Research Progress of Self-assembled Hole-transporting Monolayers in Inverted Perovskite Solar Cells

doi:10.6023/A24010026

Acta Chimica Sinica ›› 2024, Vol. 82 ›› Issue (3): 348-366.DOI: 10.6023/A24010026 Previous Articles Next Articles

Review

自组装单分子空穴传输层在反式钙钛矿太阳电池的研究进展

刘雪朋, 李博桐, 韩明远, 张先付, 陈建林, 戴松元^*()

华北电力大学新能源学院新型薄膜太阳电池北京市重点实验室北京 102206

投稿日期:2024-01-22 发布日期:2024-02-18

作者简介:

刘雪朋, 副教授. 主要从事新型太阳电池中有机光电材料的设计、合成及构效关系探索; 新型薄膜太阳电池中关键材料开发及界面修饰. 现工作于华北电力大学新能源学院. 主要研究方向: 钙钛矿太阳电池.

戴松元, 教授, “新型薄膜太阳电池”北京市重点实验室主任. 长期从事新型太阳电池的研究, 包括染料敏化太阳电池、钙钛矿太阳电池、量子点太阳电池及其他新兴纳米杂化有机/无机太阳电池的研究; 能源转换材料和储能材料的研究和纳米材料的制备和合成等. 现工作于华北电力大学新能源学院. 主要研究方向: 新型薄膜太阳电池.

基金资助:
国家重点研发计划(2020YFB1506400); 国家自然科学基金项目(61904053); 国家自然科学基金项目(22279033); “111”项目(B16016); 江苏省碳达峰碳中和科技创新专项资金项目(BE2022026)

Research Progress of Self-assembled Hole-transporting Monolayers in Inverted Perovskite Solar Cells

Xuepeng Liu, Botong Li, Mingyuan Han, Xianfu Zhang, Jianlin Chen, Songyuan Dai()

North China Electric Power University, School of New Energy, Beijing Key Laboratory of Novel Thin-Film Solar Cells, Beijing 102206, China

Received:2024-01-22 Published:2024-02-18
Contact: *E-mail: sydai@ncepu.edu.cn
Supported by:
National Key Research and Development Program of China(2020YFB1506400); National Natural Science Foundation of China(61904053); National Natural Science Foundation of China(22279033); 111 project(B16016); Special Foundation for Carbon Peak Carbon Neutralization Technology Innovation Program of Jiangsu Province(BE2022026)

Hole transport layer plays an important role in extracting and transporting photogenerated holes from the perovskite layer and suppressing back electron in Perovskite solar cell (PSC). It is an important component of high-performance devices. Classic hole transport materials, such as 2,2',7,7'-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (spiro- OMeTAD), poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA), etc., have high prices and low hole mobility, which limit the large-scale application. In recent years, self-assembled monolayers (SAM) have been widely used as hole transport layers in inverted PSC to improve device performance. SAM molecular structure contains anchoring functional groups, which can form a single molecule film on the substrate. It has the advantages of low material consumption, no need for additives, low parasitic absorption, compatibility with tandem devices, and is conducive to large-scale manufacturing. It has become a research hotspot in the field of perovskite solar cells. In the light of the development of PSC, this review classifies and summarizes the recent studies on SAM-based hole transport layers according to the different anchoring groups in the SAM molecular structure, and analyzes the effects of the molecular structure changes on the molecular properties and device performance. Finally, the development of SAM as a hole transport layer is summarized and prospected.

Key words: perovskite solar cell, hole transporting materials, self-assembled monolayers, photoelectric conversion efficiency, stability

Cite this article

Xuepeng Liu, Botong Li, Mingyuan Han, Xianfu Zhang, Jianlin Chen, Songyuan Dai. Research Progress of Self-assembled Hole-transporting Monolayers in Inverted Perovskite Solar Cells[J]. Acta Chimica Sinica, 2024, 82(3): 348-366.

Export EndNote|Reference Manager|ProCite|BibTeX|RefWorks

share this article

Fig. & Tab. 12

References 110

[1]	Kim, H.-S.; Lee, C.-R.; Im, J.-H.; Lee, K.-B.; Moehl, T.; Marchioro, A.; Moon, S.-J.; Humphry-Baker, R.; Yum, J.-H.; Moser, J. E.; Grätzel, M.; Park, N.-G. Sci. Rep. 2012, 2, 591. doi: 10.1038/srep00591
[2]	Best Research-Cell Efficiency Chart. NREL https://www.nrel.gov/pv/cell-efficiency.html 2023).
[3]	Kim, J. Y.; Lee, J.-W.; Jung, H. S.; Shin, H.; Park, N.-G. Chem. Rev. 2020, 120, 7867. doi: 10.1021/acs.chemrev.0c00107
[4]	Shao, J.-Y.; Zhong, Y.-W. Chin. J. Org. Chem. 2021, 41, 1447 (in Chinese). doi: 10.6023/cjoc202009033
	(邵将洋, 钟羽武, 有机化学, 2021, 41, 1447.) doi: 10.6023/cjoc202009033
[5]	Urieta-Mora, J.; García-Benito, I.; Molina-Ontoria, A.; Martín, N. Chem. Soc. Rev. 2018, 47, 8541. doi: 10.1039/c8cs00262b pmid: 30283961
[6]	Gangala, S.; Misra, R. J. Mater. Chem. A 2018, 6, 18750. doi: 10.1039/C8TA08503J
[7]	Liu, Q.; Ren, B.; Sun, Y.; Xie, L.; Huang, W. Acta Chim. Sinica 2021, 79, 1181 (in Chinese). doi: 10.6023/A21060253
	(刘庆琳, 任保轶, 孙亚光, 解令海, 黄维, 化学学报, 2021, 79, 1181.) doi: 10.6023/A21060253
[8]	Liu, X.-P.; Kong, F.-T.; Chen, W.-C.; Yu, T.; Guo, F.-L.; Chen, J.; Dai, S.-Y. Acta Phys.-Chim. Sin. 2016, 32, 1347 (in Chinese). doi: 10.3866/PKU.WHXB201603143
	(刘雪朋, 孔凡太, 陈汪超, 于婷, 郭福领, 陈健, 戴松元, 物理化学学报, 2016, 32, 1347.)
[9]	Marinova, N.; Tress, W.; Humphry-Baker, R.; Dar, M. I.; Bojinov, V.; Zakeeruddin, S. M.; Nazeeruddin, M. K.; Grätzel, M. ACS Nano 2015, 9, 4200. doi: 10.1021/acsnano.5b00447 pmid: 25769194
[10]	Meng, L.; You, J.; Guo, T.-F.; Yang, Y. Acc. Chem. Res. 2016, 49, 155. doi: 10.1021/acs.accounts.5b00404
[11]	Yang, Y.; Zhu, C.; Lin, F.; Chen, T.; Pan, D.; Guo, X. Acta Chim. Sinica 2019, 77, 964 (in Chinese). doi: 10.6023/A19040143
	(杨英, 朱从潭, 林飞宇, 陈甜, 潘德群, 郭学益, 化学学报, 2019, 77, 964.) doi: 10.6023/A19040143
[12]	Isikgor, F. H.; Zhumagali, S.; Merino, L. V. T.; De Bastiani, M.; McCulloch, I.; De Wolf, S. Nat. Rev. Mater. 2023, 8, 89. doi: 10.1038/s41578-022-00503-3
[13]	Ali, F.; Roldán-Carmona, C.; Sohail, M.; Nazeeruddin, M. K. Adv. Energy Mater. 2020, 10, 2002989. doi: 10.1002/aenm.v10.48
[14]	Wang, S.; Guo, H.; Wu, Y. Materials Futures 2023, 2, 012105. doi: 10.1088/2752-5724/acbb5a
[15]	Galvis, C. E. P.; Ruiz, D. A. G.; Martinez-Ferrero, E.; Palomares, E. Chem. Sci. 2024, 15, 1534. doi: 10.1039/D3SC04668K
[16]	Lan, Z.-R.; Shao, J.-Y.; Zhong, Y.-W. Mol. Syst. Des. Eng. 2023, 8, 1440. doi: 10.1039/D3ME00144J
[17]	Cheng, H.; Li, Y.; Zhong, Y. Mater. Chem. Front. 2023, 7, 3958. doi: 10.1039/D3QM00209H
[18]	Wu, G.; Kong, F.; Weng, J.; Dai, S.; Xi, X.; Zhang, C. Prog. Chem. 2011, 23, 1929 (in Chinese).
	(武国华, 孔凡太, 翁坚, 戴松元, 奚小网, 张昌能, 化学进展, 2011, 23, 1929.)
[19]	Kong, F.; Dai, S.; Wang, K. Huaxue Tongbao 2005, 68, 338 (in Chinese).
	(孔凡太, 戴松元, 王孔嘉, 化学通报, 2005, 68, 338.)
[20]	Dai, S.; Zhang, C.; Huang, Y. Dye-Sensitized Solar Cell Technology and Process, Science Press, Beijing, 2016 (in Chinese).
	(戴松元, 张昌能, 黄阳, 染料敏化太阳电池技术与工艺, 科学出版社, 北京, 2016.)
[21]	Dai, S.; Liu, W.; Yan, J. Dye-Sensitized Solar Cell, Science Press, Beijing, 2014 (in Chinese).
	(戴松元, 刘伟庆, 闫金定, 染料敏化太阳电池, 科学出版社, 北京, 2014.)
[22]	Gissler, W.; Memming, R. J. Electrochem. Soc. 1977, 124, 1710. doi: 10.1149/1.2133141
[23]	Gerischer, H.; Michel-Beyerle, M.; Rebentrost, F.; Tributsch, H. Electrochim. Acta 1968, 13, 1509. doi: 10.1016/0013-4686(68)80076-3
[24]	Gerischer, H.; Tributsch, H. Berichte der Bunsengesellschaft für physikalische Chemie 1968, 72, 437. doi: 10.1002/bbpc.v72.3
[25]	Anderson, S.; Constable, E. C.; Dare-Edwards, M. P.; Goodenough, J. B.; Hamnett, A.; Seddon, K. R.; Wright, R. D. Nature 1979, 280, 571. doi: 10.1038/280571a0
[26]	Tributsch, H. Coordin. Chem. Rev. 2004, 248, 1511. doi: 10.1016/j.ccr.2004.05.030
[27]	McEvoy, A.; Grätzel, M. Sol. Energy Mat. Sol. C. 1994, 32, 221. doi: 10.1016/0927-0248(94)90260-7
[28]	Tsubomura, H.; Matsumura, M.; Nomura, Y.; Amamiya, T. Nature 1976, 261, 402. doi: 10.1038/261402a0
[29]	O'regan, B.; Grätzel, M. Nature 1991, 353, 737. doi: 10.1038/353737a0
[30]	Bach, U.; Lupo, D.; Comte, P.; Moser, J.-E.; Weissörtel, F.; Salbeck, J.; Spreitzer, H.; Grätzel, M. Nature 1998, 395, 583. doi: 10.1038/26936
[31]	Kojima, A.; Teshima, K.; Shirai, Y.; Miyasaka, T. J. Am. Chem. Soc. 2009, 131, 6050. doi: 10.1021/ja809598r
[32]	Im, J.-H.; Lee, C.-R.; Lee, J.-W.; Park, S.-W.; Park, N.-G. Nanoscale 2011, 3, 4088. doi: 10.1039/c1nr10867k
[33]	Lee, M. M.; Teuscher, J.; Miyasaka, T.; Murakami, T. N.; Snaith, H. J. Science 2012, 338, 643. doi: 10.1126/science.1228604
[34]	Jeng, J. Y.; Chiang, Y. F.; Lee, M. H.; Peng, S. R.; Guo, T. F.; Chen, P.; Wen, T. C. Adv. Mater. 2013, 25, 3727. doi: 10.1002/adma.v25.27
[35]	Liu, M.; Johnston, M. B.; Snaith, H. J. Nature 2013, 501, 395. doi: 10.1038/nature12509
[36]	Li, X.; Chen, C. C.; Cai, M.; Hua, X.; Xie, F.; Liu, X.; Hua, J.; Long, Y. T.; Tian, H.; Han, L. Adv. Energy Mater. 2018, 8, 1800715. doi: 10.1002/aenm.v8.20
[37]	Zhumagali, S.; Isikgor, F. H.; Maity, P.; Yin, J.; Ugur, E.; De Bastiani, M.; Subbiah, A. S.; Mirabelli, A. J.; Azmi, R.; Harrison, G. T.; Troughton, J.; Aydin, E.; Liu, J.; Allen, T.; Rehman, A. u.; Baran, D.; Mohammed, O. F.; De Wolf, S. Adv. Energy Mater. 2021, 11, 2101662. doi: 10.1002/aenm.v11.40
[38]	Wang, Y.; Liao, Q.; Chen, J.; Huang, W.; Zhuang, X.; Tang, Y.; Li, B.; Yao, X.; Feng, X.; Zhang, X.; Su, M.; He, Z.; Marks, T. J.; Facchetti, A.; Guo, X. J. Am. Chem. Soc. 2020, 142, 16632. doi: 10.1021/jacs.0c06373
[39]	Afraj, S. N.; Kuan, C. H.; Lin, J. S.; Ni, J. S.; Velusamy, A.; Chen, M. C.; Diau, E. W. G. Adv. Funct. Mater. 2023, 33, 2213939. doi: 10.1002/adfm.v33.17
[40]	Kim, S. Y.; Cho, S. J.; Byeon, S. E.; He, X.; Yoon, H. J. Adv. Energy Mater. 2020, 10, 2002606. doi: 10.1002/aenm.v10.44
[41]	Galoppini, E. Coordin. Chem. Rev. 2004, 248, 1283. doi: 10.1016/j.ccr.2004.03.016
[42]	Bauer, T.; Schmaltz, T.; Lenz, T.; Halik, M.; Meyer, B.; Clark, T. ACS Appl. Mater. Interfaces 2013, 5, 6073. doi: 10.1021/am4008374
[43]	Zhang, S.; Ye, F.; Wang, X.; Chen, R.; Zhang, H.; Zhan, L.; Jiang, X.; Li, Y.; Ji, X.; Liu, S.; Yu, M.; Yu, F.; Zhang, Y.; Wu, R.; Liu, Z.; Ning, Z.; Neher, D.; Han, L.; Lin, Y.; Tian, H.; Chen, W.; Stolterfoht, M.; Zhang, L.; Zhu, W.-H.; Wu, Y. Science 2023, 380, 404. doi: 10.1126/science.adg3755 pmid: 37104579
[44]	Zhu, J.; Luo, Y.; He, R.; Chen, C.; Wang, Y.; Luo, J.; Yi, Z.; Thiesbrummel, J.; Wang, C.; Lang, F.; Lai, H.; Xu, Y.; Wang, J.; Zhang, Z.; Liang, W.; Cui, G.; Ren, S.; Hao, X.; Huang, H.; Wang, Y.; Yao, F.; Lin, Q.; Wu, L.; Zhang, J.; Stolterfoht, M.; Fu, F.; Zhao, D. Nature Energy 2023, 8, 714. doi: 10.1038/s41560-023-01274-z
[45]	Park, S. M.; Wei, M.; Lempesis, N.; Yu, W.; Hossain, T.; Agosta, L.; Carnevali, V.; Atapattu, H. R.; Serles, P.; Eickemeyer, F. T.; Shin, H.; Vafaie, M.; Choi, D.; Darabi, K.; Jung, E. D.; Yang, Y.; Kim, D. B.; Zakeeruddin, S. M.; Chen, B.; Amassian, A.; Filleter, T.; Kanatzidis, M. G.; Graham, K. R.; Xiao, L.; Rothlisberger, U.; Grätzel, M.; Sargent, E. H. Nature 2023, 624, 289. doi: 10.1038/s41586-023-06745-7
[46]	Kim, M.; Jeong, J.; Lu, H.; Lee, T. K.; Eickemeyer, F. T.; Liu, Y.; Choi, I. W.; Choi, S. J.; Jo, Y.; Kim, H.-B.; Mo, S.-I.; Kim, Y.-K.; Lee, H.; An, N. G.; Cho, S.; Tress, W. R.; Zakeeruddin, S. M.; Hagfeldt, A.; Kim, J. Y.; Grätzel, M.; Kim, D. S. Science 2022, 375, 302. doi: 10.1126/science.abh1885
[47]	Phung, N.; Verheijen, M.; Todinova, A.; Datta, K.; Verhage, M.; Al-Ashouri, A.; Köbler, H.; Li, X.; Abate, A.; Albrecht, S.; Creatore, M. ACS Appl. Mater. Interfaces 2021, 14, 2166. doi: 10.1021/acsami.1c15860
[48]	Mao, L.; Yang, T.; Zhang, H.; Shi, J.; Hu, Y.; Zeng, P.; Li, F.; Gong, J.; Fang, X.; Sun, Y.; Liu, X.; Du, J.; Han, A.; Zhang, L.; Liu, W.; Meng, F.; Cui, X.; Liu, Z.; Liu, M. Adv. Mater. 2022, 34, 2206193. doi: 10.1002/adma.v34.40
[49]	Li, Z.; Sun, X.; Zheng, X.; Li, B.; Gao, D.; Zhang, S.; Wu, X.; Li, S.; Gong, J.; Luther, J. M.; Li, Z.; Zhu, Z. Science 2023, 382, 284. doi: 10.1126/science.ade9637 pmid: 37856581
[50]	Yu, S.; Xiong, Z.; Zhou, H.; Zhang, Q.; Wang, Z.; Ma, F.; Qu, Z.; Zhao, Y.; Chu, X.; Zhang, X.; You, J. Science 2023, 382, 1399. doi: 10.1126/science.adj8858
[51]	Liu, C.; Yang, Y.; Chen, H.; Xu, J.; Liu, A.; Bati, A. S.; Zhu, H.; Grater, L.; Hadke, S. S.; Huang, C.; Sangwan, V. K.; Cai, T.; Shin, D.; Chen, L. X.; Hersam, M. C.; Mirkin, C. A.; Chen, B.; Kanatzidis, M. G.; Sargent, E. H. Science 2023, 382, 810. doi: 10.1126/science.adk1633
[52]	Farag, A.; Feeney, T.; Hossain, I. M.; Schackmar, F.; Fassl, P.; Küster, K.; Bäuerle, R.; Ruiz-Preciado, M. A.; Hentschel, M.; Ritzer, D. B.; Diercks, A.; Li, Y.; Nejand, B. A.; Laufer, F.; Singh, R.; Strarke, U.; Paetzold, U. W. Adv. Energy Mater. 2023, 13, 2203982. doi: 10.1002/aenm.v13.8
[53]	Qin, S.; Lu, C.; Jia, Z.; Wang, Y.; Li, S.; Lai, W.; Shi, P.; Wang, R.; Zhu, C.; Du, J.; Zhang, J.; Meng, L.; Li, Y. Adv. Mater. 2022, 34, 2108829. doi: 10.1002/adma.v34.11
[54]	Al-Ashouri, A.; Köhnen, E.; Li, B.; Magomedov, A.; Hempel, H.; Caprioglio, P.; Márquez, J. A.; Morales Vilches, A. B.; Kasparavicius, E.; Smith, J. A.; Phung, N.; Menzel, D.; Grischek, M.; Kegelmann, L.; Skroblin, D.; Gollwitzer, C.; Malinauskas, T.; Jost, M.; MatiČ, G.; Rech, B.; Schlatmann, R.; Topic, M.; Korte, L.; Abate, A.; Stannowski, B.; Neher, D.; Stolterfoht, M.; Unold, T.; Getautis, V.; Albrecht, S. Science 2020, 370, 1300. doi: 10.1126/science.abd4016 pmid: 33303611
[55]	Tan, Q.; Li, Z.; Luo, G.; Zhang, X.; Che, B.; Chen, G.; Gao, H.; He, D.; Ma, G.; Wang, J.; Xiu, J.; Yi, H.; Chen, T.; He, Z. Nature 2023, 620, 545. doi: 10.1038/s41586-023-06207-0
[56]	Radhakrishna, K.; Manjunath, S. B.; Devadiga, D.; Chetri, R.; Nagaraja, A. T. ACS Appl. Energy Mater. 2023, 6, 3635. doi: 10.1021/acsaem.2c03025
[57]	Magomedov, A.; Al-Ashouri, A.; Kasparavičius, E.; Strazdaite, S.; Niaura, G.; Jošt, M.; Malinauskas, T.; Albrecht, S.; Getautis, V. Adv. Energy Mater. 2018, 8, 1801892. doi: 10.1002/aenm.v8.32
[58]	Al-Ashouri, A.; Magomedov, A.; Roß, M.; Jošt, M.; Talaikis, M.; Chistiakova, G.; Bertram, T.; Márquez, J. A.; Köhnen, E.; Kasparavičius, E.; Levcenco, S.; Gil-Escrig, L.; Hages, C. J.; Schlatmann, R.; Rech, B.; Malinauskas, T.; Unold, T.; Kaufmann, C. A.; Korte, L.; Niaura, G.; Getautis, V.; Albrecht, S. Energ. Environ. Sci. 2019, 12, 3356. doi: 10.1039/c9ee02268f
[59]	Mariotti, S.; Köhnen, E.; Scheler, F.; Sveinbjörnsson, K.; Zimmermann, L.; Piot, M.; Yang, F.; Li, B.; Warby, J.; Musiienko, A.; Menzel, D.; Lang, F.; Kessler, S.; Levine, I.; Mantione, D.; Al-Ashouri, A.; Hartel, M. S.; Xu, K.; Cruz, A.; Kurpiers, J.; Wagner, P.; Kobler, H.; Li, J.; Magomedov, A.; Mecerreyes, D.; Unger, E.; Abate, A.; Stolterfoht, M.; Stannowski, B.; Schlatmann, R.; Korte, L.; Albrecht, S. Science 2023, 381, 63. doi: 10.1126/science.adf5872 pmid: 37410849
[60]	Zheng, J.; Ying, Z.; Yang, Z.; Lin, Z.; Wei, H.; Chen, L.; Yang, X.; Zeng, Y.; Li, X.; Ye, J. Nature Energy 2023, 8, 1250. doi: 10.1038/s41560-023-01382-w
[61]	Deng, X.; Qi, F.; Li, F.; Wu, S.; Lin, F. R.; Zhang, Z.; Guan, Z.; Yang, Z.; Lee, C. S.; Jen, A. K. Y. Angew. Chem. Int. Ed. 2022, 61, e202203088.
[62]	Manthou, V. S.; Pefkianakis, E. K.; Falaras, P.; Vougioukalakis, G. C. ChemSusChem 2015, 8, 588. doi: 10.1002/cssc.v8.4
[63]	Liu, X.; Ding, B.; Han, M.; Yang, Z.; Chen, J.; Shi, P.; Xue, X.; Ghadari, R.; Zhang, X.; Wang, R.; Brooks, K.; Tao, L.; Kinge, S.; Dai, S.; Sheng, J.; Dyson, P. J.; Nazeeruddin, M. K.; Ding, Y. Angew. Chem. Int. Ed. 2023, 62, e202304350.
[64]	Wang, G.; Zheng, J.; Duan, W.; Yang, J.; Mahmud, M. A.; Lian, Q.; Tang, S.; Liao, C.; Bing, J.; Yi, J.; Leung, T. L.; Cui, X.; Chen, H.; Jiang, F.; Huang, Y.; Lambertz, A.; Jankovec, M.; Topič, M.; Bremner, S.; Zhang, Y.-Z.; Cheng, C.; Ding, K.; Ho-Baillie, A. Joule 2023, 7, 2583. doi: 10.1016/j.joule.2023.09.007
[65]	Pitaro, M.; Alonso, J. S.; Di Mario, L.; Romero, D. G.; Tran, K.; Zaharia, T.; Johansson, M. B.; Johansson, E. M.; Loi, M. A. J. Mater. Chem. A 2023, 11, 11755. doi: 10.1039/D3TA01276J
[66]	Ullah, A.; Park, K. H.; Nguyen, H. D.; Siddique, Y.; Shah, S.; Tran, H.; Park, S.; Lee, S. I.; Lee, K. K.; Han, C. H.; Kim, K.; Ahn, S.; Jeong, I.; Park, Y. S.; Hong, S. Adv. Energy Mater. 2022, 12, 2103175. doi: 10.1002/aenm.v12.2
[67]	Ullah, A.; Park, K. H.; Lee, Y.; Park, S.; Faheem, A. B.; Nguyen, H. D.; Siddique, Y.; Lee, K. K.; Jo, Y.; Han, C. H.; Ahn, S.; Jeong, I.; Cho, S.; Kim, B.; Park, Y. S.; Hong, S. Adv. Funct. Mater. 2022, 32, 2208793. doi: 10.1002/adfm.v32.49
[68]	Zheng, X.; Li, Z.; Zhang, Y.; Chen, M.; Liu, T.; Xiao, C.; Gao, D.; Patel, J. B.; Kuciauskas, D.; Magomedov, A.; Scheidt, R. A.; Wan, X.; Harvey, S. P.; Dai, Z.; Zhang, C.; Morales, D.; Pruett, H.; Wieliczka, B. M.; Kirmani, A. R.; Padture, N. P.; Graham, K. R.; Yan, Y.; Nazeeruddin, M. K.; Mcgehee, M. D.; Zhu, Z.; Luther, J. M. Nature Energy 2023, 8, 462. doi: 10.1038/s41560-023-01227-6
[69]	Ren, Z.; Cui, Z.; Shi, X.; Wang, L.; Dou, Y.; Wang, F.; Lin, H.; Yan, H.; Chen, S. Joule 2023, 7, 2894. doi: 10.1016/j.joule.2023.10.014
[70]	Sun, A.; Tian, C.; Zhuang, R.; Chen, C.; Zheng, Y.; Wu, X.; Tang, C.; Liu, Y.; Li, Z.; Ouyang, B.; Du, J.; Li, Z.; Cai, J.; Chen, J.; Wu, X.; Hua, Y.; Chen, C.-C. Adv. Energy Mater. 2024, 2303941.
[71]	Jiang, W.; Hu, Y.; Li, F.; Lin, F. R.; Jen, A. K.-Y. CCS Chem. 2024, DOI:10.31635/ccschem.024.202303710
[72]	Truong, M. A.; Funasaki, T.; Ueberricke, L.; Nojo, W.; Murdey, R.; Yamada, T.; Hu, S.; Akatsuka, A.; Sekiguchi, N.; Hira, S.; Xie, L.; Nakamura, T.; Shioya, N.; Kan, D.; Tsuji, Y.; Iikubo, S.; Yoshida, H.; Shimakawa, Y.; Hasegawa, T.; Kanemitsu, Y.; Suzuki, T.; Wakamiya, A. J. Am. Chem. Soc. 2023, 145, 7528. doi: 10.1021/jacs.3c00805
[73]	Bin, H.; Datta, K.; Wang, J.; van der Pol, T. P.; Li, J.; Wienk, M. M.; Janssen, R. A. ACS Appl. Mater. Interfaces 2022, 14, 16497. doi: 10.1021/acsami.2c01900
[74]	Bi, H.; Liu, J.; Zhang, Z.; Wang, L.; Beresneviciute, R.; Tavgeniene, D.; Kapil, G.; Ding, C.; Baranwal, A. K.; Sahamir, S. R.; Sanehira, Y.; Segawa, H.; Grigalevicius, S.; Shen, Q.; Hayase, S. ACS Energy Lett. 2023, 8, 3852. doi: 10.1021/acsenergylett.3c01275
[75]	Li, Z.; Tan, Q.; Chen, G.; Gao, H.; Wang, J.; Zhang, X.; Xiu, J.; Chen, W.; He, Z. Nanoscale 2023, 15, 1676. doi: 10.1039/D2NR05677A
[76]	Liu, M.; Li, M.; Li, Y.; An, Y.; Yao, Z.; Fan, B.; Qi, F.; Liu, K.; Yip, H. L.; Lin, F. R.; Jen, A. K. Y. Adv. Energy Mater. 2024, 2303742.
[77]	Jiang, W.; Li, F.; Li, M.; Qi, F.; Lin, F. R.; Jen, A. K. Y. Angew. Chem. Int. Ed. 2022, 61, e202213560.
[78]	Wang, W.; Wei, K.; Yang, L.; Deng, J.; Zhang, J.; Tang, W. Mater. Horiz. 2023, 10, 2609. doi: 10.1039/D3MH00219E
[79]	He, R.; Wang, W.; Yi, Z.; Lang, F.; Chen, C.; Luo, J.; Zhu, J.; Thiesbrummel, J.; Shah, S.; Wei, K.; Luo, Y.; Wang, C.; Lai, H.; Huang, H.; Zhou, J.; Zou, B.; Yin, X.; Ren, S.; Hao, X.; Wu, L.; Zhang, J.; Zhang, J.; Stolterfoht, M.; Fu, F.; Tang, W.; Zhao, D. Nature 2023, 618, 80. doi: 10.1038/s41586-023-05992-y
[80]	Jiang, W.; Liu, M.; Li, Y.; Lin, F.; Jen, A. K. Chem. Sci. 2024, 15, 2778. doi: 10.1039/D3SC05485C
[81]	Wang, W.; Liu, X.; Wang, J.; Chen, C.; Yu, J.; Zhao, D.; Tang, W. Adv. Energy Mater. 2023, 13, 2300694. doi: 10.1002/aenm.v13.23
[82]	Yi, Z.; Wang, W.; He, R.; Zhu, J.; Jiao, W.; Luo, Y.; Xu, Y.; Wang, Y.; Zeng, Z.; Wei, K.; Zhang, J.; Tsang, S.-W.; Chen, C.; Tang, W.; Zhao, D. Energ. Environ. Sci. 2024, 17, 202. doi: 10.1039/D3EE02839A
[83]	Li, E.; Liu, C.; Lin, H.; Xu, X.; Liu, S.; Zhang, S.; Yu, M.; Cao, X. M.; Wu, Y.; Zhu, W. H. Adv. Funct. Mater. 2021, 31, 2103847. doi: 10.1002/adfm.v31.35
[84]	Li, C.; Zhang, Z.; Zhang, H.; Yan, W.; Li, Y.; Liang, L.; Yu, W.; Yu, X.; Wang, Y.; Yang, Y.; Nazeeruddin, M. K.; Gao, P. Angew. Chem. Int. Ed. 2023, 63, e202315281.
[85]	Guo, R.; Zhang, X.; Zheng, X.; Li, L.; Li, M.; Zhao, Y.; Zhang, S.; Luo, L.; You, S.; Li, W.; Gong, Z.; Huang, R.; Cui, Y.; Rong, Y.; Zeng, H.; Li, X. Adv. Funct. Mater. 2023, 33, 2211955. doi: 10.1002/adfm.v33.10
[86]	Ozaki, M.; Ishikura, Y.; Truong, M. A.; Liu, J.; Okada, I.; Tanabe, T.; Sekimoto, S.; Ohtsuki, T.; Murata, Y.; Murdey, R.; Wakamiya, A. J. Mater. Chem. A 2019, 7, 16947. doi: 10.1039/C9TA02142F
[87]	Wang, J.; Liu, K.; Ma, L.; Zhan, X. Chem. Rev. 2016, 116, 14675. doi: 10.1021/acs.chemrev.6b00432
[88]	Yalcin, E.; Can, M.; Rodriguez-Seco, C.; Aktas, E.; Pudi, R.; Cambarau, W.; Demic, S.; Palomares, E. Energ. Environ. Sci. 2019, 12, 230. doi: 10.1039/c8ee01831f
[89]	Aktas, E.; Phung, N.; Köbler, H.; González, D. A.; Méndez, M.; Kafedjiska, I.; Turren-Cruz, S.-H.; Wenisch, R.; Lauermann, I.; Abate, A.; Palomares, E. Energ. Environ. Sci. 2021, 14, 3976. doi: 10.1039/D0EE03807E
[90]	Aktas, E.; Pudi, R.; Phung, N.; Wenisch, R.; Gregori, L.; Meggiolaro, D.; Flatken, M. A.; De Angelis, F.; Lauermann, I.; Abate, A.; Palomares, E. ACS Appl. Mater. Interfaces 2022, 14, 17461. doi: 10.1021/acsami.2c01981
[91]	Li, W.; Cariello, M.; Méndez, M.; Cooke, G.; Palomares, E. ACS Appl. Energy Mater. 2023, 6, 1239. doi: 10.1021/acsaem.2c02880
[92]	Yalcin, E.; Aktas, E.; Mendéz, M.; Arkan, E.; Sánchez, J. G.; Martínez-Ferrero, E.; Silvestri, F.; Barrena, E.; Can, M.; Demic, S.; Palomares, E. ACS Appl. Mater. Interfaces 2023, 15, 57153.
[93]	Li, E.; Bi, E.; Wu, Y.; Zhang, W.; Li, L.; Chen, H.; Han, L.; Tian, H.; Zhu, W. H. Adv. Funct. Mater. 2020, 30, 1909509. doi: 10.1002/adfm.v30.7
[94]	Arkan, E.; Yalcin, E.; Unal, M.; Arkan, M. Z. Y.; Can, M.; Tozlu, C.; Demic, S. Mater. Chem. Phys. 2020, 254, 123435. doi: 10.1016/j.matchemphys.2020.123435
[95]	Arkan, E.; Unal, M.; Yalcin, E.; Arkan, M. Z. Y.; Yurtdas, S.; Can, M.; Tozlu, C.; Demic, S. Mat. Sci. Semicon. Proc. 2021, 123, 105514. doi: 10.1016/j.mssp.2020.105514
[96]	Arkan, E.; Arkan, M. Z. Y.; Unal, M.; Yalcin, E.; Aydin, H.; Çelebi, C.; Can, M.; Tozlu, C.; Demic, S. Opt. Mater. 2020, 105, 109910. doi: 10.1016/j.optmat.2020.109910
[97]	Chang, C. Y.; Huang, H. H.; Tsai, H.; Lin, S. L.; Liu, P. H.; Chen, W.; Hsu, F. C.; Nie, W.; Chen, Y. F.; Wang, L. Adv. Sci. 2021, 8, 2002718. doi: 10.1002/advs.v8.5
[98]	Aktas, E.; Jiménez-López, J.; Azizi, K.; Torres, T.; Palomares, E. Nanoscale Horiz. 2020, 5, 1415. doi: 10.1039/d0nh00443j pmid: 32856637
[99]	Hung, C. M.; Mai, C. L.; Wu, C. C.; Chen, B. H.; Lu, C. H.; Chu, C. C.; Wang, M. C.; Yang, S. D.; Chen, H. C.; Yeh, C. Y.; Chou, P.-T. Angew. Chem. Int. Ed. 2023, 62, e202309831.
[100]	Zhang, Z.; Zhu, R.; Tang, Y.; Su, Z.; Hu, S.; Zhang, X.; Zhang, J.; Zhao, J.; Xue, Y.; Gao, X.; Li, G.; Pascual, J.; Abate, A.; Li, M. Adv. Mater. 2024, 2312264.
[101]	Liao, Q.; Wang, Y.; Zhang, Z.; Yang, K.; Shi, Y.; Feng, K.; Li, B.; Huang, J.; Gao, P.; Guo, X. J. Energy Chem. 2022, 68, 87. doi: 10.1016/j.jechem.2021.11.001
[102]	Liao, Q.; Wang, Y.; Hao, M.; Li, B.; Yang, K.; Ji, X.; Wang, Z.; Wang, K.; Chi, W.; Guo, X.; Huang, W. ACS Appl. Mater. Interfaces 2022, 14, 43547. doi: 10.1021/acsami.2c10758
[103]	Li, L.; Wei, M.; Carnevali, V.; Zeng, H.; Zeng, M.; Liu, R.; Lempesis, N.; Eickemeyer, F. T.; Luo, L.; Agosta, L.; Dankl, M.; Zakeeruddin, S. M.; Roethlisberger, U.; Grätzel, M.; Rong, Y.; Li, X. Adv. Mater. 2023, 2303869.
[104]	Zhang, S.; Wu, R.; Mu, C.; Wang, Y.; Han, L.; Wu, Y.; Zhu, W.-H. ACS Mater. Lett. 2022, 4, 1976.
[105]	Guo, H.; Liu, C.; Hu, H.; Zhang, S.; Ji, X.; Cao, X.-M.; Ning, Z.; Zhu, W.-H.; Tian, H.; Wu, Y. Natl. Sci. Rev. 2023, 10, nwad057.
[106]	Kong, W.; Li, W.; Liu, C.; Liu, H.; Miao, J.; Wang, W.; Chen, S.; Hu, M.; Li, D.; Amini, A.; Yang, S.; Wang, J.; Xu, B.; Cheng, C. ACS Nano 2019, 13, 1625.
[107]	Huang, S.; Liu, Z.; Xu, J.; Zhang, D.; Dong, H.; Wu, Z.; Duan, L. Chem. Eng. J. 2022, 430, 132986. doi: 10.1016/j.cej.2021.132986
[108]	Jiang, Q.; Tirawat, R.; Kerner, R. A.; Gaulding, E. A.; Xian, Y.; Wang, X.; Newkirk, J. M.; Yan, Y.; Berry, J. J.; Zhu, K. Nature 2023, 623, 313. doi: 10.1038/s41586-023-06610-7
[109]	Cui, H.; Huang, L.; Zhou, S.; Wang, C.; Hu, X.; Guan, H.; Wang, S.; Shao, W.; Pu, D.; Dong, K.; Zhou, J.; Jia, P.; Wang, W.; Tao, C.; Ke, W.; Fang, G. Energ. Environ. Sci. 2023, 16, 5992. doi: 10.1039/D3EE02818F
[110]	Zeng, K.; Chen, Y.; Zhu, W.-H.; Tian, H.; Xie, Y. J. Am. Chem. Soc. 2020, 142, 5154. doi: 10.1021/jacs.9b12675

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
V1036	-4.7	ITO/V1036+C4/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83-Br_0.17)₃/C₆₀/BCP/Cu	1.63	1.09	21.4	76.5	17.8	[57]
MeO- 2PACz	-5.1	ITO/MeO-2PACz/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83- Br_0.17)₃/C₆₀/BCP/Cu(Ag)	1.63	1.144	22.2	80.5	20.2	[58]
2PACz	-5.6	ITO/2PACz/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83Br_0.17)₃/ C₆₀/BCP/Cu(Ag)	1.60	1.188	21.9	80.2	20.8	[58]
2PACz	-5.6	两端: silicon(Si)heterojunction bottom cell/ITO/2PACz/Cs_0.22FA_0.78Pb(I_0.85Br_0.15)₃+5%MAPbCl₃/LiF or PI+C₆₀/SnO₂/IZO/LiF/Ag	顶电池: 1.68 底电池: Si	1.98	20.24	81.81	32.5	[59]
DC-PA	-5.38	ITO/DC-PA+IAHA/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.16	24.66	82.45	23.59	[61]
Ph-2PACz	-5.52	ITO/Ph-2PACz/Cs_0.15FA_0.65MA_0.2Pb(I_0.8Br_0.2)₃/LiF/C₆₀/BCP/Cu	1.67	1.26	20.5	82.6	21.3	[64]
Ph-2PACz	-5.52	两端: Ag/ITO/<p>a-Si:H/<i>a-Si:H/c-Si(n)/ <i>a-Si:H/<n>a-Si:H/ITO/Ph-2PACz/Cs_0.15FA_0.65-MA_0.2Pb(I_0.8Br_0.2)₃/LiF/C₆₀/SnO₂/Ag/ITO/ARC	顶电池: 1.67 底电池: Si	1.91	19.1	79.1	28.9	[64]
Br-2PACz	-5.28	ITO/Br-2PACz/Cs_0.25FA_0.75Sn_0.5Pb_0.5I₃/C₆₀/BCP/Ag	1.2~1.3	0.81	32.1	75	19.51	[65]
Br-2EPT	-5.47	TCO/Br-2EPT/FA_0.92MA_0.08Pb(I_0.92Br_0.08)₃/C₆₀/BCP/Cu	1.56	1.09	25.11	82	22.44	[66]
Br-2EPO	-5.37	FTO/Br-2EPO/Cs_0.05(FA_0.92MA_0.08)Pb(I_0.92Br_0.08)₃/ C₆₀/BCP/Cu		1.04	24.25	80.74	21.02	[67]
Br-2EPSe	-5.33	FTO/Br-2EPSe/Cs_0.05(FA_0.92MA_0.08)Pb(I_0.92Br_0.08)₃/C₆₀/BCP/Cu		1.12	24.49	82.86	22.73	[67]
Me- 4PACz	-5.6	ITO/Me-4PACz/Cs_0.05(FA_0.77MA_0.23)_0.95Pb(I_0.77- Br_0.23)₃/(LiF)/C₆₀/SnO₂/Ag	1.68	1.22	20.7	82	20.8	[54]
		两端: Ag/AZO/a-Si(p)/a-Si(i)/c-Si(n)/a-Si(i)/nc-SiO_x(n)/ ITO/Me-4PACz/Cs_0.05(FA_0.77MA_0.23)_0.95Pb(I_0.77- Br_0.23)₃/(LiF)/C₆₀/SnO₂/IZO/Ag/LiF	顶电池: 1.68 底电池: Si	1.90	19.26	79.52	29.15	[54]
		FTO/NiO_x/Me-4PACz/Cs_0.05MA_0.05FA_0.90PbI₃/ DMDP/C₆₀/BCP/Ag	1.5	1.17	26.2	85.8	26.4	[51]
Poly- 4PACz	-5.28	ITO/Poly-4PACz/MA_0.7FA_0.3PbI₃ (1,000 nm)/C₆₀/BCP/Cu	—	1.17	24.8	83.9	24.4	[69]
Ph-4PACz	-5.52	FTO/Al₂O₃-NPs/Ph-4PACz/Cs_0.05(FA_0.98MA_0.02)_0.95Pb(I_0.98Br_0.02)₃/PDI/PCBM/BCP/Ag	1.55	1.207	25.18	84.23	25.6	[70]
Cbz2S	-5.45	ITO/Cbz2S/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	0.997	24.15	80.20	19.23	[71]
Cbz2SMe	-5.37	ITO/Cbz2SMe/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.172	25.16	82.82	24.42	[71]
3PATAT- C3	-5.44	TCO/3PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag	1.57	1.13	24.5	83	23.0	[72]
2PATAT- C3	-5.43	TCO/2PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.14	23.3	83	22.2
1PATAT- C3	-5.45	TCO/1PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.06	24.0	82	21.1
3PATAT- C4	-5.41	TCO/3PATAT-C4/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.14	23.3	83	22.1
4dp3PACz	-5.77	ITO/4dp3PACz/FA_0.8Cs_0.2PbI_1.8Br_1.2/GuBr/C₆₀/BCP/Ag	1.77	1.214	17.8	79.44	17.17	[74]
4dp3PACz	-5.77	两端: ITO/4dp3PACz/FA_0.8Cs_0.2PbI_1.8Br_1.2)/C₆₀/ ALDSnO₂/IZO/PEDOT:PSS/Cs_0.025FA_0.475MA_0.5- Sn_0.5Pb_0.5I_2.925Br_0.075/C₆₀/BCP/Ag	顶电池: 1.77 底电池: 1.25	1.77	17.53	85.3	26.47	[74]
2BrCzPA	-6.15	ITO/2BrCzPA/Cs_0.05(FA_0.85MA_0.15)_0.95- Pb(I_0.85Br_0.15)₃/PCBM/BCP/Ag	1.62	1.10	11.43	33.77	4.24	[75]
2BrPTZPA	-5.77	ITO/2BrPTZPA/Cs_0.05(FA_0.85MA_0.15)_0.95- Pb(I_0.85Br_0.15)₃/PCBM/BCP/Ag		1.18	22.29	80.02	22.06
2BrPXZPA	-5.59	ITO/2BrPXZPA/Cs_0.05(FA_0.85MA_0.15)_0.95Pb(I_0.85- Br_0.15)₃/PCBM/BCP/Ag		1.19	22.51	81.69	22.93
DMAcPA	-5.98	ITO/(DMAcPA)Perovskite/PEABr/PCBM/BCP/ Ag	1.56	1.187	25.69	84.73	25.86	[55]
MeO- BTBT	-5.39	ITO/MeO-BTBT/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/ BCP/Ag	1.56^a	1.16	24.87	85.28	24.53	[76]
4PACz	-5.43	ITO/4PACz/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.07	23.20	58.43	14.5	[77]
CbzPh	-5.36	ITO/CbzPh/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag		1.12	23.43	73.06	19.2
CbzNaph	-5.24	ITO/CbzNaph/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag		1.17	24.69	83.39	24.1
4PADCB	-5.53	ITO/4PADCB/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ SnO₂/Cu	1.77	1.31	17.80	79.18	18.46	[79]
4PADCB	-5.53	两端: ITO/4PADCB/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/SnO₂/IZO/PEDOT:PSS/FA_0.6MA_0.3Cs_0.1Sn_0.5Pb_0.5I₃/C₆₀/SnO₂/Cu	顶电池: 1.77 底电池: 1.25	2.11	15.37	83.3	27.01	[79]
BCB- C4PA	-5.25	ITO/BCB-C4PA/Cs_0.07FA_0.9MA_0.03Pb(I_0.92Br_0.08)₃/ C₆₀/BCP/Ag	1.55	1.13	24.4	80	22.2	[78]
CbzBF	-5.50	ITO/CbzBF/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.09	24.00	83.04	21.72	[80]
CbzBT	-5.54	ITO/CbzBT/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.16	24.54	84.41	24.04	[80]
BCB10Br-C4PA	-5.63	ITO/BCB10Br-C4PA/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ ALD-SnO₂/Cu	1.77	1.286	17.54	82.61	18.63	[81]
BCB10Br-C4PA	-5.63	四端: ITO/BCB10Br-C4PA/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ ALD-SnO₂/transparent electrode/ glass/ITO/PEDOT:PSS/(FASnI₃)_0.6(MAPbI₃)_0.4/C₆₀/BCP/Cu	顶电池: 1.77 底电池: 1.25	1.264	—	—	26.24	[81]
DCB-BPA	-5.56	ITO/DCB-BPA/FA_0.8Cs_0.2PbI_1.8Br_1.2/C₆₀/BCP/Cu	1.77	1.33	17.75	82.70	19.53	[82]
DCB-BPA	-5.56	四端: ITO/DCB-BPA/FA_0.8Cs_0.2PbI_1.8Br_1.2/C₆₀/SnO₂/IZO/transparent electrode/glass/ITO/ PEDOT:PSS/(FASnI₃)_0.6(MAPbI₃)_0.4/C₆₀/BCP/Cu	顶电池: 1.77 底电池: 1.25	—	—	—	26.90	[82]
MeO- 4PADCB	-5.34	ITO/NiO_x/MeO-4PADCB/Cs_0.05FA_0.85MA_0.1PbI₃/ CF3-PEAI+MAI/C₆₀/BCP/Ag	1.53	1.19	25.4	84.6	25.6	[49]
		ITO/NiO_x/MeO-4PADCB/Cs_0.05FA_0.8MA_0.15Pb(I_0.76Br_0.24)₃/CF₃-PEAI+MAI/C₆₀/BCP/Ag	1.68	1.25	21.5	84.5	22.7
		ITO/NiO_x/MeO-4PADCB/Cs_0.15FA_0.85Pb(I_0.6Br_0.4)₃/CF₃-PEAI+MAI/C₆₀/BCP/Ag	1.80	1.34	17.9	83.6	20.1
TPT-H6	-5.14	ITO/TPT-H6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/BCP/Ag	1.5	0.714	21.54	65.19	11.97	[83]
TPT-S6	-5.18	ITO/TPT-S6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		0.998	21.50	75.31	16.16
TPT-C6	-5.20	ITO/TPT-C6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		1.077	23.32	75.46	18.87
TPT-P6	-5.20	ITO/TPT-P6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		1.125	23.49	81.08	21.43
MeO- PhPACz	-5.61	ITO/MeO-PhPACz/Cs_0.05FA_0.8MA_0.15Pb(I_0.75Br_0.25)₃/C₆₀/BCP/Ag	1.68	1.215	20.59	84.28	21.10	[84]
PPA	-5.28	ITO/PPA/Cs_0.05FA_0.85MA_0.1PbI₃/OABr/PCBM/BCP/Ag	1.53	1.14	24.83	82.0	23.24	[85]
PPAOMe	-5.02	ITO/PPA/Cs_0.05FA_0.85MA_0.1PbI₃/OABr/PCBM/BCP/Ag	1.53	1.10	24.70	79.2	21.52	[85]

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
V1036	-4.7	ITO/V1036+C4/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83-Br_0.17)₃/C₆₀/BCP/Cu	1.63	1.09	21.4	76.5	17.8	[57]
MeO- 2PACz	-5.1	ITO/MeO-2PACz/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83- Br_0.17)₃/C₆₀/BCP/Cu(Ag)	1.63	1.144	22.2	80.5	20.2	[58]
2PACz	-5.6	ITO/2PACz/Cs_0.05(MA_0.17FA_0.83)_0.95Pb(I_0.83Br_0.17)₃/ C₆₀/BCP/Cu(Ag)	1.60	1.188	21.9	80.2	20.8	[58]
2PACz	-5.6	两端: silicon(Si)heterojunction bottom cell/ITO/2PACz/Cs_0.22FA_0.78Pb(I_0.85Br_0.15)₃+5%MAPbCl₃/LiF or PI+C₆₀/SnO₂/IZO/LiF/Ag	顶电池: 1.68 底电池: Si	1.98	20.24	81.81	32.5	[59]
DC-PA	-5.38	ITO/DC-PA+IAHA/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.16	24.66	82.45	23.59	[61]
Ph-2PACz	-5.52	ITO/Ph-2PACz/Cs_0.15FA_0.65MA_0.2Pb(I_0.8Br_0.2)₃/LiF/C₆₀/BCP/Cu	1.67	1.26	20.5	82.6	21.3	[64]
Ph-2PACz	-5.52	两端: Ag/ITO/<p>a-Si:H/<i>a-Si:H/c-Si(n)/ <i>a-Si:H/<n>a-Si:H/ITO/Ph-2PACz/Cs_0.15FA_0.65-MA_0.2Pb(I_0.8Br_0.2)₃/LiF/C₆₀/SnO₂/Ag/ITO/ARC	顶电池: 1.67 底电池: Si	1.91	19.1	79.1	28.9	[64]
Br-2PACz	-5.28	ITO/Br-2PACz/Cs_0.25FA_0.75Sn_0.5Pb_0.5I₃/C₆₀/BCP/Ag	1.2~1.3	0.81	32.1	75	19.51	[65]
Br-2EPT	-5.47	TCO/Br-2EPT/FA_0.92MA_0.08Pb(I_0.92Br_0.08)₃/C₆₀/BCP/Cu	1.56	1.09	25.11	82	22.44	[66]
Br-2EPO	-5.37	FTO/Br-2EPO/Cs_0.05(FA_0.92MA_0.08)Pb(I_0.92Br_0.08)₃/ C₆₀/BCP/Cu		1.04	24.25	80.74	21.02	[67]
Br-2EPSe	-5.33	FTO/Br-2EPSe/Cs_0.05(FA_0.92MA_0.08)Pb(I_0.92Br_0.08)₃/C₆₀/BCP/Cu		1.12	24.49	82.86	22.73	[67]
Me- 4PACz	-5.6	ITO/Me-4PACz/Cs_0.05(FA_0.77MA_0.23)_0.95Pb(I_0.77- Br_0.23)₃/(LiF)/C₆₀/SnO₂/Ag	1.68	1.22	20.7	82	20.8	[54]
		两端: Ag/AZO/a-Si(p)/a-Si(i)/c-Si(n)/a-Si(i)/nc-SiO_x(n)/ ITO/Me-4PACz/Cs_0.05(FA_0.77MA_0.23)_0.95Pb(I_0.77- Br_0.23)₃/(LiF)/C₆₀/SnO₂/IZO/Ag/LiF	顶电池: 1.68 底电池: Si	1.90	19.26	79.52	29.15	[54]
		FTO/NiO_x/Me-4PACz/Cs_0.05MA_0.05FA_0.90PbI₃/ DMDP/C₆₀/BCP/Ag	1.5	1.17	26.2	85.8	26.4	[51]
Poly- 4PACz	-5.28	ITO/Poly-4PACz/MA_0.7FA_0.3PbI₃ (1,000 nm)/C₆₀/BCP/Cu	—	1.17	24.8	83.9	24.4	[69]
Ph-4PACz	-5.52	FTO/Al₂O₃-NPs/Ph-4PACz/Cs_0.05(FA_0.98MA_0.02)_0.95Pb(I_0.98Br_0.02)₃/PDI/PCBM/BCP/Ag	1.55	1.207	25.18	84.23	25.6	[70]
Cbz2S	-5.45	ITO/Cbz2S/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	0.997	24.15	80.20	19.23	[71]
Cbz2SMe	-5.37	ITO/Cbz2SMe/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.172	25.16	82.82	24.42	[71]
3PATAT- C3	-5.44	TCO/3PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag	1.57	1.13	24.5	83	23.0	[72]
2PATAT- C3	-5.43	TCO/2PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.14	23.3	83	22.2
1PATAT- C3	-5.45	TCO/1PATAT-C3/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.06	24.0	82	21.1
3PATAT- C4	-5.41	TCO/3PATAT-C4/Cs_0.05FA_0.80MA_0.15PbI_2.75Br_0.25/ EDAI₂/C₆₀/BCP/Ag		1.14	23.3	83	22.1
4dp3PACz	-5.77	ITO/4dp3PACz/FA_0.8Cs_0.2PbI_1.8Br_1.2/GuBr/C₆₀/BCP/Ag	1.77	1.214	17.8	79.44	17.17	[74]
4dp3PACz	-5.77	两端: ITO/4dp3PACz/FA_0.8Cs_0.2PbI_1.8Br_1.2)/C₆₀/ ALDSnO₂/IZO/PEDOT:PSS/Cs_0.025FA_0.475MA_0.5- Sn_0.5Pb_0.5I_2.925Br_0.075/C₆₀/BCP/Ag	顶电池: 1.77 底电池: 1.25	1.77	17.53	85.3	26.47	[74]
2BrCzPA	-6.15	ITO/2BrCzPA/Cs_0.05(FA_0.85MA_0.15)_0.95- Pb(I_0.85Br_0.15)₃/PCBM/BCP/Ag	1.62	1.10	11.43	33.77	4.24	[75]
2BrPTZPA	-5.77	ITO/2BrPTZPA/Cs_0.05(FA_0.85MA_0.15)_0.95- Pb(I_0.85Br_0.15)₃/PCBM/BCP/Ag		1.18	22.29	80.02	22.06
2BrPXZPA	-5.59	ITO/2BrPXZPA/Cs_0.05(FA_0.85MA_0.15)_0.95Pb(I_0.85- Br_0.15)₃/PCBM/BCP/Ag		1.19	22.51	81.69	22.93
DMAcPA	-5.98	ITO/(DMAcPA)Perovskite/PEABr/PCBM/BCP/ Ag	1.56	1.187	25.69	84.73	25.86	[55]
MeO- BTBT	-5.39	ITO/MeO-BTBT/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/ BCP/Ag	1.56^a	1.16	24.87	85.28	24.53	[76]
4PACz	-5.43	ITO/4PACz/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.07	23.20	58.43	14.5	[77]
CbzPh	-5.36	ITO/CbzPh/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag		1.12	23.43	73.06	19.2
CbzNaph	-5.24	ITO/CbzNaph/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag		1.17	24.69	83.39	24.1
4PADCB	-5.53	ITO/4PADCB/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ SnO₂/Cu	1.77	1.31	17.80	79.18	18.46	[79]
4PADCB	-5.53	两端: ITO/4PADCB/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/SnO₂/IZO/PEDOT:PSS/FA_0.6MA_0.3Cs_0.1Sn_0.5Pb_0.5I₃/C₆₀/SnO₂/Cu	顶电池: 1.77 底电池: 1.25	2.11	15.37	83.3	27.01	[79]
BCB- C4PA	-5.25	ITO/BCB-C4PA/Cs_0.07FA_0.9MA_0.03Pb(I_0.92Br_0.08)₃/ C₆₀/BCP/Ag	1.55	1.13	24.4	80	22.2	[78]
CbzBF	-5.50	ITO/CbzBF/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.09	24.00	83.04	21.72	[80]
CbzBT	-5.54	ITO/CbzBT/Cs_0.05MA_0.15FA_0.80PbI₃/PI/C₆₀/BCP/Ag	1.56^a	1.16	24.54	84.41	24.04	[80]
BCB10Br-C4PA	-5.63	ITO/BCB10Br-C4PA/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ ALD-SnO₂/Cu	1.77	1.286	17.54	82.61	18.63	[81]
BCB10Br-C4PA	-5.63	四端: ITO/BCB10Br-C4PA/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/ ALD-SnO₂/transparent electrode/ glass/ITO/PEDOT:PSS/(FASnI₃)_0.6(MAPbI₃)_0.4/C₆₀/BCP/Cu	顶电池: 1.77 底电池: 1.25	1.264	—	—	26.24	[81]
DCB-BPA	-5.56	ITO/DCB-BPA/FA_0.8Cs_0.2PbI_1.8Br_1.2/C₆₀/BCP/Cu	1.77	1.33	17.75	82.70	19.53	[82]
DCB-BPA	-5.56	四端: ITO/DCB-BPA/FA_0.8Cs_0.2PbI_1.8Br_1.2/C₆₀/SnO₂/IZO/transparent electrode/glass/ITO/ PEDOT:PSS/(FASnI₃)_0.6(MAPbI₃)_0.4/C₆₀/BCP/Cu	顶电池: 1.77 底电池: 1.25	—	—	—	26.90	[82]
MeO- 4PADCB	-5.34	ITO/NiO_x/MeO-4PADCB/Cs_0.05FA_0.85MA_0.1PbI₃/ CF3-PEAI+MAI/C₆₀/BCP/Ag	1.53	1.19	25.4	84.6	25.6	[49]
		ITO/NiO_x/MeO-4PADCB/Cs_0.05FA_0.8MA_0.15Pb(I_0.76Br_0.24)₃/CF₃-PEAI+MAI/C₆₀/BCP/Ag	1.68	1.25	21.5	84.5	22.7
		ITO/NiO_x/MeO-4PADCB/Cs_0.15FA_0.85Pb(I_0.6Br_0.4)₃/CF₃-PEAI+MAI/C₆₀/BCP/Ag	1.80	1.34	17.9	83.6	20.1
TPT-H6	-5.14	ITO/TPT-H6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/BCP/Ag	1.5	0.714	21.54	65.19	11.97	[83]
TPT-S6	-5.18	ITO/TPT-S6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		0.998	21.50	75.31	16.16
TPT-C6	-5.20	ITO/TPT-C6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		1.077	23.32	75.46	18.87
TPT-P6	-5.20	ITO/TPT-P6/Cs_0.05MA_0.12FA_0.83Pb(I_0.85Br_0.15)₃/C₆₀/ BCP/Ag		1.125	23.49	81.08	21.43
MeO- PhPACz	-5.61	ITO/MeO-PhPACz/Cs_0.05FA_0.8MA_0.15Pb(I_0.75Br_0.25)₃/C₆₀/BCP/Ag	1.68	1.215	20.59	84.28	21.10	[84]
PPA	-5.28	ITO/PPA/Cs_0.05FA_0.85MA_0.1PbI₃/OABr/PCBM/BCP/Ag	1.53	1.14	24.83	82.0	23.24	[85]
PPAOMe	-5.02	ITO/PPA/Cs_0.05FA_0.85MA_0.1PbI₃/OABr/PCBM/BCP/Ag	1.53	1.10	24.70	79.2	21.52	[85]

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
TPA	-5.33	ITO/TPA/MAPbI₃/PCBM/BCP/Ag	1.5	1.06	19.4	77	15.9	[88]
MC-43	-5.11	ITO/MC-43/MAPbI₃/PCBM/BCP/Ag	1.5	1.07	20.3	80	17.3	[88]
EVAD03	-5.05	ITO/EVAD03/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/BCP/Cu	1.6	1.156	22.9	80	21.2	[89]
EVAD04	-5.06	ITO/EVAD03/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/BCP/Cu	1.6	1.164	22.6	80	21.0	[89]
RC-24	-5.13	ITO/RC-24/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu	1.6	1.123	22.3	79	19.8	[90]
RC-25	-5.22	ITO/RC-25/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu		1.116	22.1	79	19.6
RC-34	-5.32	ITO/RC-34/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu		1.109	22.5	79	19.7
MC-45	-5.12	ITO/MC-45/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag	1.58	1.09	20.56	74.35	16.69	[92]
MC-54	-5.16	ITO/MC-54/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag		1.10	22.32	79.15	19.52
MC-55	-5.26	ITO/MC-55/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag		1.09	21.90	79.32	18.99
Spiro- Acid	-5.02	ITO/Spiro-Acid/Cs_0.05(FA_0.85MA_0.15)_0.95Pb(I_0.85- Br_0.15)₃/C₆₀/BCP/Ag	1.63	0.99	22.20	82.6	18.15	[91]
2F	-5.42	ITO/2F/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/TEACl/C₆₀/SnO₂/Cu	1.77	1.31	17.93	82.31	19.33	[44]
		ITO/2F/FA_0.8Cs_0.2Pb(I_0.95Br_0.05)₃/TEACl/C₆₀/SnO₂/ Cu	1.57	1.15	23.59	82.42	22.36
		ITO/2F/FA_0.6MA_0.3Cs_0.1Pb_0.5Sn_0.5I₃/EDAI₂/C₆₀/SnO₂/Cu	1.25	0.872	32.55	81.89	23.24
		两端: ITO/(PTAA)2F/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/SnO₂/ IZO/(PEDOT:PSS)or(PEDOT:PSS/2F)/FA_0.6MA_0.3Cs_0.1Pb_0.5Sn_0.5I₃/C₆₀/ALD-SnO₂/Cu	顶电池: 1.77 底电池: 1.25	2.130	15.52	82.36	27.22
TPA-PT- C6	-5.2	ITO/TPA-PT-C6+CA-Br/MAPbI₃/PCBM/BCP/Ag	1.5	1.039	21.80	77.35	17.49	[93]
EA-49	-5.07	ITO/EA-49/MAPbI₃/PCBM/Ca/Ag	1.5	1.024	17.25	68.15	12.03	[94]
P3HT- COOH	-5.42	ITO/P3HT-COOH/MAPbI₃/PCBM-PEI/Ag	1.58	1.010	22.83	82.6	20.74	[97]
TT1	-5.4	ITO/TT1/MAPbI₃/C₆₀/Ag	1.5	1.045±0.01	17.85±1.0	68.7± 0.6	14.85	[98]
AC-1	-5.39	ITO/AC-1/perovskite/PEAI/PCBM/BCP/Ag	1.55	1.084	18.83	80.49	16.43	[99]
AC-3	-5.39	ITO/AC-3/perovskite/PEAI/PCBM/BCP/Ag		1.108	24.27	82.56	22.20
AC-5	-5.39	ITO/AC-5/perovskite/PEAI/PCBM/BCP/Ag		1.130	24.42	84.05	23.19
9CPA	-5.19	FTO/9CPA/Cs_0.1FA_0.6MA_0.3Pb_0.5Sn_0.5I₃/C₆₀/BCP/Ag	1.25	0.89	32.5	76	22.1	[100]
9CAA	-5.35	FTO/9CAA/Cs_0.1FA_0.6MA_0.3Pb_0.5Sn_0.5I₃/C₆₀/BCP/ Ag	1.25	0.89	32.8	79	23.1	[100]

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
TPA	-5.33	ITO/TPA/MAPbI₃/PCBM/BCP/Ag	1.5	1.06	19.4	77	15.9	[88]
MC-43	-5.11	ITO/MC-43/MAPbI₃/PCBM/BCP/Ag	1.5	1.07	20.3	80	17.3	[88]
EVAD03	-5.05	ITO/EVAD03/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/BCP/Cu	1.6	1.156	22.9	80	21.2	[89]
EVAD04	-5.06	ITO/EVAD03/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/BCP/Cu	1.6	1.164	22.6	80	21.0	[89]
RC-24	-5.13	ITO/RC-24/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu	1.6	1.123	22.3	79	19.8	[90]
RC-25	-5.22	ITO/RC-25/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu		1.116	22.1	79	19.6
RC-34	-5.32	ITO/RC-34/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Cu		1.109	22.5	79	19.7
MC-45	-5.12	ITO/MC-45/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag	1.58	1.09	20.56	74.35	16.69	[92]
MC-54	-5.16	ITO/MC-54/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag		1.10	22.32	79.15	19.52
MC-55	-5.26	ITO/MC-55/Cs_0.05FA_0.79MA_0.16Pb(I_0.84Br_0.16)₃/C₆₀/ BCP/Ag		1.09	21.90	79.32	18.99
Spiro- Acid	-5.02	ITO/Spiro-Acid/Cs_0.05(FA_0.85MA_0.15)_0.95Pb(I_0.85- Br_0.15)₃/C₆₀/BCP/Ag	1.63	0.99	22.20	82.6	18.15	[91]
2F	-5.42	ITO/2F/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/TEACl/C₆₀/SnO₂/Cu	1.77	1.31	17.93	82.31	19.33	[44]
		ITO/2F/FA_0.8Cs_0.2Pb(I_0.95Br_0.05)₃/TEACl/C₆₀/SnO₂/ Cu	1.57	1.15	23.59	82.42	22.36
		ITO/2F/FA_0.6MA_0.3Cs_0.1Pb_0.5Sn_0.5I₃/EDAI₂/C₆₀/SnO₂/Cu	1.25	0.872	32.55	81.89	23.24
		两端: ITO/(PTAA)2F/FA_0.8Cs_0.2Pb(I_0.6Br_0.4)₃/C₆₀/SnO₂/ IZO/(PEDOT:PSS)or(PEDOT:PSS/2F)/FA_0.6MA_0.3Cs_0.1Pb_0.5Sn_0.5I₃/C₆₀/ALD-SnO₂/Cu	顶电池: 1.77 底电池: 1.25	2.130	15.52	82.36	27.22
TPA-PT- C6	-5.2	ITO/TPA-PT-C6+CA-Br/MAPbI₃/PCBM/BCP/Ag	1.5	1.039	21.80	77.35	17.49	[93]
EA-49	-5.07	ITO/EA-49/MAPbI₃/PCBM/Ca/Ag	1.5	1.024	17.25	68.15	12.03	[94]
P3HT- COOH	-5.42	ITO/P3HT-COOH/MAPbI₃/PCBM-PEI/Ag	1.58	1.010	22.83	82.6	20.74	[97]
TT1	-5.4	ITO/TT1/MAPbI₃/C₆₀/Ag	1.5	1.045±0.01	17.85±1.0	68.7± 0.6	14.85	[98]
AC-1	-5.39	ITO/AC-1/perovskite/PEAI/PCBM/BCP/Ag	1.55	1.084	18.83	80.49	16.43	[99]
AC-3	-5.39	ITO/AC-3/perovskite/PEAI/PCBM/BCP/Ag		1.108	24.27	82.56	22.20
AC-5	-5.39	ITO/AC-5/perovskite/PEAI/PCBM/BCP/Ag		1.130	24.42	84.05	23.19
9CPA	-5.19	FTO/9CPA/Cs_0.1FA_0.6MA_0.3Pb_0.5Sn_0.5I₃/C₆₀/BCP/Ag	1.25	0.89	32.5	76	22.1	[100]
9CAA	-5.35	FTO/9CAA/Cs_0.1FA_0.6MA_0.3Pb_0.5Sn_0.5I₃/C₆₀/BCP/ Ag	1.25	0.89	32.8	79	23.1	[100]

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
MPA-BT-CA	-5.29	ITO/MPA-BT-CA/(FA_0.17MA_0.94PbI_3.11)_0.95- (PbCl₂)_0.05/C₆₀/BCP/Ag	1.53	1.13	22.25	84.8	21.24	[38]
MPA-BT-BA	-5.19	ITO/MPA-BT-BA/(FA_0.17MA_0.94PbI_3.11)_0.95- (PbCl₂)_0.05/C₆₀/ZrAcac/Ag	1.53	1.12	22.76	81.0	20.58	[101]
MPA-BT-RA	-5.24	ITO/MPA-BT-RA/(FA_0.17MA_0.94PbI_3.11)_0.95- (PbCl₂)_0.05/C₆₀/ZrAcac/Ag	1.53	1.10	22.03	81.1	19.65	[101]
FMPA-BT-CA	-5.45	ITO/FMPA-BT-RA/perovskite/C₆₀/BCP/Cu	1.53	1.151	23.33	83.3	22.37	[102]
2FMPA- BT-CA	-5.37	ITO/2FMPA-BT-RA/perovskite/C₆₀/BCP/Cu	1.53	1.143	22.81	83.1	21.68	[102]
BT-T	-5.28	ITO/NiO_x/Cs_0.05(FA_0.98MA_0.02)_0.95Pb(I_0.98Br_0.02)₃- (BT-T)/PCBM/BCP/Ag	1.59	1.17	24.60	81.6	23.48	[103]
PQxD	-5.28	ITO/PQxD/FASnI₃/C₆₀/BCP/Ag	1.4	0.542	19.28	68.1	7.1	[39]
TQxD	-5.30	ITO/TQxD/FASnI₃/C₆₀/BCP/Ag	1.4	0.574	21.05	68.8	8.3	[39]
Cz-CA	-5.72	ITO/Cz-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92Br_0.08)₃/ PEAI/PCBM/C₆₀/BCP/Ag	1.56	—	—	—	20.17	[104]
Cz-Ph-CA	-5.53	ITO/Cz-Ph-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92- Br_0.08)₃/PEAI/PCBM/C₆₀/BCP/Ag		—	—	—	20.66
TPA-CA	-5.87	ITO/TPA-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92Br_0.08)₃/PEAI/PCBM/C₆₀/BCP/Ag		—	—	—	17.58
TPA-Ph- CA	-5.61	ITO/TPA-Ph-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92- Br_0.08)₃/PEAI/PCBM/C₆₀/BCP/Ag		—	—	—	20.26
MPA-CA	-5.45	ITO/MPA-Ph-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92- Br_0.08)₃/PEAI/PCBM/C₆₀/BCP/Ag		—	—	—	20.36
MPA-Ph-CA	-5.39	ITO/MPA-Ph-CA/Cs_0.05(MA_0.08FA_0.92)_0.95Pb(I_0.92- Br_0.08)₃/PEAI/PCBM/C₆₀/BCP/Ag		1.139	23.55	84.02	22.53

自组装单分子空穴传输层在反式钙钛矿太阳电池的研究进展

Research Progress of Self-assembled Hole-transporting Monolayers in Inverted Perovskite Solar Cells

RichHTML

PDF

Knowledge

Abstract

Cite this article

share this article

Fig. & Tab. 12

References 110

Related Articles 15

Recommended Articles

Metrics

Comments

分子名	HOMO (eV)	器件结构	钙钛矿带隙/eV	V_oc/V	J_sc/ (mA•cm⁻²)	FF/%	PCE/%	Ref.
MTPA-BA	-5.48	ITO/MTPA-BA/Cs_0.05(FA_0.95MA_0.05)_0.95Pb(I_0.95- Br_0.05)₃/PCBM/C₆₀/BCP/Ag	1.57	1.14	23.24	85.2	22.62	[105]
MPA-CPA	-5.4	ITO/MPA-CAP/ Cs_0.05(FA_0.95MA_0.05)_0.95Pb(I_0.95Br_0.05)₃/F-PEAI/C₆₀/ BCP/Ag	1.56	1.21	24.78	84.7	25.4	[43]
PQx	-5.28	ITO/PQx/FASnI₃/C₆₀/BCP/Ag	1.4	0.455	19.97	66.6	6.1	[39]
TQx	-5.30	ITO/TQx/FASnI₃/C₆₀/BCP/Ag	1.4	0.546	21.30	69.0	8.0	[39]
TPAC	-5.35	ITO/TPAC/MAPbI_3-xCl_x/C₆₀/BCP/Ag	1.6	1.12	22.07	78.89	19.42	[106]
DMeTPA	-5.36	ITO/DMeTPA/Cs_0.05(FA_0.88MA_0.12)_0.95PbI₃/C₆₀/BCP/Ag	1.53	1.00	24.31	80.5	19.47	[107]
DMeTPA-O	-5.41	ITO/DMeTPA-O/Cs_0.05(FA_0.88MA_0.12)_0.95PbI₃/C₆₀/ BCP/Ag		1.01	24.93	81.7	20.57
DMeOTPA-O	-5.32	ITO/DMeOTPA-O/Cs_0.05(FA_0.88MA_0.12)_0.95PbI₃/C₆₀/BCP/Ag		0.97	23.82	80.8	18.67

[1]	Zhixiang Yuan, Hao Zhang, Sijia Hu, Botao Zhang, Jianjun Zhang, Guanglei Cui. Research Progress of Ion-initiated in situ Generated Solid Polymer Electrolytes for High-safety Lithium Batteries^★ [J]. Acta Chimica Sinica, 2023, 81(8): 1064-1080.
[2]	Fengqin Gao, Yang Liu, Yinli Zhang, Yucheng Jiang. Study on Construction and Performance of Immobilized Enzyme Reactors by Carboxyl-functionalized Fe₃O₄ [J]. Acta Chimica Sinica, 2023, 81(4): 338-344.
[3]	Han Zha, Jin Fang, Lingpeng Yan, Yongzhen Yang, Changqi Ma. Research Progress of Thermal Failure Mechanism and Ternary Blending to Improve Thermal Stability of Organic Solar Cells [J]. Acta Chimica Sinica, 2023, 81(2): 131-145.
[4]	Yanfu Liu, Shilin Li, Yanan Jing, Linge Xiao, Huiqiong Zhou. Research Progress in Degradation Mechanism of Organic Solar Cells [J]. Acta Chimica Sinica, 2022, 80(7): 993-1009.
[5]	Ning Xu, Qinglong Qiao, Xiaogang Liu, Zhaochao Xu. Enhancing Brightness and Photostability of Organic Small Molecular Fluorescent Dyes Through Inhibiting Twisted Intramolecular Charge Transfer (TICT)^※ [J]. Acta Chimica Sinica, 2022, 80(4): 553-562.
[6]	Jing Zhou, Xueying Tian, Binkai Wang, Shasha Zhang, Zonghao Liu, Wei Chen. Application of Low Temperature Atomic Layer Deposition Packaging Technology in OLED and Its Implications for Organic and Perovskite Solar Cell Packaging [J]. Acta Chimica Sinica, 2022, 80(3): 395-422.
[7]	Min Dai, Gangtie Lei, Zhao Zhang, Zhi Li, Hujun Cao, Ping Chen. Room Temperature Hydrogen Absorption of V₂O₅ Catalyzed MgH₂/Mg^※ [J]. Acta Chimica Sinica, 2022, 80(3): 303-309.
[8]	Qing Huang, Rui Ding, Lai Chen, Yun Lu, Qi Shi, Qiyu Zhang, Qijun Nie, Yuefeng Su, Feng Wu. Dual-Decoration and Mechanism Analysis of Ni-rich LiNi_0.83Co_0.11Mn_0.06O₂ Cathodes by Na₂PO₃F [J]. Acta Chimica Sinica, 2022, 80(2): 150-158.
[9]	Wenjun Wu, Yuting Li, Xi Feng, Wenxing Ding. Perovskite Dual-function Passivator: Room Temperature Ionic Liquid Obtained from Mechanochemical Preparation [J]. Acta Chimica Sinica, 2022, 80(11): 1469-1475.
[10]	Zheng Gong, Yi Zhang, Hua Lu, Shuxun Cui. Single-chain Mechanics of Proline-based Polyesters [J]. Acta Chimica Sinica, 2022, 80(1): 7-10.
[11]	Zewei Lyu, Minfang Han, Zaihong Sun, Kaihua Sun. Evolution of Electrochemical Characteristics of Solid Oxide Fuel Cells During Initial-Stage Operation [J]. Acta Chimica Sinica, 2021, 79(6): 763-770.
[12]	Junhui Miao, Zicheng Ding, Jun Liu, Lixiang Wang. Research Progress in Organic Solar Cells Based on Small Molecule Donors and Polymer Acceptors [J]. Acta Chimica Sinica, 2021, 79(5): 545-556.
[13]	Chang-An Liu, Shi-Bo Hong, Bei Li. Molecular Dynamics Simulation of the Stability Behavior of Graphene in Glycerol/Urea Solvents in Liquid-Phase Exfoliation [J]. Acta Chimica Sinica, 2021, 79(4): 530-538.
[14]	Yue Lu, Yang Ge, Manling Sui. Different Degradation Mechanism of CH₃NH₃PbI₃ Based Perovskite Solar Cells under Ultraviolet and Visible Light Illumination [J]. Acta Chimica Sinica, 2021, 79(3): 344-352.
[15]	Tiankun Zhao, Peng Wang, Mingyu Ji, Shanjia Li, Mingjun Yang, Xiuying Pu. Post-Synthetic Modification Research of Salan Titanium bis-Chelates via Sonogashira Reaction [J]. Acta Chimica Sinica, 2021, 79(11): 1385-1393.