有机化学 ›› 2013, Vol. 33 ›› Issue (04): 715-737.DOI: 10.6023/cjoc201301075 上一篇    下一篇

综述与进展

基于氮杂环卡宾的多齿C,N-配体过渡金属化合物的合成与应用

顾绍金a, 黄菁菁a, 陈万芝b   

  1. a 武汉纺织大学纺织新材料与先进加工技术国家重点实验室培育基地 武汉 430200;
    b 浙江大学化学系 杭州 310028
  • 收稿日期:2013-01-29 修回日期:2013-03-17 发布日期:2013-03-22
  • 通讯作者: 陈万芝 E-mail:chenwzz@zju.edu.cn
  • 基金资助:

    国家自然科学基金(No. 21202127)和中国纺织工业联合会科技指导性(No. 2012005)资助项目.

Synthesis and Catalytic Applications of Transition Metal Complexes of Multidentate N-Heterocyclic Carbenes

Gu Shaojina, Huang Jingjinga, Chen Wanzhib   

  1. a State Key Laboratory Breeding Base of New Textile Materials and Advanced Processing Technologies, Wuhan Textile University, Wuhan 430200;
    b Department of Chemistry, Zhejiang Uiniversity, Hangzhou 310028
  • Received:2013-01-29 Revised:2013-03-17 Published:2013-03-22
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 21202127) and the China National Textile and Apparel Council Scientific and Technical Guidance of the Project Plan (No. 2012005).

综述了基于氮杂环卡宾的多齿C,N-配体过渡金属化合物的合成与应用研究的最新进展, 结合本课题组的工作介绍了含有吡啶、嘧啶、吡唑、萘啶、哒嗪、三唑和邻菲罗啉等氮杂环基团的氮杂环卡宾过渡金属化合物在有机合成中的应用.

Recent progresses in the organometallic chemistry of multidentate C,N-ligands based on functionalized N-heterocyclic carbenes is summarized. Our related works on pyridine-, pyrimidine-, pyrazole-, naphthyridine-, pyridazine-, triazole, and phenanthroline-functionalized N-heterocyclic carbenes are included.

Key words: multidentate ligands, N-heterocyclic carbene, synthesis, catalysis