过渡金属及主族元素配合物活化NH3中N—H键的研究进展

doi:10.6023/cjoc201301081

摘要/Abstract

NH₃是一种在自然界生命过程及人类社会化学化工生产过程中非常重要的小分子. 近年来, 在过渡金属元素(如Ir, Rh, Ru, Fe, Pd等)及主族元素(如Si, Ge, Sn等)配合物活化NH₃中N—H键的研究方面取得了一系列进展. 介绍这方面研究的新成果.

关键词: 氨气, N—H键, 活化, 过渡金属配合物, 主族元素配合物

Activation of ammonia has received increasing attention in recent years due to its important role both in nature and industry processes. A series of transition metal (such as Ir, Rh, Ru, Fe, Pd, etc.) and main group element (such as Si, Ge, Sn, etc.) complexes have been reported to activate N—H bond of ammonia in the past three decades. This review includes the recent progresses in homogeneous N—H bond activation of ammonia by transition metal and main group element complexes.

Key words: Ammonia, N—H bond, activation , transition metal complex, main group element complex

引用此文

房华毅, 凌镇, 付雪峰. 过渡金属及主族元素配合物活化NH₃中N—H键的研究进展[J]. 有机化学, 2013, 33(04): 738-748.

Fang Huayi, Ling Zhen, Fu Xuefeng. N—H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes[J]. Chin. J. Org. Chem., 2013, 33(04): 738-748.

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过渡金属及主族元素配合物活化NH₃中N—H键的研究进展

N—H Bond Activation of Ammonia by Transition Metal and Main Group Element Complexes

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