact angle of liquid product from CO2 reduction. (c) Schematic illustration of the air-liquid-solid triphase interface when hydrophobic Cu dendrite is placed in water. Reprinted with permission from ref. [28,30]. Copyright © 2019 Tsinghua University Press and Springer-Verlag GmbH Germany. © 2019 Springer Nature Limited.

Figure 4. (a) Schematic illustration of the graphite/carbon nanoparticals/Cu/PTFE electrode for CO2 electroreduction. (b) Schematic illustration of hydrophobic/hydrophilic structure of perfluorinated sulfonic acid ionomer layer. Reprinted with permission from ref. [31,33]. Copyright © 2018, 2020 American Association for the Advancement of Science.

Figure 6. (a) Schematic illustration of the in-situ fluorescence electrochemical spectroscopy measurements. (b) Interfacial CO2 concentration plotted against current density over three types of GDE. Reprinted with permission from ref. [38].

References 65

[1]	Chu, S.; Majumdar, A. Nature 2012, 488,294.
[2]	Windle, C.D.; Perutz, R.N. Coordin. Chem. Rev. 2012, 256,2562.
[3]	Liu, C.; Colon, B.C.; Ziesack, M.; Silver, P.A.; Nocera, D.G. Science 2016, 352,1210.
[4]	Li, Z.J.; Li, G.; Chen, X.L.; Xia, Z.; Yang, B.; Yao, J.N.; Lei, L.C.; Hou, Y. ChemSusChem 2018, 11,2382.
[5]	Choi, K.M.; Kim, D.; Rungtaweevoranit, B.; Trickett, C.A.; Barmanbek, J.T. D.; Alshammari, A.S.; Yang, P.D.; Yaghi, O.M. J. Am. Chem. Soc. 2017, 139,356.
[6]	Hori, Y.; Kikuchi, K.; Murata, A.; Suzuki, S. Chem. Lett. 1986, 6,897.
[7]	Hori, Y.; Murata, A.; Takahashi, R. J. Chem. Soc. Faraday Trans. 1989, 85,2309.
[8]	Saveant, J.M. ChemElectroChem 2016, 3,1967.
[9]	Dufek, E.J.; Lister, T.E.; Stone, S.G.; Mcllwain, M.E. J. Electrochem. Soc. 2012, 159,F514.
[10]	Carroll, J.J.; Slupsky, J.D.; Mather, A.E. J. Phys. Chem. Ref. Data 1991, 20,1201.
[11]	Tackett, B.M.; Gomez, E.; Chen, J.G. Nat. Catal. 2019, 2,381.
[12]	Chi, C.; Juliet, F.K. K.; Stafford, W.S. Chem 2018, 4,2571.
[13]	Zhang, Y.; Guo, S.X.; Zhang, X.L.; Bond, A.M.; Zhang, J. Nano Today 2020, 31,100835.
[14]	Hori, Y.; Wakebe, H.; Tsukamoto, T.; Koga, O. Electrochim. Acta 1994, 39,1833.
[15]	Schreier, M.; Yoon, Y.; Jackson, M.N.; Surendranath, Y. Angew. Chem. Int. Ed. 2018, 57,10221.
[16]	Hori, Y.; Kikuchi, K.; Suzuki, S. Chem. Lett. 1985, 11,1695.
[17]	Cheng, T.; Xiao, H.; Goddard, W.A. J. Am. Chem. Soc. 2016, 138,133802.
[18]	Jones, J.; Prakash, G.K. S.; Olah, G.A. Isr. J. Chem. 2014, 54,1451.
[19]	Gao, S.; Lin, Y.; Jiao, X.C.; Sun, Y.F.; Luo, Q.Q.; Zhang, W.H.; Li, D.Q.; Yang, J.L.; Xie, Y. Nature 2016, 529,68.
[20]	Habisreutinger, S.N.; Schmidt-Mende, L.; Stolarczyk, J.K. Angew. Chem. Int. Ed. 2013, 52,7372.
[21]	Ting, L.R. L.; Yeo, B.S. Curr. Opin. Electrochem. 2018, 8,126.
[22]	Albo, J.; Sáez, A.; Solla-Gullón, J.; Montiel, V.; Irabien, A. Appl. Catal. B-Environ. 2015, 176,709.
[23]	Li, J.; Chen, G.X.; Zhu, Y.Y.; Liang, Z.; Pei, A.; Wu, C.L.; Wang, H.X.; Lee, H.R.; Liu, K.; Chu, S.; Cui, Y. Nat. Catal. 2018, 1,592.
[24]	Xu, W.W.; Lu, Z.Y.; Sun, X.M.; Jiang, L.; Duan, X. Acc. Chem. Res. 2018, 51,1590.
[25]	Lu, Z.Y.; Zhu, W.; Yu, X.Y.; Zhang, H.C.; Li, Y.J.; Sun, X.M.; Wang, X.W.; Wang, H.; Wang, J.M.; Luo, J.; Lei, X.D.; Jiang, L. Adv. Mater. 2014, 26,2683.
[26]	Wen, L.P.; Tian, Y.; Jiang, L. Angew. Chem. Int. Ed. 2015, 54,3387.
[27]	Wang, J.M.; Zheng, Y.M.; Nie, F.Q.; Zhai, J.; Jiang, L. Langmuir 2009, 25,14129.
[28]	Cai, Z,; Zhang, Y.S.; Zhao, Y.X.; Wu, Y.S.; Xu, W.W.; Wen, X.M.; Zhong, Y.; Zhang, Y.; Liu, W.; Wang, H.L.; Kuang, Y.; Sun, X.M. Nano Res. 2019, 12,345.
[29]	Schouten, K.J. P.; Kwon, Y.; Van der Ham, C.J. M.; Qin, Z.; Koper, M.T. M. Chem. Sci. 2011, 2,1902.
[30]	Wakerley, D.; Lamaison, S.; Ozanam, F.; Menguy, N.; Mercier, D.; Marcus, P.; Fontecave, M.; Mougel, V. Nat. Mater. 2019, 18,1222.
[31]	Dinh, C.T.; Burdyny, T.; Kibria, M.G.; Selfitokaldani, A.; Gabardo, C.M.; de Arquer, F.P. G.; Kiani, A.; Edwards, J.P.; De Luna, P.; Bushuyev, O.S.; Zou, C.Q.; Quintero-Bermudez, R.; Pang, Y.J.; Sinton, D.; Sargent, E.H. Science 2018, 360,783.
[32]	Zheng, T.T.; Jiang, K.; Ta, N.; Hu, Y.F.; Zeng, J.; Liu, J.Y.; Wang, H.T. Joule 2019, 3,265.
[33]	de Arquer, F.P. G.; Dinh, C.T.; Ozden, A.; Wicks, J.; McCallum, C.; Kirmani, A.R.; Nam, D.H.; Gabardo, C.; Seifitokaldani, A.; Wang, X.; Li, Y.C.; Li, F.W.; Edwards, J.; Richter, L.J.; Thorpe, S.J.; Sinton, D.; Sargent, E.H. Science 2020, 367,661.
[34]	Kaczur, J.J.; Yang, H.Z.; Liu, Z.C.; Sajjad, S.A.; Masel, R.I. Front. Chem. 2018, 6,263.
[35]	Yin, Z.L.; Peng, H.Q.; Wei, X.; Zhou, H.; Gong, J.; Huai, M.M.; Xiao, L.; Wang, G.W.; Lu, J.T.; Zhuang, L. Energy Environ. Sci. 2019, 12,2455.
[36]	Xiong, X.Y.; Wang, Z.P.; Zhang, Y.; Li, Z.H.; Shi, R.; Zhang, T.R. Appl. Catal. B-Environ. 2020, 264,118518.
[37]	Burdyny, T.; Graham, P.J.; Pang, Y.J.; Dinh, C.T.; Min, L.; Sargent, E.H.; Sinton, D. ACS Sustain. Chem. Eng. 2017, 5,4031.
[38]	Shi, R.; Guo, J.H.; Zhang, Y.R.; Waterhouse, G.I. N.; Han, Z.J.; Zhao, Y.X.; Shang, L.; Zhou, C.; Jiang, L.; Zhang, T.R. Nat. Commun. 2020, 11,3028.
[39]	Nesbitt, N.T.; Burdyny, T.; Simonson, H.; Salvatore, D.; Bohra, D.; Kas, R.; Smith, W.A. ACS Catal. 2020, 10,14093.
[40]	Liu, Z.; Sheng, X.; Wang, D.D.; Feng, X.J. iScience 2019, 17,67.
[41]	Giorgi, L.; Antilini, E.; Pozio, A.; Passalacqua, E. Electrochim. Acta 1998, 43,3675.
[42]	Martínez-Rodríguez, M.J.; Cui, T.; Shipalee, S.; Seraphin, S.; Duong, B.; Van Zee, J.W. J. Power Sources 2012, 207,91.
[43]	Jhong, H.-R. M.; Brushett, F.R.; Yin, L.L.; Stevenson, D.M.; Kenis, P.J. A. J. Electrochem. Soc. 2012, 159,B292.
[44]	Kim, B.; Hillman, F.; Arioshi, M.; Fujikawa, S.; Kenis, P.J. A. J. Power Sources 2016, 312,192.
[45]	Jhong, H.-R. M.; Brushett, F.R.; Kenis, P.J. A. Adv. Energy Mater. 2013, 3,589.
[46]	Gabado, C.M.; Seifitokaldani, A.; Edwards, J.P.; Dinh, C.-T.; Burdyny, T.; Kibria, M.G.; O’Brien, C.P.; Sargent, E.H.; Sinton, D. Energy Environ. Sci. 2018, 11,2531.
[47]	Thorson, M.R.; Siil, K.I.; Kenis, P.J. A. J. Electrochem. Soc. 2013, 160,F69.
[48]	Kim, B.; Ma, S.; Jhong, H.-R. M.; Kenis, P.J. A. Electrochim. Acta 2015, 166,271.
[49]	Verma, S.; Lu, X.; Ma, S.; Masel, R.I.; Kenis, P.J. A. Phys. Chem. Chem. Phys. 2016, 18,7075.
[50]	Chen, K.H.; Li, H.R.; He, L.N. Chin. J. Org. Chem. 2020, 40,2195. (in Chinese)
	( 陈凯宏, 李红茹, 何良年, 有机化学, 2020, 40,2195.)
[51]	Jhong, H.-R. M.; Tornow, C.E.; Kim, C.; Verma, S.; Oberst, J.L.; Anderson, P.S.; Gewirth, A.A.; Fujigaya, T.; Nakashima, N.; Kenis, P.J. A. ChemPhysChem 2017, 18,3274.
[52]	Wang, Y.J.; Wilkinson, D.P.; Zhang, J.J. Chem. Rev. 2011, 111,7625.
[53]	Liu, M.M.; Zhang, R.Z.; Chen, W. Chem. Rev. 2014, 114,5117.
[54]	Wang, Z.L.; Xu, D.; Xu, J.J.; Zhang, X.B. Chem. Soc. Rev. 2014, 43,7746.
[55]	Li, Y.G.; Gong, M.; Liang, Y.Y.; Feng, J.; Kim, J.E.; Wang, H.L.; Hong, G.S.; Zhang, B.; Dai, H.J. Nat. Commun. 2013, 4,1805.
[56]	Lu, Z.Y.; Xu, W.W.; Ma, J.; Li, Y.J.; Sun, X.M.; Jiang, L. Adv. Mater. 2016, 28,7155.
[57]	Lei, Y.J.; Sun, R.Z.; Zhang, X.C.; Feng, X.J.; Jiang, L. Adv. Mater. 2016, 28,1477.
[58]	Wang, Y.L.; Shi, R.; Shang, L.; Waterhouse, G.I. N.; Zhao, J.Q.; Zhang, Q.H.; Gu, L.; Zhang, T.R. Angew. Chem. Int. Ed. 2020, 59,13057.
[59]	Chen, S.L.; Patil, S.A.; Schroeder, U. Appl. Mater. 2018, 211,1089.
[60]	Li, J.; Chang, K.; Zhang, H.C.; He, M.; Goddard, W.A.; Chen, J.G. G.; Cheng, M.J.; Lu, Q. ACS Catal. 2019, 9,4709.
[61]	Chen, R.X.; Su, H.Y.; Liu, D.Y.; Huang, R.; Meng, X.G.; Cui, X.J.; Tian, Z.Q.; Zhang, D.H.; Deng, D.H. Angew. Chem. Int. Ed. 2019, 59,154.
[62]	Jouny, M.; Luc, W.; Jiao, F. Nat. Catal. 2018, 1,1002.
[63]	Li, Y.J.; Zhang, H.C.; Xu, T.H.; Lu, Z.Y.; Wu, X.C.; Wan, P.B.; Sun, X.M.; Jiang, L. Adv. Funct. Mater. 2015, 25,1737.
[64]	Hao, M.; Chanbonneau, V.; Fomena, N.N.; Gaudet, J.; Bruce, D.R.; Garbarino, S.; Harrington, D.A.; Gauy, D. ACS Appl. Energy Mater. 2019, 2,5734.
[65]	Yuan, J.X.; Cheng, X.D.; Wang, H.Q.; Lei, C.J.; Pardiwala, S.; Yang, B.; Li, Z.J.; Zhang, Q.H.; Lei, L.C.; Wang, S.B.; Hou, Y. Nano-Micro Lett. 2020, 12,104.

三相界面电催化二氧化碳还原研究进展

Research Progress on Triphase Interface Electrocatalytic Carbon Dioxide Reduction

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 6

References 65

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shan Li, Junxin Lu, Jie Liu, Lvqi Jiang, Wenbin Yi. Electrochemical Synthesis of α-Fluoroalkylated Ketones using Sodium Fluoroalkylsulfinate [J]. Acta Chimica Sinica, 2024, 82(2): 110-114.
[2]	Zhenhong Yang, Xiaojuan Gan, Shuzhe Wang, Junyuan Duan, Tianyou Zhai, Youwen Liu. Preparation of Metallic Ni₃N Nanoparticles and Its Electrooxidation Performance for Ethylene Glycol^★ [J]. Acta Chimica Sinica, 2023, 81(11): 1471-1477.
[3]	Shaobing Yan, Long Jiao, Chuanxin He, Hailong Jiang. Pyrolysis of ZIF-67/Graphene Composite to Co Nanoparticles Confined in N-Doped Carbon for Efficient Electrocatalytic Oxygen Reduction [J]. Acta Chimica Sinica, 2022, 80(8): 1084-1090.
[4]	Jiawei He, Liu Jiao, Xueyi Cheng, Guanghai Chen, Qiang Wu, Xizhang Wang, Lijun Yang, Zheng Hu. Structural Regulation of Metal Organic Framework-derived Hollow Carbon Nanocages and Their Lithium-Sulfur Battery Performance [J]. Acta Chimica Sinica, 2022, 80(7): 896-902.
[5]	Yinlong Jiang, Guochao Li, Qingsong Chen, Zhongning Xu, Shanshan Lin, Guocong Guo. Porous Bismuth Nanoflowers Enriched with Lattice Dislocations for Highly Efficient Electrocatalytic Reduction of Carbon Dioxide to Formate^※ [J]. Acta Chimica Sinica, 2022, 80(6): 703-707.
[6]	Dan Wang, Bo Feng, Xiaoxin Zhang, Yanan Liu, Yan Pei, Minghua Qiao, Baoning Zong. Nitrogen-doped Carbon Pyrolyzed from ZIF-8 for Electrocatalytic Oxygen Reduction to Hydrogen Peroxide [J]. Acta Chimica Sinica, 2022, 80(6): 772-780.
[7]	Zeyang Li, Yusen Yang, Min Wei. Structural Design and Performance of Electrocatalysts for Carbon Dioxide Reduction: A Review [J]. Acta Chimica Sinica, 2022, 80(2): 199-213.
[8]	Pan An, Qinghui Zhang, Zhuang Yang, Jiaxing Wu, Jiaying Zhang, Yajun Wang, Yuming Li, Guiyuan Jiang. Research Progress of Solar Hydrogen Production Technology under Double Carbon Target [J]. Acta Chimica Sinica, 2022, 80(12): 1629-1642.
[9]	Jinge Wang, Wei Zhou, Jiayi Li, Yani Ding, Jihui Gao. Recent Advances and Performance Enhancement Mechanisms of Pulsed Electrocatalysis [J]. Acta Chimica Sinica, 2022, 80(11): 1555-1568.
[10]	Lin Li, Zizhao Wang, Jiawei Liu, Jia Chen, Xiao Jin, Caili Dai. Synthesis and Performance Evaluation of Polyhydroxy Benzene Sulfonate Oil Displacement Agent Based on Enhanced Interfacial Wettability Control [J]. Acta Chimica Sinica, 2022, 80(1): 63-68.
[11]	Su Zhan, Fuxiang Zhang. Recent Progress on Electrocatalytic Synthesis of Ammonia Under Amibent Conditions [J]. Acta Chimica Sinica, 2021, 79(2): 146-157.
[12]	Sun Qi, Xiao Feng-Shou. Exploration of Porous Organic Polymers as a Platform for Biomimetic Catalysis [J]. Acta Chimica Sinica, 2020, 78(9): 827-832.
[13]	Liu Shengwei, Zhao Jianjun, Xu Yiming. Larger Adsorption Effect of Fluoride than Phosphate on Phenol Degradation over the Irradiated Anatase TiO₂ and Pt/TiO₂ [J]. Acta Chim. Sinica, 2019, 77(4): 351-357.
[14]	Ma Guojia, Zheng Haikun, Chang Shinan, Wang Shuoshuo. Wettability Analysis and Design of Micro-nanostructured Superhydrophobic Surface [J]. Acta Chim. Sinica, 2019, 77(3): 269-277.
[15]	Wu Kuangheng, Zhou Yawei, Ma Xianyin, Ding Chen, Cai Wenbin. Controlled Synthesis of Gold-Platinum Catalysts for Ethanol Electro-oxidation Reaction [J]. Acta Chim. Sinica, 2018, 76(4): 292-297.